Citation: LIU Xing-Rui, YAN Hui-Juan, WANG Dong, WAN Li-Jun. In situ AFM Investigation of Interfacial Morphology of Single Crystal Silicon Wafer Anode[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 283-289. doi: 10.3866/PKU.WHXB201511132 shu

In situ AFM Investigation of Interfacial Morphology of Single Crystal Silicon Wafer Anode

1.
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Corresponding author: WANG Dong,
Received Date: 2 October 2015
Available Online: 12 November 2015
Fund Project: 科技部(2011YQ03012415,2011CB932302) (2011YQ03012415,2011CB932302)国家自然科学基金(21127901,21573252)资助项目 (21127901,21573252)

The interfacial morphology of a single crystal Si wafer anode during the first discharging-charging cycle was investigated using in situ atomic force microscopy (AFM). The solid-electrolyte interphase (SEI) began to grow from 1.5 V, developing rapidly between 1.25 and 1.0 V, and slowed down after 0.6 V. The morphology suggested that the SEI had a layered structure. The outer layer of SEI was soft and easy to be scraped off during the AFM tip scanning. The underlayer of SEI had granular features. During the lithiation process, the Si surface became grainy because of the insertion of Li ions. After the first cycle, the Si surface was completely covered by inhomogeneous SEI. The thickness of the SEI was approximately 10-40 nm.
- Si anode,
- Solid electrolyte interphase,
- In situ atomic force microscopy
1. [1]
  (1) Palacin, M. R. Chem. Soc. Rev. 2009, 38, 2565. doi: 10.1039/B820555H
2. [2]
  (2) Beattie, S. D.; Larcher, D.; Morcrette, M.; Simon, B.; Tarascon, J. M. J. Electrochem. Soc. 2008, 155, A158. doi: 10.1149/1.2817828
3. [3]
  (3) Wu, H.; Cui, Y. Nano Today 2012, 7, 414. doi: 10.1016/j.nantod.2012.08.004
4. [4]
  (4) Kong, F.; Kostecki, R.; Nadeau, G.; Song, X.; Zaghib, K.; Kinoshita, K.; McLarnon, F. J. Power Sources 2001, 97, 58. doi: 10.1016/S0378-7753(01)00588-2
5. [5]
  (5) Wu, H.; Zheng, G.; Liu, N.; Carney, T. J.; Yang, Y.; Cui, Y. Nano Lett. 2012, 12, 904. doi: 10.1021/nl203967r
6. [6]
  (6) Szczech, J. R.; Jin, S. Energy Environ. Sci. 2011, 4, 56. doi: 10.1039/C0EE00281J
7. [7]
  (7) Liu, X. H.; Zhong, L.; Huang, S.; Mao, S. X.; Zhu, T.; Huang, J. Y. ACS Nano 2012, 6, 1522. doi: 10.1021/nn204476h
8. [8]
  (8) McDowell, M. T.; Lee, S. W.; Harris, J. T.; Korgel, B. A.; Wang, C.; Nix, W. D.; Cui, Y. Nano Lett. 2013, 13, 758. doi: 10.1021/nl3044508
9. [9]
  (9) Chen, D.; Mei, X.; Ji, G.; Lu, M.; Xie, J.; Lu, J.; Lee, J. Y. Angew. Chem. Int. Edit. 2012, 51, 2409. doi: 10.1002/anie.201107885
10. [10]
  (10) Zhou, X.; Yin, Y. X.; Wan, L. J.; Guo, Y. G. Chem. Commun. 2012, 48, 2198. doi: 10.1039/c2cc17061b
11. [11]
  (11) Li, X.; Meduri, P.; Chen, X.; Qi, W.; Engelhard, M. H.; Xu, W.; Ding, F.; Xiao, J.; Wang, W.; Wang, C. J. Mater. Chem. 2012, 22, 11014. doi: 10.1039/C2JM31286G
12. [12]
  (12) Liu, N.; Wu, H.; McDowell, M. T.; Yao, Y.; Wang, C.; Cui, Y. Nano Lett. 2012, 12, 3315. doi: 10.1021/nl3014814
