Citation: LIN You-Cheng, ZHONG Xin-Xian, HUANG Han-Xing, WANG Hong-Qiang, FENG Qi-Peng, LI Qing-Yu. Preparation and Application of Polyaniline Doped with Different Sulfonic Acids for Supercapacitor[J]. Acta Physico-Chimica Sinica, ;2016, 32(2): 474-480. doi: 10.3866/PKU.WHXB201511104 shu

Preparation and Application of Polyaniline Doped with Different Sulfonic Acids for Supercapacitor

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Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education, Guangxi Key Laboratory of Low Carbon Energy Materials, School of Chemistry and Pharmaceutial Sciences, Guangxi Normal University, Guilin 541004, Guangxi Zhuang Autonomous Region, P. R. China

Corresponding author: ZHONG Xin-Xian, LI Qing-Yu,
Received Date: 20 July 2015
Available Online: 6 November 2015
Fund Project: 中国博士后科学基金(2014M562499XB) (2014M562499XB)国家自然科学基金(U1401246,51474110)资助项目 (U1401246,51474110)

Polyaniline (PANI) nanomaterials doped with three different sulfonic acid surfactants (perfluorinated sulfonic acid ion exchange resin (Nafion), sodium dodecyl sulfate (SDS), and sodium dodecyl benzene sulfonate (SDBS)) were prepared using an emulsion polymerization method with manganese dioxide (MnO₂) as the oxidant. The structure and morphology of the products were studied by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD). Symmetric redox supercapacitor was assembled with doped PANI as the active electrode material. The electrochemical performances of the materials were evaluated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge tests. These results suggest that the introduction of surfactant is beneficial for the formation of a fiber structure and increases the dispersion of PANI. A PANI-Nafion network with distributed porosity and average diameters of 30-40 nm is obtained. The specific capacitances of PANI-Nafion, PANI-SDS, and PANI-SDBS electrodes at 0.1 A·g^-1 are 385.3, 359.7, and 401.6 F·g^-1, respectively. Among these electrodes PANI-Nafion delivers the best cycle performance, maintaining 70.7% of its initial capacitance after 1000 cycles.
- Polyaniline,
- Organic sulfonic acid,
- Emulsion polymerization,
- Nanofiber,
- Supercapacitor
1. [1]
  (1) Wang, L. L.; Xing, R. G.; Zhang, B. W.; Hou, Y. Acta Phys. -Chim. Sin. 2014, 30 (9), 1659. [汪丽丽, 邢瑞光, 张邦文, 侯渊. 物理化学学报, 2014, 30 (9), 1659.] doi: 10.3866/PKU.WHXB201406162
2. [2]
  (2) Fan, T. J.; Tong, S. Z.; Zeng, W. J.; Niu, Q. L.; Liu, Y. D.; Kao, C. H.; Li, J. Y.; Huang, W.; Min, Y.; Arthur, J. E. Synth. Met. 2015, 199, 79. doi: 10.1016/j.synthmet.2014.11.017
3. [3]
  (3) Simon, P.; Gogotsi, Y. Nat. Mater. 2008, 7, 845. doi: 10.1038/nmat2297
4. [4]
  (4) Zhang, Y.; Feng, H.; Wu, X. B.; Wang, L. Z.; Zhang, A. Q.; Xia, T. C.; Dong, H. C.; Li, X. F.; Zhang, L. S. Int. J. Hydrog. Energy 2009, 34, 4889. doi: 10.1016/j.ijhydene.2009.04.005
