Citation: JIN Yan-Xia, TANG Cen, MENG Xiu-Qing, WANG Xiao-Xia, XIE Guan-Qun, LUO Meng-Fei, LI Xiao-Nian. Highly Stable CsNO₃/SiO₂ Catalysts for the Synthesis of Vinylidene Chloride Using a Gaseous Phase Method[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 510-518. doi: 10.3866/PKU.WHXB201511134 shu

Highly Stable CsNO₃/SiO₂ Catalysts for the Synthesis of Vinylidene Chloride Using a Gaseous Phase Method

1.
1 Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China;
2.
2 State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Industrial Catalysis Institute, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Corresponding author: XIE Guan-Qun, LUO Meng-Fei,
Received Date: 14 September 2015
Available Online: 13 November 2015
Fund Project: 国家自然科学基金(21476207) (21476207)浙江师范大学浙江省省属高校化学重中之重学科和先进催化材料教育部重点实验室开放课题基金(ZJHX201413)资助项目 (ZJHX201413)

CsNO₃/SiO₂ catalysts were prepared using an impregnation method, and were applied in the vapor phase catalytic synthesis of vinylidene chloride (VDC) from 1,1,2-trichloroethane (TCE). The influence of reaction temperature on the deactivation of CsNO₃/SiO₂ catalysts was investigated in detail. It was found that low reaction temperatures (< 350 ℃) lead to a rapid deactivation, while high reaction temperatures (> 400 ℃) result in a high and stable catalytic activity. During the dehydrochlorination process, CsNO₃ species were transformed into CsCl, and coke was formed and deposited on the catalyst surface. However, the chemical change of the Cs species and deposited coke were not the main reason for the deactivation of CsNO₃/SiO₂ catalyst. Some chlorine-containing species (organic products or HCl) were formed during the reaction and were difficult to desorb from the catalyst surface, which accounts for the deactivation of CsNO₃/SiO₂ catalysts at low reaction temperatures. High temperature treatment (550 ℃) in a non-oxidizing atmosphere could remove the contaminants and regenerate the catalysts completely. The life test of CsNO₃/SiO₂ catalyst was carried out at 400 ℃ for 100 h. The TCE conversion and the selectivity to VDC remained stable at 98% and 78%, respectively, showing good prospect for industrial applications.
- Vinylidenechloride,
- 1,1,2-Trichloroethane,
- CsNO₃,
- Dehydrochlorination,
- Heterogeneous reaction
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Highly Stable CsNO3/SiO2 Catalysts for the Synthesis of Vinylidene Chloride Using a Gaseous Phase Method

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通讯作者: 陈斌, bchen63@163.com

Highly Stable CsNO₃/SiO₂ Catalysts for the Synthesis of Vinylidene Chloride Using a Gaseous Phase Method