Citation: LIU Xing-Rui, YAN Hui-Juan, WANG Dong, WAN Li-Jun. In situ AFM Investigation of Interfacial Morphology of Single Crystal Silicon Wafer Anode[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 283-289. doi: 10.3866/PKU.WHXB201511132 shu

In situ AFM Investigation of Interfacial Morphology of Single Crystal Silicon Wafer Anode

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CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Corresponding author: WANG Dong,
Received Date: 2 October 2015
Available Online: 12 November 2015
Fund Project: 科技部(2011YQ03012415,2011CB932302) (2011YQ03012415,2011CB932302)国家自然科学基金(21127901,21573252)资助项目 (21127901,21573252)

The interfacial morphology of a single crystal Si wafer anode during the first discharging-charging cycle was investigated using in situ atomic force microscopy (AFM). The solid-electrolyte interphase (SEI) began to grow from 1.5 V, developing rapidly between 1.25 and 1.0 V, and slowed down after 0.6 V. The morphology suggested that the SEI had a layered structure. The outer layer of SEI was soft and easy to be scraped off during the AFM tip scanning. The underlayer of SEI had granular features. During the lithiation process, the Si surface became grainy because of the insertion of Li ions. After the first cycle, the Si surface was completely covered by inhomogeneous SEI. The thickness of the SEI was approximately 10-40 nm.
- Si anode,
- Solid electrolyte interphase,
- In situ atomic force microscopy
1. [1]
  (1) Palacin, M. R. Chem. Soc. Rev. 2009, 38, 2565. doi: 10.1039/B820555H
2. [2]
  (2) Beattie, S. D.; Larcher, D.; Morcrette, M.; Simon, B.; Tarascon, J. M. J. Electrochem. Soc. 2008, 155, A158. doi: 10.1149/1.2817828
3. [3]
  (3) Wu, H.; Cui, Y. Nano Today 2012, 7, 414. doi: 10.1016/j.nantod.2012.08.004
4. [4]
  (4) Kong, F.; Kostecki, R.; Nadeau, G.; Song, X.; Zaghib, K.; Kinoshita, K.; McLarnon, F. J. Power Sources 2001, 97, 58. doi: 10.1016/S0378-7753(01)00588-2
5. [5]
  (5) Wu, H.; Zheng, G.; Liu, N.; Carney, T. J.; Yang, Y.; Cui, Y. Nano Lett. 2012, 12, 904. doi: 10.1021/nl203967r
6. [6]
  (6) Szczech, J. R.; Jin, S. Energy Environ. Sci. 2011, 4, 56. doi: 10.1039/C0EE00281J
7. [7]
  (7) Liu, X. H.; Zhong, L.; Huang, S.; Mao, S. X.; Zhu, T.; Huang, J. Y. ACS Nano 2012, 6, 1522. doi: 10.1021/nn204476h
8. [8]
  (8) McDowell, M. T.; Lee, S. W.; Harris, J. T.; Korgel, B. A.; Wang, C.; Nix, W. D.; Cui, Y. Nano Lett. 2013, 13, 758. doi: 10.1021/nl3044508
9. [9]
  (9) Chen, D.; Mei, X.; Ji, G.; Lu, M.; Xie, J.; Lu, J.; Lee, J. Y. Angew. Chem. Int. Edit. 2012, 51, 2409. doi: 10.1002/anie.201107885
10. [10]
  (10) Zhou, X.; Yin, Y. X.; Wan, L. J.; Guo, Y. G. Chem. Commun. 2012, 48, 2198. doi: 10.1039/c2cc17061b
11. [11]
  (11) Li, X.; Meduri, P.; Chen, X.; Qi, W.; Engelhard, M. H.; Xu, W.; Ding, F.; Xiao, J.; Wang, W.; Wang, C. J. Mater. Chem. 2012, 22, 11014. doi: 10.1039/C2JM31286G
12. [12]
  (12) Liu, N.; Wu, H.; McDowell, M. T.; Yao, Y.; Wang, C.; Cui, Y. Nano Lett. 2012, 12, 3315. doi: 10.1021/nl3014814
13. [13]
  (13) Xu, K. Chem. Rev. 2014, 114, 11503. doi: 10.1021/cr500003w
14. [14]
  (14) Nie, M.; Chalasani, D.; Abraham, D. P.; Chen, Y.; Bose, A.; Lucht, B. L. J. Phys. Chem. C 2013, 117, 1257. doi: 10.1021/jp3118055
15. [15]
  (15) Philippe, B.; Dedryvère, R.; Gorgoi, M.; Rensmo, H.; Gonbeau, D.; Edström, K. Chem. Mater. 2013, 25, 394. doi: 10.1021/cm303399v
16. [16]
  (16) Arreaga-Salas, D. E.; Sra, A. K.; Roodenko, K.; Chabal, Y. J.; Hinkle, C. L. J. Phys. Chem. C 2012, 116, 9072. doi: 10.1021/jp300787p
17. [17]
  (17) Sacci, R. L.; Dudney, N. J.; More, K. L.; Parent, L. R.; Arslan, I.; Browning, N. D.; Unocic, R. R. Chem. Commun. 2014, 50, 2104. doi: 10.1039/c3cc49029g
18. [18]
