Citation: HUANG Wei-Xin, QIAN Kun, WU Zong-Fang, CHEN Shi-Long. Structure-Sensitivity of Au Catalysis[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 48-60. doi: 10.3866/PKU.WHXB201511092 shu

Structure-Sensitivity of Au Catalysis

1.
CAS Key Laboratory of Materials for Energy Conversion, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China

Corresponding author: HUANG Wei-Xin,
Received Date: 12 October 2015
Available Online: 9 November 2015
Fund Project: 国家重点基础研究发展规划项目(973)(2013CB933104) (973)(2013CB933104)国家自然科学基金(21525313,20973161,21373192) (21525313,20973161,21373192)教育部中央高校基本科研业务费(WK2060030017) (WK2060030017)

Au catalysis is representative of nanocatalysis. Au catalysis has been demonstrated to be very complex and structure-sensitive. In this short review we summarize the literature reports on Au catalysis and our recent progress on the fundamental understanding of Au catalysis using model catalysts from single crystals to nanocrystals. We demonstrate the structure-sensitivity of Au catalysis used for NO decomposition, CO oxidation, and propylene epoxidation with H₂ and O₂ and the corresponding active Au structures. We discuss the effects of the geometric and electronic structures and the Au-oxide support interactions on Au catalysis, and the origin of high catalytic activity of the Au surface at low temperatures. Finally, we provide an outlook for future research directions of structure-sensitive Au catalysis.
- Surface chemistry,
- Heterogeneous catalysis,
- Model catalyst,
- CO oxidation reaction,
- NO decomposition reaction,
- Propylene epoxidation reaction
1. [1]
  (1) Hutchings, G. J. J. Catal. 1985, 96, 292. doi: 10.1016/0021-9517(85)90383-5
2. [2]
  (2) Nkosi, B.; Coville, N. J.; Hutchings, G. J. Appl. Catal. 1988, 43, 33. doi: 10.1016/S0166-9834(00)80898-2
3. [3]
  (3) Haruta, M.; Kobayashi, T.; Sano, H.; Yamada, N. Chem. Lett. 1987, 16, 405.
4. [4]
  (4) Haruta, M.; Yamada, N.; Kobayashi, T.; Iijima, S. J. Catal. 1989, 115, 301. doi: 10.1016/0021-9517(89)90034-1
5. [5]
  (5) Bond, G. C.; Thompson, D. T. Cat. Rev. Sci. Eng. 1999, 41, 319. doi: 10.1081/CR-100101171
6. [6]
  (6) Haruta, M.; Daté, M. Appl. Catal. A: Gen. 2001, 222, 427. doi: 10.1016/S0926-860X(01)00847-X
7. [7]
  (7) Hashmi, A. S. K.; Hutchings, G. J. Angew. Chem. Int. Edit. 2006, 45, 7896.
8. [8]
  (8) Takei, T.; Akita, T.; Nakamura, I.; Fujitani, T.; Okumura, M.; Okazaki, K.; Huang, J.; Ishida, T.; Haruta, M. Adv. Catal. 2012, 55, 1.
9. [9]
  (9) Ide, M. S.; Davis, R. J. Accounts Chem. Res. 2014, 47, 825. doi: 10.1021/ar4001907
10. [10]
  (10) Ojeda, M.; Iglesia, E. Chem. Commun. 2009, No. 3, 352.
11. [11]
  (11) Lee, S.; Molina, L. M.; López, M.; Alonso, J. A.; Hammer, B.; Lee, B.; Seifert, S.; Winans, R. E.; Elam, J. W.; Pellin, M. J.; Vajda, S. Angew. Chem. Int. Edit. 2009, 48, 1467. doi: 10.1002/anie.v48:8
12. [12]
  (12) Huang, J.; Akita, T.; Faye, J.; Fujitani, T.; Takei, T.; Haruta, M. Angew. Chem. Int. Edit. 2009, 48, 7862. doi: 10.1002/anie.v48:42
13. [13]
  (13) Fujitani, T.; Nakamura, I. Angew. Chem. Int. Edit. 2011, 50, 10144. doi: 10.1002/anie.201104694
14. [14]
  (14) Schubert, M. M.; Hackenberg, S.; van Veen, A. C.; Muhler, M.; Plzak, V.; Behm, R. J. J. Catal. 2001, 197, 113.
15. [15]
  (15) Daté, M.; Okumura, M.; Tsubota, S.; Haruta, M. Angew. Chem. Int. Edit. 2004, 43, 2129.
