Citation: LI Ya-Jie, NI Xing-Yuan, SHEN Jun, LIU Dong, LIU Nian-Ping, ZHOU Xiao-Wei. Preparation and Performance of Polypyrrole/Nitric Acid Activated Carbon Aerogel Nanocomposite Materials for Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 493-502. doi: 10.3866/PKU.WHXB201511131 shu

Preparation and Performance of Polypyrrole/Nitric Acid Activated Carbon Aerogel Nanocomposite Materials for Supercapacitors

1.
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, Institute of Physical Science and Engineering, Tongji University, Shanghai 200092, P. R. China

Corresponding author: NI Xing-Yuan,
Received Date: 25 June 2015
Available Online: 10 November 2015
Fund Project: 国家自然科学基金(51072137,50802064,11074189) (51072137,50802064,11074189)国家科技支撑计划重点项目(2009BAC62B02) (2009BAC62B02)上海科学技术委员会项目(11nm0501600)资助 (11nm0501600)

Polypyrrole (PPY)/nitric acid (HNO3) activated carbon aerogel (HCA) composites are prepared through chemical oxidative polymerization with different PPY/HCAmass ratios. Fourier transform infrared (FTIR) spectroscopy and scanning electron microscope (SEM) were employed to investigate the components and morphology of the samples. The results demonstrate that the synthesized materials maintain the threedimensional nanoporous structure of the carbon aerogel (CA); the activation by nitric acid and composition with PPY do not destroy the porous structure of the carbon aerogel and the complex still has the original threedimensional nanoporous structure. Composites with different mass ratios (3:1, 2:1, 1:1, 1:2, 1:3) of PPY/HCA were prepared and the electrochemical properties were measured by cyclic voltammetry, galvanostatic charge-discharge test, and electrochemical impedance spectroscopy. The results confirm that the PPY/HCA composite with a ratio of 1:1 exhibits the best electrochemical performances; it has a high specific capacitance of 336 F·g^-1, which is more than two times higher than that of CA (103 F·g^-1); it also exhibits outstanding conductivity and cycling stability, retaining 91% of its initial capacitance after 2000 cycles. Therefore, this composite is quite a promising electrode material for supercapacitors.
- Activated carbon aerogel,
- Polypyrrole,
- Supercapacitor,
- Chemical oxidative polymerization,
- Composite electrode material,
- Capacitive property
1. [1]
  (1) Wang, J. B.; Yang, X. Q.; Wu, D. C.; Fu, R.W.; Dresselhaus, M.S.; Dresselhaus, G. Journal of Power Sources 2008, 185, 589. doi: 10.1016/j.jpowsour.2008.06.070
2. [2]
  (2) Li, J.; Wang, X. Y.; Huang, Q. H.; Gambo, S.; Sebastian, P. J.Journal of Power Sources 2006, 158, 784.
3. [3]
  (3) Burke, A. Journal of Power Sources 2000, 91, 37 doi: 10.1016/S0378-7753(00)00485-7
4. [4]
  (4) Lewandowski, A.; Jakobczyk, P.; Galinski, M. Electrochimica Acta 2012, 86, 225. doi: 10.1016/j.electacta.2012.05.060
5. [5]
  (5) Wang, K. X.; Wang, Y. G.; Wang, Y. R.; Hosono, E.; Zhou, H. S.J. Phys. Chem. C 2009, 113, 1093. doi: 10.1021/jp807463u
6. [6]
  (6) Chen, H.; Wang, F.; Tong, S. S.; Guo, S. L.; Pan, X. M. Applied Surface Science 2012, 258, 6097. doi: 10.1016/j.apsusc.2012.03.009
7. [7]
  (7) Gonzá lez-Garcí a, P.; Centeno, T. A.; Urones-Garrote, E.; Ávila-Brande, D.; Otero-Dí az, L.C. Applied Surface Science 2013, 265, 731. doi: 10.1016/j.apsusc.2012.11.092
8. [8]
  (8) Halama, A.; Szubzda, B.; Pasciak, G.; Electrochimica Acta 2010, 55, 7501. doi: 10.1016/j.electacta.2010.03.040
9. [9]
  (9) Schmit, C.; Probstle, H.; Fricke, J. J. Non-Cryst. Solids 2001, 285, 2772.
10. [10]
  (10) Liang, J.; Wei, B. Q.; Zhang, B.; Xu, C. L.; Wu, D. H.; Ma, R.Z. Journal of Power Sources 1999, 84, 126.
11. [11]
  (11) Lei, C. H.; Wilson, P.; Lekakou, C. Journal of Power Sources 2011, 196, 7823.