  (18) Baddour-Hadjean, R.; Pereira-Ramos, J. P. Chem. Rev. 2009, 110, 1278. doi: 10.1021/cr800344k
19. [19]
  (19) Li, J. T.; Zhou, Z. Y.; Broadwell, I.; Sun, S. G. Accounts Chem. Res. 2012, 45, 485. doi: 10.1021/ar200215t
20. [20]
  (20) Rhodes, K.; Kirkham, M.; Meisner, R.; Parish, C. M.; Dudney, N.; Daniel, C. Rev. Sci. Instrum. 2011, 82, 075107. doi: 10.1063/1.3607961
21. [21]
  (21) Sugimoto, Y.; Pou, P.; Abe, M.; Jelinek, P.; Pérez, R.; Morita, S.; Custance, Ó. Nature 2007, 446, 64. doi: 10.1038/nature05530
22. [22]
  (22) Morita, S. J. Electron Microsc. 2011, 60, S199. doi: 10.1093/jmicro/dfr047
23. [23]
  (23) Jeong, S. K.; Inaba, M.; Abe, T.; Ogumi, Z. J. Electrochem. Soc. 2001, 148, A989.
24. [24]
  (24) Deng, X.; Liu, X.; Yan, H.; Wang, D.; Wan, L. Sci. China Chem. 2013, 57, 178. doi: 10.1007/s11426-013-4988-4
25. [25]
  (25) Liu, X. R.; Wang, L.; Wan, L. J.; Wang, D. ACS Appl. Mater. Interfaces 2015, 7, 9573. doi: 10.1021/acsami.5b01024
26. [26]
  (26) Demirocak, D. E.; Bhushan, B. J. Colloid Interface Sci. 2014, 423, 151. doi: 10.1016/j.jcis.2014.02.035
27. [27]
  (27) Liu, X. R.; Wang, D.; Wan, L. J. Sci. Bull. 2015, 60, 839. doi: 10.1007/s11434-015-0763-6
28. [28]
  (28) Domi, Y.; Ochida, M.; Tsubouchi, S.; Nakagawa, H.; Yamanaka, T.; Doi, T.; Abe, T.; Ogumi, Z. J. Phys. Chem. C 2011, 115, 25484. doi: 10.1021/jp2064672
29. [29]
  (29) Liu, R. R.; Deng, X.; Liu, X. R.; Yan, H. J.; Cao, A. M.; Wang, D. Chem. Commun. 2014, 50, 15756. doi: 10.1039/C4CC07290A
30. [30]
  (30) Beaulieu, L. Y.; Hatchard, T. D.; Bonakdarpour, A.; Fleischauer, M. D.; Dahn, J. R. J. Electrochem. Soc. 2003, 150, A1457. doi: 10.1149/1.1613668
31. [31]
  (31) Martin, L.; Martinez, H.; Ulldemolins, M.; Pecquenard, B.; Le Cras, F. Solid State Ionics 2012, 215, 36. doi: 10.1016/j.ssi.2012.03.042
32. [32]
  (32) He, Y.; Yu, X.; Li, G.; Wang, R.; Li, H.; Wang, Y.; Gao, H.; Huang, X. J. Power Sources 2012, 216, 131. doi: 10.1016/j.jpowsour.2012.04.105
33. [33]
  (33) Becker, C. R.; Strawhecker, K. E.; McAllister, Q. P.; Lundgren, C. A. ACS Nano 2013, 7, 9173. doi: 10.1021/nn4037909
34. [34]
  (34) McAllister, Q. P.; Strawhecker, K. E.; Becker, C. R.; Lundgren, C. A. J. Power Sources 2014, 257, 380. doi: 10.1016/j.jpowsour.2014.01.077
35. [35]
  (35) Liu, X. R.; Deng, X.; Liu, R. R.; Yan, H. J.; Guo, Y. G.; Wang, D.; Wan, L. J. ACS Appl. Mater. Interfaces 2014, 6, 20317. doi: 10.1021/am505847s
36. [36]
  (36) Zheng, J.; Zheng, H.; Wang, R.; Ben, L.; Lu, W.; Chen, L.; Li, H. Phys. Chem. Chem. Phys. 2014, 16, 13229. doi: 10.1039/c4cp01968g
37. [37]
  (37) Tokranov, A.; Sheldon, B. W.; Li, C.; Minne, S.; Xiao, X. ACS Appl. Mater. Interfaces 2014, 6, 6672. doi: 10.1021/am500363t
38. [38]
  (38) Gosalvez, M.; Nieminen, R. New J. Phys. 2003, 5, 100. doi: http://dx.doi.org/10.1088/1367-2630/5/1/400
39. [39]
  (39) Sato, K.; Shikida, M.; Yamashiro, T.; Tsunekawa, M.; Ito, S. Sens. Actuators A 1999, 73, 122. doi: 10.1016/S0924-4247(98)00270-2
40. [40]
  (40) Guzman, H. V.; Perrino, A. P.; Garcia, R. ACS Nano 2013, 7, 3198. doi: 10.1021/nn4012835
41. [41]
  (41) Alsteens, D.; Dupres, V.; Yunus, S.; Latgé, J. P.; Heinisch, J. J. J.; Dufréne, Y. F. Langmuir 2012, 28, 16738. doi: 10.1021/la303891j
42. [42]
  (42) Wind, R. A.; Jones, H.; Little, M. J.; Hines, M. A. J. Phys. Chem. B 2002, 106, 1557. doi: 10.1021/jp011361j
43. [43]
  (43) Philipsen, H. G.; Kelly, J. J. J. Phys. Chem. B 2005, 109, 17245. doi: 10.1021/jp052595w
44. [44]
  (44) Cresce, A. V.; Russell, S. M.; Baker, D. R.; Gaskell, K. J.; Xu, K. Nano Lett. 2014, 14, 1405. doi: 10.1021/nl404471v
45. [45]
  (45) Leroy, S.; Martinez, H.; Dedryvere, R.; Lemordant, D.; Gonbeau, D. Appl. Surf. Sci. 2007, 253, 4895. doi: 10.1016/j.apsusc.2006.10.071
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