Citation: HUANG Wei-Xin, QIAN Kun, WU Zong-Fang, CHEN Shi-Long. Structure-Sensitivity of Au Catalysis[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 48-60. doi: 10.3866/PKU.WHXB201511092 shu

Structure-Sensitivity of Au Catalysis

1.
CAS Key Laboratory of Materials for Energy Conversion, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China

Corresponding author: HUANG Wei-Xin,
Received Date: 12 October 2015
Available Online: 9 November 2015
Fund Project: 国家重点基础研究发展规划项目(973)(2013CB933104) (973)(2013CB933104)国家自然科学基金(21525313,20973161,21373192) (21525313,20973161,21373192)教育部中央高校基本科研业务费(WK2060030017) (WK2060030017)

Au catalysis is representative of nanocatalysis. Au catalysis has been demonstrated to be very complex and structure-sensitive. In this short review we summarize the literature reports on Au catalysis and our recent progress on the fundamental understanding of Au catalysis using model catalysts from single crystals to nanocrystals. We demonstrate the structure-sensitivity of Au catalysis used for NO decomposition, CO oxidation, and propylene epoxidation with H₂ and O₂ and the corresponding active Au structures. We discuss the effects of the geometric and electronic structures and the Au-oxide support interactions on Au catalysis, and the origin of high catalytic activity of the Au surface at low temperatures. Finally, we provide an outlook for future research directions of structure-sensitive Au catalysis.
- Surface chemistry,
- Heterogeneous catalysis,
- Model catalyst,
- CO oxidation reaction,
- NO decomposition reaction,
- Propylene epoxidation reaction
1. [1]
  (1) Hutchings, G. J. J. Catal. 1985, 96, 292. doi: 10.1016/0021-9517(85)90383-5
2. [2]
  (2) Nkosi, B.; Coville, N. J.; Hutchings, G. J. Appl. Catal. 1988, 43, 33. doi: 10.1016/S0166-9834(00)80898-2
3. [3]
  (3) Haruta, M.; Kobayashi, T.; Sano, H.; Yamada, N. Chem. Lett. 1987, 16, 405.
4. [4]
  (4) Haruta, M.; Yamada, N.; Kobayashi, T.; Iijima, S. J. Catal. 1989, 115, 301. doi: 10.1016/0021-9517(89)90034-1
5. [5]
  (5) Bond, G. C.; Thompson, D. T. Cat. Rev. Sci. Eng. 1999, 41, 319. doi: 10.1081/CR-100101171
6. [6]
  (6) Haruta, M.; Daté, M. Appl. Catal. A: Gen. 2001, 222, 427. doi: 10.1016/S0926-860X(01)00847-X
7. [7]
  (7) Hashmi, A. S. K.; Hutchings, G. J. Angew. Chem. Int. Edit. 2006, 45, 7896.
8. [8]
  (8) Takei, T.; Akita, T.; Nakamura, I.; Fujitani, T.; Okumura, M.; Okazaki, K.; Huang, J.; Ishida, T.; Haruta, M. Adv. Catal. 2012, 55, 1.
9. [9]
  (9) Ide, M. S.; Davis, R. J. Accounts Chem. Res. 2014, 47, 825. doi: 10.1021/ar4001907
10. [10]
  (10) Ojeda, M.; Iglesia, E. Chem. Commun. 2009, No. 3, 352.
11. [11]
  (11) Lee, S.; Molina, L. M.; López, M.; Alonso, J. A.; Hammer, B.; Lee, B.; Seifert, S.; Winans, R. E.; Elam, J. W.; Pellin, M. J.; Vajda, S. Angew. Chem. Int. Edit. 2009, 48, 1467. doi: 10.1002/anie.v48:8
12. [12]
  (12) Huang, J.; Akita, T.; Faye, J.; Fujitani, T.; Takei, T.; Haruta, M. Angew. Chem. Int. Edit. 2009, 48, 7862. doi: 10.1002/anie.v48:42
13. [13]
  (13) Fujitani, T.; Nakamura, I. Angew. Chem. Int. Edit. 2011, 50, 10144. doi: 10.1002/anie.201104694
14. [14]
  (14) Schubert, M. M.; Hackenberg, S.; van Veen, A. C.; Muhler, M.; Plzak, V.; Behm, R. J. J. Catal. 2001, 197, 113.
15. [15]
  (15) Daté, M.; Okumura, M.; Tsubota, S.; Haruta, M. Angew. Chem. Int. Edit. 2004, 43, 2129.