13. [13]
  (13) Xu, K. Chem. Rev. 2014, 114, 11503. doi: 10.1021/cr500003w
14. [14]
  (14) Nie, M.; Chalasani, D.; Abraham, D. P.; Chen, Y.; Bose, A.; Lucht, B. L. J. Phys. Chem. C 2013, 117, 1257. doi: 10.1021/jp3118055
15. [15]
  (15) Philippe, B.; Dedryvère, R.; Gorgoi, M.; Rensmo, H.; Gonbeau, D.; Edström, K. Chem. Mater. 2013, 25, 394. doi: 10.1021/cm303399v
16. [16]
  (16) Arreaga-Salas, D. E.; Sra, A. K.; Roodenko, K.; Chabal, Y. J.; Hinkle, C. L. J. Phys. Chem. C 2012, 116, 9072. doi: 10.1021/jp300787p
17. [17]
  (17) Sacci, R. L.; Dudney, N. J.; More, K. L.; Parent, L. R.; Arslan, I.; Browning, N. D.; Unocic, R. R. Chem. Commun. 2014, 50, 2104. doi: 10.1039/c3cc49029g
18. [18]
  (18) Baddour-Hadjean, R.; Pereira-Ramos, J. P. Chem. Rev. 2009, 110, 1278. doi: 10.1021/cr800344k
19. [19]
  (19) Li, J. T.; Zhou, Z. Y.; Broadwell, I.; Sun, S. G. Accounts Chem. Res. 2012, 45, 485. doi: 10.1021/ar200215t
20. [20]
  (20) Rhodes, K.; Kirkham, M.; Meisner, R.; Parish, C. M.; Dudney, N.; Daniel, C. Rev. Sci. Instrum. 2011, 82, 075107. doi: 10.1063/1.3607961
21. [21]
  (21) Sugimoto, Y.; Pou, P.; Abe, M.; Jelinek, P.; Pérez, R.; Morita, S.; Custance, Ó. Nature 2007, 446, 64. doi: 10.1038/nature05530
22. [22]
  (22) Morita, S. J. Electron Microsc. 2011, 60, S199. doi: 10.1093/jmicro/dfr047
23. [23]
  (23) Jeong, S. K.; Inaba, M.; Abe, T.; Ogumi, Z. J. Electrochem. Soc. 2001, 148, A989.
24. [24]
  (24) Deng, X.; Liu, X.; Yan, H.; Wang, D.; Wan, L. Sci. China Chem. 2013, 57, 178. doi: 10.1007/s11426-013-4988-4
25. [25]
  (25) Liu, X. R.; Wang, L.; Wan, L. J.; Wang, D. ACS Appl. Mater. Interfaces 2015, 7, 9573. doi: 10.1021/acsami.5b01024
26. [26]
  (26) Demirocak, D. E.; Bhushan, B. J. Colloid Interface Sci. 2014, 423, 151. doi: 10.1016/j.jcis.2014.02.035
27. [27]
  (27) Liu, X. R.; Wang, D.; Wan, L. J. Sci. Bull. 2015, 60, 839. doi: 10.1007/s11434-015-0763-6
28. [28]
  (28) Domi, Y.; Ochida, M.; Tsubouchi, S.; Nakagawa, H.; Yamanaka, T.; Doi, T.; Abe, T.; Ogumi, Z. J. Phys. Chem. C 2011, 115, 25484. doi: 10.1021/jp2064672
29. [29]
  (29) Liu, R. R.; Deng, X.; Liu, X. R.; Yan, H. J.; Cao, A. M.; Wang, D. Chem. Commun. 2014, 50, 15756. doi: 10.1039/C4CC07290A
30. [30]
  (30) Beaulieu, L. Y.; Hatchard, T. D.; Bonakdarpour, A.; Fleischauer, M. D.; Dahn, J. R. J. Electrochem. Soc. 2003, 150, A1457. doi: 10.1149/1.1613668
31. [31]
  (31) Martin, L.; Martinez, H.; Ulldemolins, M.; Pecquenard, B.; Le Cras, F. Solid State Ionics 2012, 215, 36. doi: 10.1016/j.ssi.2012.03.042
32. [32]
  (32) He, Y.; Yu, X.; Li, G.; Wang, R.; Li, H.; Wang, Y.; Gao, H.; Huang, X. J. Power Sources 2012, 216, 131. doi: 10.1016/j.jpowsour.2012.04.105
33. [33]
  (33) Becker, C. R.; Strawhecker, K. E.; McAllister, Q. P.; Lundgren, C. A. ACS Nano 2013, 7, 9173. doi: 10.1021/nn4037909
34. [34]
  (34) McAllister, Q. P.; Strawhecker, K. E.; Becker, C. R.; Lundgren, C. A. J. Power Sources 2014, 257, 380. doi: 10.1016/j.jpowsour.2014.01.077
