Citation: FENG Lei, HAO Jing-Cheng. Preparation and Property of Gold Nanoparticles from Muliple Self- Assembled Structures as Templates in LA/C₁₄DMAO/H₂O System[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 380-390. doi: 10.3866/PKU.WHXB201511193 shu

Preparation and Property of Gold Nanoparticles from Muliple Self- Assembled Structures as Templates in LA/C₁₄DMAO/H₂O System

FENG Lei ,
HAO Jing-Cheng ^,

1.
Key Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan 250100, P. R. China

Corresponding author: HAO Jing-Cheng,
Received Date: 12 October 2015
Available Online: 19 November 2015
Fund Project: 国家自然科学基金(2140102006,21273134) (2140102006,21273134)山东省自然科学基金(ZR2013BQ025)资助项目 (ZR2013BQ025)

Rich phase behavior was observed in salt-free cationic/anionic (catanionic) surfactant mixtures of lauric acid (LA) with a nonionic surfactant, tetradecyldimethylamine oxide (C₁₄DMAO), in water. The phase behavior and microstructures of the LA/C₁₄DMAO/H₂O system were investigated by freeze-fracture transmission electron microscope (FF-TEM), polarized optical microscope (POM), differential scanning calorimetry (DSC), rheological measurements, and ²H NMR. A variety of self-assembled microstructures were determined, including micelles (L₁ phase), lamellae (L_αl phase), vesicles (L_αv phase) and gels. Using the L₁ and L_αl phases as the templates, gold nanoparticles could be produced, as confirmed by transmission electron microscope (TEM) and energy dispersive spectrometer (EDS). Compared with the traditional method of preparing Au nanomaterials in aqueous solutions, this method can avoid the addition of NaBH₄ as a reducing agent. The sample solution plays roles as a template and a reductant and the reduction process does not destroy the original self-assembled microstructures in the solution. Hence, by controlling the aggregate structures of the template solution, one can achieve the goal of regulating the morphology of Au nanomaterials, which provides a new path for the preparation of noble metal nanostructured materials with different shapes and structures. The results of the methyl thiazolyl tetrazolium (MTT) assay with HK-2 cells show that, as a gene carrier, spherical Au-nanoparticles prepared in a micellar phase possess the characteristics of higher loading efficiency and lower toxicity than those obtained in traditional surfactant systems, demonstrating potential applications in gene therapy.
- Lauric acid,
- Tetradecyldimethylamine oxide,
- Phase behavior,
- Template,
- Au nanomaterial
1. [1]
  (1) Kaler, E. W.; Murthy, A. K.; Rodriguez, B. E.; Zasadzinski, J. A. N. Science 1989, 245, 1371. doi: 10.1126/science.2781283
2. [2]
  (2) Morigaki, K.; Dallavalle, S.; Walde, P.; Colonna, S.; Luisi, P. L. J. Am. Chem. Soc 1997, 119, 292. doi: 10.1021/ja961728b
3. [3]
  (3) Bergstrøm, M. P.; Pedersen, J. S. Langmuir 1999, 15, 2250. doi: 10.1021/la981495x
4. [4]
  (4) Horbaschek, K. H.; Hoffmann, H.; Hao, J. J. Phys. Chem. B 2000, 104, 2781. doi: 10.1021/jp993128f
5. [5]
  (5) Campbell, S. E.; Zhang, Z.; Friberg, S. E.; Patel, R. Langmuir 1998, 14, 590. doi: 10.1021/la9707742
6. [6]
  (6) Horbaschek, K.; Hoffmann, H.; Thunig, C. J. Colloid Interface Sci. 1998, 206, 439. doi: 10.1006/jcis.1998.5690
7. [7]
  (7) Hao, J.; Li, H.; Liu, W.; Hirsch, A. Chem. Commun. 2004, No. 5, 602.
8. [8]
  (8) Song, S.; Feng, L.; Song, A.; Hao, J. J. Phys. Chem. B 2012, 116, 12850. doi: 10.1021/jp3066025
9. [9]
  (9) Song, S.; Zheng, Q.; Song, A.; Hao, J. Langmuir 2012, 28, 219.
10. [10]
  (10) Jiang, Y.; Geng, T.; Li, Q.; Li, G.; Ju, H. Colloids Surf. A 2014, 462, 27. doi: 10.1016/j.colsurfa.2014.08.020
11. [11]
  (11) Ghosh, S.; Ray, A. Ind. Eng. Chem. Res. 2015, 54, 1953. doi: 10.1021/ie503697c
12. [12]
  (12) Gao, J.; Bender, C. M.; Murphy, C. J. Langmuir 2003, 19, 9065. doi: 10.1021/la034919i
13. [13]
  (13) Murphy, C. J.; Jana, N. R. Adv. Mater. 2002, 14, 80.
14. [14]
  (14) Lu, C.; Wu, N.; Jiao, X.; Luo, C.; Cao, W. Chem. Commun. 2003, No. 9, 1056.
15. [15]
  (15) Huang, X.; El-Sayed, M. A. Lasers Med. Sci. 2008, 23, 217. doi: 10.1007/s10103-007-0470-x
16. [16]
  (16) Wei, Q.; Ji, J.; Shen, J. J. Nanosci. Nanotechnol. 2008, 8, 5708. doi: 10.1166/jnn.2008.302