16. [16]
  (16) Costello, C. K.; Kung, M. C.; Oh, H. S.; Wang, Y.; Kung, H. H. Appl. Catal. A: Gen. 2002, 232, 159. doi: 10.1016/S0926-860X(02)00092-3
17. [17]
  (17) Costello, C. K.; Yang, J. H.; Law, H. Y.; Wang, Y.; Lin, J. N.; Marks, L. D.; Kung, M. C.; Kung, H. H. Appl. Catal. A 2003, 243, 15. doi: 10.1016/S0926-860X(02)00533-1
18. [18]
  (18) Kung, H. H.; Kung, M. C.; Costello, C. K. J. Catal. 2003, 216, 425. doi: 10.1016/S0021-9517(02)00111-2
19. [19]
  (19) Sanchez-Castillo, M. A.; Couto, C.; Kim, W. B.; Dumesic, J. A. Angew. Chem. Int. Edit. 2004, 43, 1140.
20. [20]
  (20) Saavedra, J.; Doan, H. A.; Pursell, C. J.; Grabow, L. C.; Chandler, B. D. Science 2014, 345, 1599. doi: 10.1126/science.1256018
21. [21]
  (21) Anderson, J. R.; Shlmoyama, Y. In Proc. 5th Int. Congr. Catal.; Hightower, J. W. Ed.; Elsevier B. V.: North-Holland, Amsterdam, 1973; p 965.
22. [22]
  (22) Boudart, M.; Aldag, A. W.; Ptak, L. D.; Benson, J. E. J. Catal. 1968, 17, 35.
23. [23]
  (23) Boudart, M.; Aldag, A. W.; Benson, J. E.; Dougharty, N. A.; Harklns, G. C. J. Catal. 1966, 6, 92. doi: 10.1016/0021-9517(66)90113-8
24. [24]
  (24) Dorllng, T. A.; Moss, R. L. J. Catal. 1966, 5, 111. doi: 10.1016/S0021-9517(66)80130-6
25. [25]
  (25) Boudart. M. Adv. Catal. 1969, 20, 153.
26. [26]
  (26) Volta. J. C.; Portefaix, J. L. Appl. Catal. 1985, 18, 1. doi: 10.1016/S0166-9834(00)80296-1
27. [27]
  (27) Carberry, J. J. J. Catal. 1987, 107, 248. doi: 10.1016/0021-9517(87)90291-0
28. [28]
  (28) Carberry, J. J. J. Catal. 1988, 114, 277. doi: 10.1016/0021-9517(88)90031-0
29. [29]
  (29) Haruta, M.; Tsubota, S.; Kobayashi, T.; Kageyama, H.; Genet, M. J.; Delmon, B. J. Catal. 1993, 144, 175. doi: 10.1006/jcat.1993.1322
30. [30]
  (30) Bamwenda, G. R.; Tsubota, S.; Nakamura, T.; Haruta, M. Catal. Lett. 1997, 44, 83. doi: 10.1023/A:1018925008633
31. [31]
  (31) Valden, M.; Lai, X.; Goodman, D. W. Science 1998, 281, 1647. doi: 10.1126/science.281.5383.1647
32. [32]
  (32) Zanella, R.; Giorgio, S.; Shin, C. H.; Henry, C. R.; Louis, C. J. Catal. 2004, 222, 357. doi: 10.1016/j.jcat.2003.11.005
33. [33]
  (33) Tai, Y.; Yamaguchi, W.; Tajiri, K.; Kageyama, H. Appl. Catal. A: Gen. 2009, 364, 143. doi: 10.1016/j.apcata.2009.05.041
34. [34]
  (34) Laoufi, I.; Saint-Lager, M. C.; Lazzari, R.; Jupille, J.; Robach, O.; Garaudée, S.; Cabailh, G.; Dolle, P.; Cruguel, H.; Bailly, A. J. Phys. Chem. C 2011, 115, 4673. doi: 10.1021/jp1110554
35. [35]
  (35) Haruta, M. Chem. Rec. 2003, 3, 75.
36. [36]
  (36) Green, I. X.; Tang, W.; Neurock, M.; Yates, J. T., Jr. Science 2011, 333, 736. doi: 10.1126/science.1207272
37. [37]
  (37) Lopez, N.; Janssens, T. V. W.; Clausen, B. S.; Xu, Y.; Mavrikakis, M.; Bligaard, T.; Nørskov, J. K. J. Catal. 2004, 223, 232. doi: 10.1016/j.jcat.2004.01.001
38. [38]
  (38) Janssens, T. V. W.; Clausen, B. S.; Hvolbæk, B.; Falsig, H.; Christensen, C. H.; Bligaard, T.; Nørskov, J. K. Topic Catal. 2007, 44, 15. doi: 10.1007/s11244-007-0335-3
39. [39]
  (39) Falsig, H.; Hvolbæk, B.; Kristensen, I. S.; Jiang, T.; Bligaard, T.; Christensen, C. H.; Nørskov, J. K. Angew. Chem. Int. Edit. 2008, 47, 4835.