12. [12]
  (12) Peng, C.; Zhang, S.W.; Jewell, D.; Chen, G. Z. Prog. Nat. Sci. 2008, 18, 777. doi: 10.1016/j.pnsc.2008.03.002
13. [13]
  (13) Sugimoto, W.; Yokoshima, K.; Murakami, Y.; Takasu, Y.Electrochimica Acta 2006, 52, 1742. doi: 10.1016/j.electacta.2006.02.054
14. [14]
  (14) Xu, H.; Li, J. L.; Peng, Z. J.; Zhuang, J. X.; Zhang, J. L.Electrochimica Acta 2013, 90, 393. doi: 10.1016/j.electacta.2012.12.047
15. [15]
  (15) Mastragostino, M.; Arbizzani, C.; Soavi, F. Solid State Ionics 2002, 148, 493. doi: 10.1016/S0167-2738(02)00093-0
16. [16]
  (16) Li, J.; Cui, L.; Zhang, X. G. Applied Surface Science 2010, 256, 4339. doi: 10.1016/j.apsusc.2010.02.028
17. [17]
  (17) Biswas, S.; Drzal, L. T. Chemical Materials 2010, 22, 5667. doi: 10.1021/cm101132g
18. [18]
  (18) Zhao, X. F.; Jiang, Q.; Guo, Y. N.; Zhang, N.; Shan, C. X.; Zhao, Y. Journal of Inorganic Material 2010, 25, 91.
19. [19]
  (19) Mi, H. Y.; Zhang, X. G.; Xu, Y. L.; Xiao, F. Applied Surface Science 2010, 256, 2284. doi: 10.1016/j.apsusc.2009.10.053
20. [20]
  (20) Selvakumar, M.; Dhat, D. K. Applied Surface Science 2012, 263, 236. doi: 10.1016/j.apsusc.2012.09.036
21. [21]
  (21) Wang, G. X.; Zhang, B. L.; Yu, Z. L.; Qu, M. Z. Solid State Ionics 2005, 176, 1169. doi: 10.1016/j.ssi.2005.02.005
22. [22]
  (22) Liu, N. P.; Shen, J.; Liu, D. Microporous and Mesoporous Materials 2013, 167, 176. doi: 10.1016/j.micromeso.2012.09.009
23. [23]
  (23) Liu, D.; Shen, J.; Liu, N. P.; Yang, H. Y.; Du, A. Electrochimica Acta 2013, 89, 571. doi: 10.1016/j.electacta.2012.11.033
24. [24]
  (24) Cui, C. J.; Zhao, A. L.; Wu, G. M. Journal of Functional Materials 2012, 43, 1281.
25. [25]
  (25) Omastová , M.; Trchová , M.; Ková rǒ vá c, J.; Stejskalc, J.Synthetic Metals 2003, 138, 447. doi: 10.1016/S0379-6779(02)00498-8
26. [26]
  (26) Cui, L.; Li, J.; Zhang, X. G. Materials Letters 2009, 63, 683.
27. [27]
  (27) Liang, N. Synthesis and Characterization of PPY and ItsComposite Materials. Master Dissertation, Jiangsu Universityof Science and Technology, Zhenjiang, 2012. [梁宁. 聚吡咯及其复合材料的制备与性能研究[D]. 镇江: 江苏科技大学, 2012.]
28. [28]
  (28) Du, B.; Jiang, Q.; Zhao, X. F.; Lin, S. Z.; Mu, P. S.; Zhao, Y.Acta Phys. -Chim. Sin. 2009, 25 (3), 513. [杜冰, 江奇, 赵晓峰, 林孙忠, 幕佩珊, 赵勇. 物理化学学报, 2009, 25 (3), 513.] doi: 10.3866/PKU.WHXB20090319
29. [29]
  (29) Pandolfo, A. G.; Hollenkamp, A. F. Journal of Power Sources 2006, 157, 11. doi: 10.1016/j.jpowsour.2006.02.065
30. [30]
  (30) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; KluwerAcademic/Plenum Publishers: New York, 1999; p 299.
31. [31]
  (31) An, K. H.; Jeon, K. K.; Heo, J. K.; Lim, S. C.; Bae, D. J.; Lee, Y. H. Journal of the Electrochemical Society 2002, 149, A1058.
32. [32]
  (32) Liu, D.; Shen, J.; Li, Y. J.; Liu, N. P.; Liu, B. Acta Phys. -Chim. Sin. 2012, 28 (4), 843. [刘冬, 沈军, 李亚捷, 刘念平, 刘斌. 物理化学学报, 2012, 28 (4), 843.] doi: 10.3866/PKU.WHXB201202172
33. [33]
  (33) Yan, J.; Wei, T.; Shao, B.; Ma, F. Q.; Fan, Z. J. Carbon 2010, 48, 1731. doi: 10.1016/j.carbon.2010.01.014
34. [34]
  (34) Zhu, J. B.; Xu, Y. L.; Wang, J.; Wang, J. P. Acta Phys. -Chim. Sin. 2012, 28 (2), 373. [朱剑波, 徐友龙, 王杰, 王景平. 物理化学学报, 2012, 28 (2), 373.] doi: 10.3866/PKU.WHXB201112021
35. [35]
  (35) Zhou, X.W.; Wu, G. M.; Gao, G. H.; Cui, C. J.; Yang, H. Y.; Shen, J.; Zhou, B.; Zhang, Z. H. Electrochimica Acta 2012, 74, 32. doi: 10.1016/j.electacta.2012.03.178
36. [36]
  (36) Jurewicz, K.; Delpeux, S.; Bertagna, V.; Beguin, F.; Frackowiak, E. Chemical Physics Letters 2001, 347, 36.
37. [37]
  (37) Park, B. H.; Choi, J. H. Electrochimica Acta 2010, 55, 2888. doi: 10.1016/j.electacta.2009.12.084
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