Citation: ZHAO Shu-Heng, LANG Lin, JIANG Jun-Fei, YIN Xiu-Li, WU Chuang-Zhi. Synthesis and Low-Temperature Detemplation of High-Silica MFI Zeolite Membranes[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 519-526. doi: 10.3866/PKU.WHXB201511243 shu

Synthesis and Low-Temperature Detemplation of High-Silica MFI Zeolite Membranes

1.
1 CAS Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
2.
2 University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Corresponding author: LANG Lin,
Received Date: 24 September 2015
Available Online: 23 November 2015
Fund Project: 国家自然科学基金(51202245,51106165) (51202245,51106165)广东省自然科学基金(S2013010014896,10251007006000000)资助项目 (S2013010014896,10251007006000000)

High-silica MFI zeolite membranes supported on porous α-alumina discs were prepared by a seeded secondary growth method, using tetrapropylammonium hydroxide (TPAOH) as organic template. First, nanocrystals were deposited on rough α-Al₂O₃ discs by a spin-on process. Then, based on controlling the H₂O/Si molar ratio of the synthetic solution, a restricting in-plane h0h-oriented growth method with an ultra-dilute precursor was designed to prepare non-defective zeolite membranes that were as thin as possible. Finally, crosslinked and dense MFI zeolite membranes were prepared after the third synthesis step, giving a membrane layer thickness of about 8 μm, including ~5 μm dense layers and ~3 μm intermediate layers. Anovel, two-step method, coupling by low-temperature hydrocracking and oxidation, is proposed for efficient removal of the template from zeolite membranes. Compared with traditional high-temperature calcination, template removal by the two-step method could eliminate the grain boundary defects formed in response to stresses induced by heat treatment. As a result, the membranes treated by the two-step detemplation method displayed a preferable CO₂/N₂ separation factor (about 5.2) and high CO₂ permeance (5.8 × 10^-7 mol·m^-2·s^-11·Pa^-1) at 30 ℃.
- High-silica MFI zeolite membrane,
- Template removal,
- Low-temperature hydrocracking,
- Gas permeation,
- Support
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