16. [16]
  (16) Costello, C. K.; Kung, M. C.; Oh, H. S.; Wang, Y.; Kung, H. H. Appl. Catal. A: Gen. 2002, 232, 159. doi: 10.1016/S0926-860X(02)00092-3
17. [17]
  (17) Costello, C. K.; Yang, J. H.; Law, H. Y.; Wang, Y.; Lin, J. N.; Marks, L. D.; Kung, M. C.; Kung, H. H. Appl. Catal. A 2003, 243, 15. doi: 10.1016/S0926-860X(02)00533-1
18. [18]
  (18) Kung, H. H.; Kung, M. C.; Costello, C. K. J. Catal. 2003, 216, 425. doi: 10.1016/S0021-9517(02)00111-2
19. [19]
  (19) Sanchez-Castillo, M. A.; Couto, C.; Kim, W. B.; Dumesic, J. A. Angew. Chem. Int. Edit. 2004, 43, 1140.
20. [20]
  (20) Saavedra, J.; Doan, H. A.; Pursell, C. J.; Grabow, L. C.; Chandler, B. D. Science 2014, 345, 1599. doi: 10.1126/science.1256018
21. [21]
  (21) Anderson, J. R.; Shlmoyama, Y. In Proc. 5th Int. Congr. Catal.; Hightower, J. W. Ed.; Elsevier B. V.: North-Holland, Amsterdam, 1973; p 965.
22. [22]
  (22) Boudart, M.; Aldag, A. W.; Ptak, L. D.; Benson, J. E. J. Catal. 1968, 17, 35.
23. [23]
  (23) Boudart, M.; Aldag, A. W.; Benson, J. E.; Dougharty, N. A.; Harklns, G. C. J. Catal. 1966, 6, 92. doi: 10.1016/0021-9517(66)90113-8
24. [24]
  (24) Dorllng, T. A.; Moss, R. L. J. Catal. 1966, 5, 111. doi: 10.1016/S0021-9517(66)80130-6
25. [25]
  (25) Boudart. M. Adv. Catal. 1969, 20, 153.
26. [26]
  (26) Volta. J. C.; Portefaix, J. L. Appl. Catal. 1985, 18, 1. doi: 10.1016/S0166-9834(00)80296-1
27. [27]
  (27) Carberry, J. J. J. Catal. 1987, 107, 248. doi: 10.1016/0021-9517(87)90291-0
28. [28]
  (28) Carberry, J. J. J. Catal. 1988, 114, 277. doi: 10.1016/0021-9517(88)90031-0
29. [29]
  (29) Haruta, M.; Tsubota, S.; Kobayashi, T.; Kageyama, H.; Genet, M. J.; Delmon, B. J. Catal. 1993, 144, 175. doi: 10.1006/jcat.1993.1322
30. [30]
  (30) Bamwenda, G. R.; Tsubota, S.; Nakamura, T.; Haruta, M. Catal. Lett. 1997, 44, 83. doi: 10.1023/A:1018925008633
31. [31]
  (31) Valden, M.; Lai, X.; Goodman, D. W. Science 1998, 281, 1647. doi: 10.1126/science.281.5383.1647
32. [32]
  (32) Zanella, R.; Giorgio, S.; Shin, C. H.; Henry, C. R.; Louis, C. J. Catal. 2004, 222, 357. doi: 10.1016/j.jcat.2003.11.005
33. [33]
  (33) Tai, Y.; Yamaguchi, W.; Tajiri, K.; Kageyama, H. Appl. Catal. A: Gen. 2009, 364, 143. doi: 10.1016/j.apcata.2009.05.041
34. [34]
  (34) Laoufi, I.; Saint-Lager, M. C.; Lazzari, R.; Jupille, J.; Robach, O.; Garaudée, S.; Cabailh, G.; Dolle, P.; Cruguel, H.; Bailly, A. J. Phys. Chem. C 2011, 115, 4673. doi: 10.1021/jp1110554
35. [35]
  (35) Haruta, M. Chem. Rec. 2003, 3, 75.
36. [36]
  (36) Green, I. X.; Tang, W.; Neurock, M.; Yates, J. T., Jr. Science 2011, 333, 736. doi: 10.1126/science.1207272
37. [37]
  (37) Lopez, N.; Janssens, T. V. W.; Clausen, B. S.; Xu, Y.; Mavrikakis, M.; Bligaard, T.; Nørskov, J. K. J. Catal. 2004, 223, 232. doi: 10.1016/j.jcat.2004.01.001
38. [38]
  (38) Janssens, T. V. W.; Clausen, B. S.; Hvolbæk, B.; Falsig, H.; Christensen, C. H.; Bligaard, T.; Nørskov, J. K. Topic Catal. 2007, 44, 15. doi: 10.1007/s11244-007-0335-3
39. [39]
  (39) Falsig, H.; Hvolbæk, B.; Kristensen, I. S.; Jiang, T.; Bligaard, T.; Christensen, C. H.; Nørskov, J. K. Angew. Chem. Int. Edit. 2008, 47, 4835.
40. [40]
  (40) Maeda, Y.; Okumura, M.; Tsubota, S.; Kohyama, M.; Haruta, M. Appl. Surf. Sci. 2004, 222, 409. doi: 10.1016/j.apsusc.2003.09.007
41. [41]
  (41) Chen, M. S.; Goodman, D. W. Science 2004, 306, 252.
