Citation: LI Ya-Jie, NI Xing-Yuan, SHEN Jun, LIU Dong, LIU Nian-Ping, ZHOU Xiao-Wei. Preparation and Performance of Polypyrrole/Nitric Acid Activated Carbon Aerogel Nanocomposite Materials for Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 493-502. doi: 10.3866/PKU.WHXB201511131 shu

Preparation and Performance of Polypyrrole/Nitric Acid Activated Carbon Aerogel Nanocomposite Materials for Supercapacitors

1.
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, Institute of Physical Science and Engineering, Tongji University, Shanghai 200092, P. R. China

Corresponding author: NI Xing-Yuan,
Received Date: 25 June 2015
Available Online: 10 November 2015
Fund Project: 国家自然科学基金(51072137,50802064,11074189) (51072137,50802064,11074189)国家科技支撑计划重点项目(2009BAC62B02) (2009BAC62B02)上海科学技术委员会项目(11nm0501600)资助 (11nm0501600)

Polypyrrole (PPY)/nitric acid (HNO3) activated carbon aerogel (HCA) composites are prepared through chemical oxidative polymerization with different PPY/HCAmass ratios. Fourier transform infrared (FTIR) spectroscopy and scanning electron microscope (SEM) were employed to investigate the components and morphology of the samples. The results demonstrate that the synthesized materials maintain the threedimensional nanoporous structure of the carbon aerogel (CA); the activation by nitric acid and composition with PPY do not destroy the porous structure of the carbon aerogel and the complex still has the original threedimensional nanoporous structure. Composites with different mass ratios (3:1, 2:1, 1:1, 1:2, 1:3) of PPY/HCA were prepared and the electrochemical properties were measured by cyclic voltammetry, galvanostatic charge-discharge test, and electrochemical impedance spectroscopy. The results confirm that the PPY/HCA composite with a ratio of 1:1 exhibits the best electrochemical performances; it has a high specific capacitance of 336 F·g^-1, which is more than two times higher than that of CA (103 F·g^-1); it also exhibits outstanding conductivity and cycling stability, retaining 91% of its initial capacitance after 2000 cycles. Therefore, this composite is quite a promising electrode material for supercapacitors.
- Activated carbon aerogel,
- Polypyrrole,
- Supercapacitor,
- Chemical oxidative polymerization,
- Composite electrode material,
- Capacitive property
1. [1]
  (1) Wang, J. B.; Yang, X. Q.; Wu, D. C.; Fu, R.W.; Dresselhaus, M.S.; Dresselhaus, G. Journal of Power Sources 2008, 185, 589. doi: 10.1016/j.jpowsour.2008.06.070
2. [2]
  (2) Li, J.; Wang, X. Y.; Huang, Q. H.; Gambo, S.; Sebastian, P. J.Journal of Power Sources 2006, 158, 784.
3. [3]
  (3) Burke, A. Journal of Power Sources 2000, 91, 37 doi: 10.1016/S0378-7753(00)00485-7
4. [4]
  (4) Lewandowski, A.; Jakobczyk, P.; Galinski, M. Electrochimica Acta 2012, 86, 225. doi: 10.1016/j.electacta.2012.05.060
5. [5]
  (5) Wang, K. X.; Wang, Y. G.; Wang, Y. R.; Hosono, E.; Zhou, H. S.J. Phys. Chem. C 2009, 113, 1093. doi: 10.1021/jp807463u
6. [6]
  (6) Chen, H.; Wang, F.; Tong, S. S.; Guo, S. L.; Pan, X. M. Applied Surface Science 2012, 258, 6097. doi: 10.1016/j.apsusc.2012.03.009
7. [7]
  (7) Gonzá lez-Garcí a, P.; Centeno, T. A.; Urones-Garrote, E.; Ávila-Brande, D.; Otero-Dí az, L.C. Applied Surface Science 2013, 265, 731. doi: 10.1016/j.apsusc.2012.11.092
8. [8]
  (8) Halama, A.; Szubzda, B.; Pasciak, G.; Electrochimica Acta 2010, 55, 7501. doi: 10.1016/j.electacta.2010.03.040
9. [9]
  (9) Schmit, C.; Probstle, H.; Fricke, J. J. Non-Cryst. Solids 2001, 285, 2772.
10. [10]
  (10) Liang, J.; Wei, B. Q.; Zhang, B.; Xu, C. L.; Wu, D. H.; Ma, R.Z. Journal of Power Sources 1999, 84, 126.
11. [11]
  (11) Lei, C. H.; Wilson, P.; Lekakou, C. Journal of Power Sources 2011, 196, 7823.
12. [12]
  (12) Peng, C.; Zhang, S.W.; Jewell, D.; Chen, G. Z. Prog. Nat. Sci. 2008, 18, 777. doi: 10.1016/j.pnsc.2008.03.002
13. [13]
  (13) Sugimoto, W.; Yokoshima, K.; Murakami, Y.; Takasu, Y.Electrochimica Acta 2006, 52, 1742. doi: 10.1016/j.electacta.2006.02.054
14. [14]
  (14) Xu, H.; Li, J. L.; Peng, Z. J.; Zhuang, J. X.; Zhang, J. L.Electrochimica Acta 2013, 90, 393. doi: 10.1016/j.electacta.2012.12.047
15. [15]
  (15) Mastragostino, M.; Arbizzani, C.; Soavi, F. Solid State Ionics 2002, 148, 493. doi: 10.1016/S0167-2738(02)00093-0
16. [16]
