Citation: HUANG Wei-Xin, QIAN Kun, WU Zong-Fang, CHEN Shi-Long. Structure-Sensitivity of Au Catalysis[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 48-60. doi: 10.3866/PKU.WHXB201511092 shu

Structure-Sensitivity of Au Catalysis

1.
CAS Key Laboratory of Materials for Energy Conversion, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China

Corresponding author: HUANG Wei-Xin,
Received Date: 12 October 2015
Available Online: 9 November 2015
Fund Project: 国家重点基础研究发展规划项目(973)(2013CB933104) (973)(2013CB933104)国家自然科学基金(21525313,20973161,21373192) (21525313,20973161,21373192)教育部中央高校基本科研业务费(WK2060030017) (WK2060030017)

Au catalysis is representative of nanocatalysis. Au catalysis has been demonstrated to be very complex and structure-sensitive. In this short review we summarize the literature reports on Au catalysis and our recent progress on the fundamental understanding of Au catalysis using model catalysts from single crystals to nanocrystals. We demonstrate the structure-sensitivity of Au catalysis used for NO decomposition, CO oxidation, and propylene epoxidation with H₂ and O₂ and the corresponding active Au structures. We discuss the effects of the geometric and electronic structures and the Au-oxide support interactions on Au catalysis, and the origin of high catalytic activity of the Au surface at low temperatures. Finally, we provide an outlook for future research directions of structure-sensitive Au catalysis.
- Surface chemistry,
- Heterogeneous catalysis,
- Model catalyst,
- CO oxidation reaction,
- NO decomposition reaction,
- Propylene epoxidation reaction
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