40. [40]
  (40) Maeda, Y.; Okumura, M.; Tsubota, S.; Kohyama, M.; Haruta, M. Appl. Surf. Sci. 2004, 222, 409. doi: 10.1016/j.apsusc.2003.09.007
41. [41]
  (41) Chen, M. S.; Goodman, D. W. Science 2004, 306, 252.
42. [42]
  (42) Herzing, A. A.; Kiely, C. J.; Carley, A. F.; Landon, P.; Hutchings, G. J. Science 2008, 321, 1331. doi: 10.1126/science.1159639
43. [43]
  (43) Liu, Y.; Jia, C. J.; Yamasaki, J.; Terasaki, O.; Schüth, F. Angew. Chem. Int. Edit. 2010, 49, 5771. doi: 10.1002/anie.v49:33
44. [44]
  (44) Haruta, M. Catal. Today 1997, 36, 153. doi: 10.1016/S0920-5861(96)00208-8
45. [45]
  (45) Qian, K.; Fang, J.; Huang, W. X.; He, B.; Jiang, Z. Q.; Ma, Y. S.; Wei, S. Q. J. Mol. Catal. A: Chem. 2010, 320, 97. doi: 10.1016/j.molcata.2010.01.010
46. [46]
  (46) Somorjai, G. A.; Carrazza, J. Ind. Eng. Chem. Fundam. 1986, 25, 63. doi: 10.1021/i100021a009
47. [47]
  (47) Parker, I. B.; Waugh, K. C.; Bowker, M. J. Catal. 1988, 114, 457. doi: 10.1016/0021-9517(88)90049-8
48. [48]
  (48) Bennett, C. O.; Che, M. J. Catal. 1989, 120, 293. doi: 10.1016/0021-9517(89)90270-4
49. [49]
  (49) Meyer, R.; Lemire, C.; Shaikhutdinov, S. K.; Freund, H. J. Gold Bull. 2004, 37, 72. doi: 10.1007/BF03215519
50. [50]
  (50) Chen, M. S.; Goodman, D. W. Accounts Chem. Res. 2006, 39, 739. doi: 10.1021/ar040309d
51. [51]
  (51) Min, B. K.; Friend, C. M. Chem. Rev. 2007, 107, 2709. doi: 10.1021/cr050954d
52. [52]
  (52) Risse, T.; Shaikhutdinov, S.; Nilius, N.; Sterrer, M.; Freund, H. J. Accounts Chem. Res. 2008, 41, 949. doi: 10.1021/ar800078m
53. [53]
  (53) Chen, M. S.; Goodman, D. W. Chem. Soc. Rev. 2008, 37, 1860. doi: 10.1039/b707318f
54. [54]
  (54) Gong, J. L.; Mullins, C. B. Accounts Chem. Res. 2009, 42, 1063. doi: 10.1021/ar8002706
55. [55]
  (55) Carabineiro, S. A. C.; Nieuwenhuys, B. E. Gold Bull. 2010, 43, 252. doi: 10.1007/BF03214995
56. [56]
  (56) Gong, J. L. Chem. Rev. 2012, 112, 2987. doi: 10.1021/cr200041p
57. [57]
  (57) Stowers, K. J.; Madix, R. J.; Friend, C. M. J. Catal. 2013, 308, 131. doi: 10.1016/j.jcat.2013.05.033
58. [58]
  (58) Outka, D. A.; Madix, R. J. Surf. Sci. 1987, 179, 351. doi: 10.1016/0039-6028(87)90062-8
59. [59]
  (59) Gottfried, J. M.; Schmidt, K. J.; Schroeder, S. L. M.; Christmann, K. Surf. Sci. 2003, 536, 206. doi: 10.1016/S0039-6028(03)00595-8
60. [60]
  (60) Meier, D. C.; Bukhtiyarov, V.; Goodman, D.W. J. Phys. Chem. B 2003, 107, 12668. doi: 10.1021/jp030499u
61. [61]
  (61) McElhiney, G.; Pritchard, J. Surf. Sci. 1976, 60, 397. doi: 10.1016/0039-6028(76)90324-1
62. [62]
  (62) Peters, K. F.; Steadman, P.; Isern, H.; Alvarez, J.; Ferrer, S. Surf. Sci. 2000, 467, 10. doi: 10.1016/S0039-6028(00)00777-9
63. [63]
  (63) Olsen, C. W.; Masel, R. I. Surf. Sci. 1988, 201, 444. doi: 10.1016/0039-6028(88)90496-7
64. [64]
  (64) Canning, N. D. S.; Outka, D.; Madix, R. J. Surf. Sci. 1984, 141, 240. doi: 10.1016/0039-6028(84)90209-7
65. [65]
  (65) Outka, D. A.; Madix, R. J. Surf. Sci. 1987, 179, 351. doi: 10.1016/0039-6028(87)90062-8
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