17. [17]
  (17) Xiao, J.; Qi, L. Nanoscale 2011, 3, 1383. doi: 10.1039/c0nr00814a
18. [18]
  (18) Cai, W.; Fu, G.; Li, C.; Zhang, L.; Kan, C. Appl. Phys. A 2004, 78, 1187. doi: 10.1007/s00339-003-2202-9
19. [19]
  (19) Loubat, A.; Lacroix, L. M.; Robert, A.; Impéror-Clerc, M.; Poteau, R.; Maron, L.; Arenal, R.; Pansu, B.; Viau, G. J. Phys. Chem. C 2015, 119, 4422. doi: 10.1021/acs.jpcc.5b00242
20. [20]
  (20) Jana, N. R.; Gearheart, L.; Murphy, C. J. Adv. Mater. 2001, 13, 1389.
21. [21]
  (21) Xu, L.; Feng, L.; Dong, R.; Hao, J.; Dong, S. Biomacromolecules 2013, 14, 2781. doi: 10.1021/bm400616y
22. [22]
  (22) Teng, M.; Song, A.; Liu, L.; Hao, J. J. Phys. Chem. B 2008, 112, 1671. doi: 10.1021/jp075767t
23. [23]
  (23) Leontidis, E. K. K.; Kyprianidou-Leodidou, T.; Bekiari, V.; Lianos, P. Langmuir 2002, 18, 3659. doi: 10.1021/la011368s
24. [24]
  (24) Zanchet, D.; Micheel, C. M.; Parak, W. J.; Gerion, D.; Alivisatos, A. P. Nano Lett. 2001, 1, 32.
25. [25]
  (25) Gao, H.; Kong ,Y.; Cui, D.; Ozkan, C. S. Nano Lett. 2003, 3, 471. doi: 10.1021/nl025967a
26. [26]
  (26) Wu, H.; Liu, H.; Tan, S.; Yu, J.; Zhao, W.; Wang, L.; Liu, Q. J. Phys. Chem. C 2014, 118, 26825. doi: 10.1021/jp5083032
27. [27]
  (27) Maeda, H. Colloids Surf. A 1996, 109, 263. doi: 10.1016/0927-7757(95)03459-5
28. [28]
  (28) Song, A.; Dong, S.; Jia, X.; Hao, J.; Liu, W.; Liu, T. Angew. Chem. Int. Edit. 2005, 117, 4086.
29. [29]
  (29) Hoffmann, H. Adv. Mater. 1994, 6, 116.
30. [30]
  (30) Wang, L.; Liu, J.; Exarhos, G. J.; Flanigan, K. Y.; Bordia, R. J. Phys. Chem. B 2000, 104, 2810. doi: 10.1021/jp993058c
31. [31]
  (31) Li, Q.; Li, T.; Wu, J. J. Phys. Chem. B 2000, 104, 9011. doi: 10.1021/jp000336v
32. [32]
  (32) Kondo, Y.; Miyazawa, H.; Sakai, H.; Abe, M.; Yoshino, N. J. Am. Chem. Soc. 2002, 124, 6516. doi: 10.1021/ja0178564
33. [33]
  (33) Medronho, B.; Shafaei, S.; Szopko, R.; Miguel, M. G.; Olsson, U.; Schmidt, C. Langmuir 2008, 24, 6480. doi: 10.1021/la800326a
34. [34]
  (34) Liu, C.; Hao, J.; Wu, Z. J. Phys. Chem. B 2010, 114, 9795.
35. [35]
  (35) Alexandridis, P.; Zhou, D.; Khan, A. Langmuir 1996, 12, 2690. doi: 10.1021/la951025s
36. [36]
  (36) Niu, J.; Wang, D.; Qin, H.; Xiong, X.; Tan, P.; Li, Y.; Liu, R.; Lu, X.; Wu, J.; Zhang, T.; Ni, W.; Jin, J. Nature Commun. 2014, 5, 3313.
37. [37]
  (37) Pileni, M. P. Nat. Mater. 2003, 2, 145. doi: 10.1038/nmat817
38. [38]
  (38) Dong, R.; Liu, W.; Hao, J. Accounts Chem. Res. 2012, 45, 504. doi: 10.1021/ar200124g
1. [1]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
2. [2]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
3. [3]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
4. [4]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
5. [5]
  Meijin Li , Xirong Fu , Xue Zheng , Yuhan Liu , Bao Li . The Marvel of NAD⁺: Nicotinamide Adenine Dinucleotide. University Chemistry, 2024, 39(9): 35-39. doi: 10.12461/PKU.DXHX202401027
6. [6]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
7. [7]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
8. [8]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
9. [9]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
10. [10]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
11. [11]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
12. [12]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
13. [13]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
14. [14]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
15. [15]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
16. [16]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
17. [17]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
18. [18]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
19. [19]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
20. [20]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(369)
HTML views(43)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Property of Gold Nanoparticles from Muliple Self- Assembled Structures as Templates in LA/C14DMAO/H2O System

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Property of Gold Nanoparticles from Muliple Self- Assembled Structures as Templates in LA/C₁₄DMAO/H₂O System