Citation: LI Ting, LONG Zhi-Hui, ZHANG Dao-Hong. Synthesis and Electrochemical Properties of Fe2O3/rGO Nanocomposites as Lithium and Sodium Storage Materials[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 573-580. doi: 10.3866/PKU.WHXB201511105
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Metal oxides are promising high-capacity anode materials for lithium and sodium-ion batteries because of the reversible multi-electron structural conversion reactions with lithium and sodium ions. In this study, Fe2O3/rGO (reduced graphene oxide) nanocomposites were prepared using graphene oxide sheets and ferric salt as precursors through a one-step solvothermal method. The experimental results demonstrated that the Fe2O3 nanocrystals were uniformly dispersed on the surface of reduced graphene oxide sheets. The nanocomposite anodes show superior charge-discharge performances and cyclability in lithium and sodium ion batteries,indicating that reduced graphene oxide sheets can reduce the charge-transfer resistance and stabilize the structure change during cycling. It suggests a potential feasibility to use these metal oxide nanocomposites as high capacity anode materials for lithium and sodium ion batteries.
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