42. [42]
  (42) Herzing, A. A.; Kiely, C. J.; Carley, A. F.; Landon, P.; Hutchings, G. J. Science 2008, 321, 1331. doi: 10.1126/science.1159639
43. [43]
  (43) Liu, Y.; Jia, C. J.; Yamasaki, J.; Terasaki, O.; Schüth, F. Angew. Chem. Int. Edit. 2010, 49, 5771. doi: 10.1002/anie.v49:33
44. [44]
  (44) Haruta, M. Catal. Today 1997, 36, 153. doi: 10.1016/S0920-5861(96)00208-8
45. [45]
  (45) Qian, K.; Fang, J.; Huang, W. X.; He, B.; Jiang, Z. Q.; Ma, Y. S.; Wei, S. Q. J. Mol. Catal. A: Chem. 2010, 320, 97. doi: 10.1016/j.molcata.2010.01.010
46. [46]
  (46) Somorjai, G. A.; Carrazza, J. Ind. Eng. Chem. Fundam. 1986, 25, 63. doi: 10.1021/i100021a009
47. [47]
  (47) Parker, I. B.; Waugh, K. C.; Bowker, M. J. Catal. 1988, 114, 457. doi: 10.1016/0021-9517(88)90049-8
48. [48]
  (48) Bennett, C. O.; Che, M. J. Catal. 1989, 120, 293. doi: 10.1016/0021-9517(89)90270-4
49. [49]
  (49) Meyer, R.; Lemire, C.; Shaikhutdinov, S. K.; Freund, H. J. Gold Bull. 2004, 37, 72. doi: 10.1007/BF03215519
50. [50]
  (50) Chen, M. S.; Goodman, D. W. Accounts Chem. Res. 2006, 39, 739. doi: 10.1021/ar040309d
51. [51]
  (51) Min, B. K.; Friend, C. M. Chem. Rev. 2007, 107, 2709. doi: 10.1021/cr050954d
52. [52]
  (52) Risse, T.; Shaikhutdinov, S.; Nilius, N.; Sterrer, M.; Freund, H. J. Accounts Chem. Res. 2008, 41, 949. doi: 10.1021/ar800078m
53. [53]
  (53) Chen, M. S.; Goodman, D. W. Chem. Soc. Rev. 2008, 37, 1860. doi: 10.1039/b707318f
54. [54]
  (54) Gong, J. L.; Mullins, C. B. Accounts Chem. Res. 2009, 42, 1063. doi: 10.1021/ar8002706
55. [55]
  (55) Carabineiro, S. A. C.; Nieuwenhuys, B. E. Gold Bull. 2010, 43, 252. doi: 10.1007/BF03214995
56. [56]
  (56) Gong, J. L. Chem. Rev. 2012, 112, 2987. doi: 10.1021/cr200041p
57. [57]
  (57) Stowers, K. J.; Madix, R. J.; Friend, C. M. J. Catal. 2013, 308, 131. doi: 10.1016/j.jcat.2013.05.033
58. [58]
  (58) Outka, D. A.; Madix, R. J. Surf. Sci. 1987, 179, 351. doi: 10.1016/0039-6028(87)90062-8
59. [59]
  (59) Gottfried, J. M.; Schmidt, K. J.; Schroeder, S. L. M.; Christmann, K. Surf. Sci. 2003, 536, 206. doi: 10.1016/S0039-6028(03)00595-8
60. [60]
  (60) Meier, D. C.; Bukhtiyarov, V.; Goodman, D.W. J. Phys. Chem. B 2003, 107, 12668. doi: 10.1021/jp030499u
61. [61]
  (61) McElhiney, G.; Pritchard, J. Surf. Sci. 1976, 60, 397. doi: 10.1016/0039-6028(76)90324-1
62. [62]
  (62) Peters, K. F.; Steadman, P.; Isern, H.; Alvarez, J.; Ferrer, S. Surf. Sci. 2000, 467, 10. doi: 10.1016/S0039-6028(00)00777-9
63. [63]
  (63) Olsen, C. W.; Masel, R. I. Surf. Sci. 1988, 201, 444. doi: 10.1016/0039-6028(88)90496-7
64. [64]
  (64) Canning, N. D. S.; Outka, D.; Madix, R. J. Surf. Sci. 1984, 141, 240. doi: 10.1016/0039-6028(84)90209-7
65. [65]
  (65) Outka, D. A.; Madix, R. J. Surf. Sci. 1987, 179, 351. doi: 10.1016/0039-6028(87)90062-8
1. [1]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
2. [2]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
3. [3]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
4. [4]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
5. [5]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
6. [6]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
7. [7]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
10. [10]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
13. [13]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
14. [14]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
15. [15]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
16. [16]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
17. [17]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
18. [18]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
19. [19]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
20. [20]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(557)
HTML views(64)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142