Citation: LU Ye-Chang, LI Wen-Hong, ZHANG Yong-Qiang, LI Xue-Feng, DONG Jin-Feng. In-situ Viscosity of Hydrolyzed Polyacrylamides and Surfactant Worm-Like Micelle Solutions in Microscale Capillaries[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 365-372. doi: 10.3866/PKU.WHXB201511102 shu

In-situ Viscosity of Hydrolyzed Polyacrylamides and Surfactant Worm-Like Micelle Solutions in Microscale Capillaries

1.
1College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, P. R. China;
2.
2 National Engineering Laboratory for Exploration and Development of Low-Permeability Oil & Gas Fields, Xi'an 710021, P. R. China;
3.
3 Research Institute of Exploration and Development, PetroChina Changqing Oilfield Company, Xi'an 710021, P. R. China

Corresponding author: DONG Jin-Feng,
Received Date: 30 September 2015
Available Online: 10 November 2015
Fund Project: 国家自然科学基金(21573164,21273165) (21573164,21273165)

Hydrolyzed polyacrylamides (HPAMs) are shear-thinning polymers and have wide application in enhanced oil recovery (EOR), whereas worm-like micelles (WLMs) are known as “living polymers”, which can be constructed by the self-assembly of surfactant molecules. Here, a series of experiments were conducted on the fluid behavior of HPAMs and worm-like micelles in microscale capillaries with radii from 1 to 10 μm. The results show that the size of capillary has a decisive effect on the in-situ viscosity of the polymer aqueous phase. It was observed that the shear thinning effect of HPAMs is more pronounced in smaller size of capillaries, where the non-Newtonian polymer flow turns into the Newtonian flow. Evidences from filtration with a microporous filter and transmission electron microscopy (TEM) reveal that the polymer network was broken down when entering into the capillary. Conversely, WLMs can maintain their bulk viscosity to a wide extent. We assume that surfactant molecules may reassemble their aggregates and recover their network in-situ. The results suggest that WLMs have a much lower viscosity, but display similar thickening power compared with large polymers in the low or ultra-low permeability reservoirs.
- Micro-scale capillary flows,
- In-situ viscosity,
- HPAMs,
- Worm-like micelles,
- Capillary pressure
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