5. [5]
  (5) Brownson, D. A. C.; Kampouris, D. K.; Banks, C. E. J. Power Sources 2011, 196, 4873. doi: 10.1016/j.jpowsour.2011.02.022
6. [6]
  (6) Tapan, K. D.; Smita, P. Polym. Plast. Technol. Eng. 2012, 51, 1487. doi: 10.1080/03602559.2012.710697
7. [7]
  (7) Wang, J. D.; Peng, T. J.; Xian, H. Y.; Sun, H. J. Acta Phys. -Chim. Sin. 2015, 31 (1), 90. [汪建德, 彭同江, 鲜海洋, 孙红娟. 物理化学学报, 2015, 31 (1), 90.] doi: 10.3866/PKU.WHXB201411202
8. [8]
  (8) Yang, S.; Xu, G. Y.; Han, J. P.; Bing, H.; Dou, H.; Zhang, X. G.Acta Phys. -Chim. Sin. 2015, 31 (4), 685. [杨硕, 徐桂银, 韩金鹏, 邴欢, 窦辉, 张校刚. 物理化学学报, 2015, 31 (4), 685.] doi: 10.3866/PKU.WHXB201502022
9. [9]
  (9) Gnanakan, S. R. P.; Murugananthem, N.; Subramania, A. Polym. Adv. Technol. 2011, 22 (6), 788. doi: 10.1002/pat.1578
10. [10]
  (10) Liao, Y.; Gao L.; Zhang, X. H.; Chen, J. H. Mater. Res. Bull. 2012, 47 (7), 1625. doi: 10.1016/j.materresbull.2012.03.047
11. [11]
  (11) Peng, H.; Ma, G. F.; Ying, W. M.; Wang, A. D.; Huang, H. H.; Lei, Z. Q. J. Power Sources 2012, 211, 40. doi: 10.1016/j.jpowsour.2012.03.074
12. [12]
  (12) Gao, L.; Liao, Y.; Zhang, X. H.; Chen, J. H. Chem. J. Chin. Univ. 2013, 34 (2), 2845. [高磊, 廖奕, 张小华, 陈金华. 高等学校化学学报, 2013, 34 (2), 2845.] doi: 10.7503/cjcu20130366
13. [13]
  (13) Cong, H. P.; Ren, X. C.; Wang, P.; Yu, S. R. Energy Environ. Sci. 2013, 6, 1185. doi: 10.1039/C2EE24203F
14. [14]
  (14) Graeme, A. S.; Pon, K.; Adam, S. B. J. Power Sources 2011, 196, 1. doi: 10.1016/j.jpowsour.2010.06.084
15. [15]
  (15) David, V.; Pavel, L.; Kimberly, A. S.; Fred, W.; Alan, J. H. Adv. Mater. 2014, 26 (30), 5095. doi: 10.1002/adma.201400966
16. [16]
  (16) Xin, G. X.; Wang, Y. H.; Liu, X. X.; Zhang, J. H.; Wang, Y. F.; Huang, J. J.; Zang, J. B. Electrochim. Acta 2015, 167, 254. doi: 10.1016/j.electacta.2015.03.181
17. [17]
  (17) Mohd, K.; Milton, A. T.; Iuri, S. B.; Vinicius, C. Z.; Jose, J. S.A.; Andre, A. P. Indian J. Mater. Sci. 2013, 2013, 7. doi.org/10.1155/2013/718304
18. [18]
  (18) Salma, B.; Salma, G.; Khurshid, A.; Shah, A. A. Synth. Met.2012, 162, 2259. doi: 10.1016/j.synthmet.2012.11.003
19. [19]
  (19) Girija, T. C.; Sangaranarayanan, M. V. Synth. Met. 2006, 156, 244. doi: 10.1016/j.synthmet.2005.12.006
20. [20]
  (20) Jan, P.; Jaroslav, S. Polym. Degrad. Stab. 2004, 86, 187. doi: 10.1016/j.polymdegradstab.2004.04.012
21. [21]
  (21) Gaikwad, P. D.; Shirale, D. J.; Gade, V. K.; Savale, P. A.; Kharat, H. J.; Kakde, K. P.; Hussaini, S. S.; Dhumane, N. R.; Shirsat, M. D. Bull. Mater. Sci. 2006, 29 (2), 169. doi: 10.1007/BF02704611
22. [22]
  (22) Chen, T.; Dong, C. F.; Li, X. G.; Gao, J. Polym. Degrad. Stab. 2009, 94 (10), 1788. doi: 10.1016/j.polymdegradstab.2009.06.011