35. [35]
  (35) Liu, X. R.; Deng, X.; Liu, R. R.; Yan, H. J.; Guo, Y. G.; Wang, D.; Wan, L. J. ACS Appl. Mater. Interfaces 2014, 6, 20317. doi: 10.1021/am505847s
36. [36]
  (36) Zheng, J.; Zheng, H.; Wang, R.; Ben, L.; Lu, W.; Chen, L.; Li, H. Phys. Chem. Chem. Phys. 2014, 16, 13229. doi: 10.1039/c4cp01968g
37. [37]
  (37) Tokranov, A.; Sheldon, B. W.; Li, C.; Minne, S.; Xiao, X. ACS Appl. Mater. Interfaces 2014, 6, 6672. doi: 10.1021/am500363t
38. [38]
  (38) Gosalvez, M.; Nieminen, R. New J. Phys. 2003, 5, 100. doi: http://dx.doi.org/10.1088/1367-2630/5/1/400
39. [39]
  (39) Sato, K.; Shikida, M.; Yamashiro, T.; Tsunekawa, M.; Ito, S. Sens. Actuators A 1999, 73, 122. doi: 10.1016/S0924-4247(98)00270-2
40. [40]
  (40) Guzman, H. V.; Perrino, A. P.; Garcia, R. ACS Nano 2013, 7, 3198. doi: 10.1021/nn4012835
41. [41]
  (41) Alsteens, D.; Dupres, V.; Yunus, S.; Latgé, J. P.; Heinisch, J. J. J.; Dufréne, Y. F. Langmuir 2012, 28, 16738. doi: 10.1021/la303891j
42. [42]
  (42) Wind, R. A.; Jones, H.; Little, M. J.; Hines, M. A. J. Phys. Chem. B 2002, 106, 1557. doi: 10.1021/jp011361j
43. [43]
  (43) Philipsen, H. G.; Kelly, J. J. J. Phys. Chem. B 2005, 109, 17245. doi: 10.1021/jp052595w
44. [44]
  (44) Cresce, A. V.; Russell, S. M.; Baker, D. R.; Gaskell, K. J.; Xu, K. Nano Lett. 2014, 14, 1405. doi: 10.1021/nl404471v
45. [45]
  (45) Leroy, S.; Martinez, H.; Dedryvere, R.; Lemordant, D.; Gonbeau, D. Appl. Surf. Sci. 2007, 253, 4895. doi: 10.1016/j.apsusc.2006.10.071
1. [1]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048
2. [2]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
3. [3]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
4. [4]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
5. [5]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
6. [6]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
7. [7]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
8. [8]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
9. [9]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
10. [10]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
11. [11]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
12. [12]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
13. [13]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
14. [14]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
15. [15]
  Ziliang KANG , Jiamin ZHANG , Hong AN , Xiaohua LIU , Yang CHEN , Jinping LI , Libo LI . Preparation and water adsorption properties of CaCl₂@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282
16. [16]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
17. [17]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
18. [18]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
19. [19]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
20. [20]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(438)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142