Citation: FENG Lei, HAO Jing-Cheng. Preparation and Property of Gold Nanoparticles from Muliple Self- Assembled Structures as Templates in LA/C₁₄DMAO/H₂O System[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 380-390. doi: 10.3866/PKU.WHXB201511193 shu

Preparation and Property of Gold Nanoparticles from Muliple Self- Assembled Structures as Templates in LA/C₁₄DMAO/H₂O System

FENG Lei ,
HAO Jing-Cheng ^,

1.
Key Laboratory of Colloid and Interface Chemistry, Shandong University, Jinan 250100, P. R. China

Corresponding author: HAO Jing-Cheng,
Received Date: 12 October 2015
Available Online: 19 November 2015
Fund Project: 国家自然科学基金(2140102006,21273134) (2140102006,21273134)山东省自然科学基金(ZR2013BQ025)资助项目 (ZR2013BQ025)

Rich phase behavior was observed in salt-free cationic/anionic (catanionic) surfactant mixtures of lauric acid (LA) with a nonionic surfactant, tetradecyldimethylamine oxide (C₁₄DMAO), in water. The phase behavior and microstructures of the LA/C₁₄DMAO/H₂O system were investigated by freeze-fracture transmission electron microscope (FF-TEM), polarized optical microscope (POM), differential scanning calorimetry (DSC), rheological measurements, and ²H NMR. A variety of self-assembled microstructures were determined, including micelles (L₁ phase), lamellae (L_αl phase), vesicles (L_αv phase) and gels. Using the L₁ and L_αl phases as the templates, gold nanoparticles could be produced, as confirmed by transmission electron microscope (TEM) and energy dispersive spectrometer (EDS). Compared with the traditional method of preparing Au nanomaterials in aqueous solutions, this method can avoid the addition of NaBH₄ as a reducing agent. The sample solution plays roles as a template and a reductant and the reduction process does not destroy the original self-assembled microstructures in the solution. Hence, by controlling the aggregate structures of the template solution, one can achieve the goal of regulating the morphology of Au nanomaterials, which provides a new path for the preparation of noble metal nanostructured materials with different shapes and structures. The results of the methyl thiazolyl tetrazolium (MTT) assay with HK-2 cells show that, as a gene carrier, spherical Au-nanoparticles prepared in a micellar phase possess the characteristics of higher loading efficiency and lower toxicity than those obtained in traditional surfactant systems, demonstrating potential applications in gene therapy.
- Lauric acid,
- Tetradecyldimethylamine oxide,
- Phase behavior,
- Template,
- Au nanomaterial
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Property of Gold Nanoparticles from Muliple Self- Assembled Structures as Templates in LA/C14DMAO/H2O System

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通讯作者: 陈斌, bchen63@163.com

Preparation and Property of Gold Nanoparticles from Muliple Self- Assembled Structures as Templates in LA/C₁₄DMAO/H₂O System