  (16) Li, J.; Cui, L.; Zhang, X. G. Applied Surface Science 2010, 256, 4339. doi: 10.1016/j.apsusc.2010.02.028
17. [17]
  (17) Biswas, S.; Drzal, L. T. Chemical Materials 2010, 22, 5667. doi: 10.1021/cm101132g
18. [18]
  (18) Zhao, X. F.; Jiang, Q.; Guo, Y. N.; Zhang, N.; Shan, C. X.; Zhao, Y. Journal of Inorganic Material 2010, 25, 91.
19. [19]
  (19) Mi, H. Y.; Zhang, X. G.; Xu, Y. L.; Xiao, F. Applied Surface Science 2010, 256, 2284. doi: 10.1016/j.apsusc.2009.10.053
20. [20]
  (20) Selvakumar, M.; Dhat, D. K. Applied Surface Science 2012, 263, 236. doi: 10.1016/j.apsusc.2012.09.036
21. [21]
  (21) Wang, G. X.; Zhang, B. L.; Yu, Z. L.; Qu, M. Z. Solid State Ionics 2005, 176, 1169. doi: 10.1016/j.ssi.2005.02.005
22. [22]
  (22) Liu, N. P.; Shen, J.; Liu, D. Microporous and Mesoporous Materials 2013, 167, 176. doi: 10.1016/j.micromeso.2012.09.009
23. [23]
  (23) Liu, D.; Shen, J.; Liu, N. P.; Yang, H. Y.; Du, A. Electrochimica Acta 2013, 89, 571. doi: 10.1016/j.electacta.2012.11.033
24. [24]
  (24) Cui, C. J.; Zhao, A. L.; Wu, G. M. Journal of Functional Materials 2012, 43, 1281.
25. [25]
  (25) Omastová , M.; Trchová , M.; Ková rǒ vá c, J.; Stejskalc, J.Synthetic Metals 2003, 138, 447. doi: 10.1016/S0379-6779(02)00498-8
26. [26]
  (26) Cui, L.; Li, J.; Zhang, X. G. Materials Letters 2009, 63, 683.
27. [27]
  (27) Liang, N. Synthesis and Characterization of PPY and ItsComposite Materials. Master Dissertation, Jiangsu Universityof Science and Technology, Zhenjiang, 2012. [梁宁. 聚吡咯及其复合材料的制备与性能研究[D]. 镇江: 江苏科技大学, 2012.]
28. [28]
  (28) Du, B.; Jiang, Q.; Zhao, X. F.; Lin, S. Z.; Mu, P. S.; Zhao, Y.Acta Phys. -Chim. Sin. 2009, 25 (3), 513. [杜冰, 江奇, 赵晓峰, 林孙忠, 幕佩珊, 赵勇. 物理化学学报, 2009, 25 (3), 513.] doi: 10.3866/PKU.WHXB20090319
29. [29]
  (29) Pandolfo, A. G.; Hollenkamp, A. F. Journal of Power Sources 2006, 157, 11. doi: 10.1016/j.jpowsour.2006.02.065
30. [30]
  (30) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; KluwerAcademic/Plenum Publishers: New York, 1999; p 299.
31. [31]
  (31) An, K. H.; Jeon, K. K.; Heo, J. K.; Lim, S. C.; Bae, D. J.; Lee, Y. H. Journal of the Electrochemical Society 2002, 149, A1058.
32. [32]
  (32) Liu, D.; Shen, J.; Li, Y. J.; Liu, N. P.; Liu, B. Acta Phys. -Chim. Sin. 2012, 28 (4), 843. [刘冬, 沈军, 李亚捷, 刘念平, 刘斌. 物理化学学报, 2012, 28 (4), 843.] doi: 10.3866/PKU.WHXB201202172
33. [33]
  (33) Yan, J.; Wei, T.; Shao, B.; Ma, F. Q.; Fan, Z. J. Carbon 2010, 48, 1731. doi: 10.1016/j.carbon.2010.01.014
34. [34]
  (34) Zhu, J. B.; Xu, Y. L.; Wang, J.; Wang, J. P. Acta Phys. -Chim. Sin. 2012, 28 (2), 373. [朱剑波, 徐友龙, 王杰, 王景平. 物理化学学报, 2012, 28 (2), 373.] doi: 10.3866/PKU.WHXB201112021
35. [35]
  (35) Zhou, X.W.; Wu, G. M.; Gao, G. H.; Cui, C. J.; Yang, H. Y.; Shen, J.; Zhou, B.; Zhang, Z. H. Electrochimica Acta 2012, 74, 32. doi: 10.1016/j.electacta.2012.03.178
36. [36]
  (36) Jurewicz, K.; Delpeux, S.; Bertagna, V.; Beguin, F.; Frackowiak, E. Chemical Physics Letters 2001, 347, 36.
37. [37]
  (37) Park, B. H.; Choi, J. H. Electrochimica Acta 2010, 55, 2888. doi: 10.1016/j.electacta.2009.12.084
1. [1]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
2. [2]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
3. [3]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-0. doi: 10.1016/j.actphy.2025.100063
4. [4]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
5. [5]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
6. [6]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
7. [7]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
8. [8]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
9. [9]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
10. [10]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
11. [11]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
12. [12]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
13. [13]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
14. [14]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
15. [15]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
16. [16]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
17. [17]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
18. [18]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034
19. [19]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
20. [20]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(468)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142