23. [23]
  (23) Chen, W.; Rakhi, R. B.; Alshareef, H. N. J. Mater. Chem. A 2013, 1, 3315. doi: 10.1039/C3TA00499F
24. [24]
  (24) Xie, H. G.; Ma, Y. M.; Guo, J. S. Polymer 1999, 40 (1), 261. doi: 10.1016/S0032-3861(98)00224-9
25. [25]
  (25) Smitha, B.; Sridhar, S.; Animesh, K. J. Membr. Sci. 2005, 259, 10. doi: 10.1016/j.memsci.2005.01.035
26. [26]
  (26) Birgit, S.; Soowhan, K.; Vijayakumar, M.; Yang, Z. G.; Liu, J.J. Membr. Sci. 2011, 372, 11. doi: 10.1016/j.memsci.2011.01.025
27. [27]
  (27) Kim, B. C.; Ko, J. M.; Wallace, G. G. J. Power Sources 2008, 177, 665. doi: 10.1016/j.jpowsour.2007.11.078
28. [28]
  (28) Huang, Y. G.; Zhong, X. X.; Huang, H. X.; Li, Q. Y.; Wang, Z.H.; Feng, Q. P.; Wang, H. Q. Int. J. Hydrog. Energy 2014, 39(28), 16132. doi: 10.1016/j.ijhydene.2014.06.013
29. [29]
  (29) Sudipta, C.; Fabien, S.; Christine, C.; Suzy, V.; Alexandre, B.Carbohydr. Polym. 2012, 90 (2), 967. doi: 10.1016/j.carbpol.2012.06.028
30. [30]
  (30) Yang, M.; Li, J. X.; Li, H. H.; Su, L.W.; Wei, J. P.; Zhou, Z.Phys. Chem. Chem. Phys. 2012, 14, 11048. doi: 10.1039/C2CP41604B
31. [31]
  (31) Qiu, Y.; Lu, L.; Wang, S. S.; Zhang, X. H.; He, S. T.; He, T.J. Power Sources 2014, 253, 300. doi: 10.1016/j.jpowsour.2013.12.061
32. [32]
  (32) Gu, Y. S.; Tsai, J. Y. Synth. Met. 2012, 161 (23-24), 2743. doi: 10.1016/j.synthmet.2011.10.013
33. [33]
  (33) Zhou, D. H.; Li, Y. H.; Wang, J. Y.; Xu, P.; Han, X. J. Mater. Lett. 2011, 65 (23-24), 3601. doi: 10.1016/j.matlet.2011.08.021
34. [34]
  (34) Zhang, L. Y.; He, S. J.; Chen, S. L.; Guo, Q. H.; Hou, H. Q. Acta Phys. -Chim. Sin. 2010, 26 (12), 3181. [张雷勇, 何水剑, 陈水亮, 郭乔辉, 侯豪情. 物理化学学报, 2010, 26 (12), 3181.] doi: 10.3866/PKU.WHXB20101135
35. [35]
  (35) Trchová , M.; Sé deň ková , I.; Tobolková , E.; Stejskal, J. Polym. Degrad. Stab. 2004, 86 (1), 179. doi: 10.1016/j.polymdegradstab.2004.04.011
36. [36]
  (36) Lu, X. H.; Ng, H. Y.; Xu, J. Y.; He, H. B. Synth. Met. 2002, 128, 167. doi: 10.1016/S0379-6779(01)00668-3
37. [37]
  (37) Liu, W.; Ashok, L. C.; Ramaswamy, N.; Jayant, K.; Sukant, T.; Ferdinando, F. B.; Lynne, S. J. Am. Chem. Soc. 1999, 121 (49), 11345. doi: 10.1021/ja9926156
38. [38]
  (38) David, E. S.; Su-Moon, P. J. Electrochem. Soc. 1988, 135 (9), 2254. doi: 10.1149/1.2096248
39. [39]
  (39) Mi, H. Y.; Zhang, X. G.; Yang, S. D.; Ye, X. G.; Luo, J. M.Mater. Chem. Phys. 2008, 112 (1), 127. doi: 10.1016/j.matchemphys.2008.05.022
40. [40]
  (40) Yan, J.; Wei, T.; Fan, A. J.; Qian, W. Z.; Zhang, M. L.; Shen, X.D.; Wei, F. J. Power Sources 2010, 195, 3041. doi: 10.1016/j.jpowsour.2009.11.028
41. [41]
  (41) Kima, B. C.; Too, C. O.; Kwon, J. S.; Ko, J. M.; Wallace, G. G.Synth. Met. 2011, 161, 1130. doi: 10.1016/j.synthmet.2011.01.015
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