Citation: ZHU Shan-Hui, WANG Jian-Guo, FAN Wei-Bin. Advances in Catalytic Hydrogenolysis of Glycerol to Fine Chemicals[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 85-97. doi: 10.3866/PKU.WHXB201511061 shu

Advances in Catalytic Hydrogenolysis of Glycerol to Fine Chemicals

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China

Corresponding author: ZHU Shan-Hui, FAN Wei-Bin,
Received Date: 11 October 2015
Available Online: 6 November 2015
Fund Project: 国家自然科学基金(21403269,21273264) (21403269,21273264)国家重点基础研究发展规划项目(973)(2011CB201403) (973)(2011CB201403)中国科学院青年创新促进会(2015140)资助 (2015140)

With the rapid growth of the biodiesel industry, huge amounts of glycerol have been produced as a byproduct. Thus, it is highly desirable to convert low-cost glycerol into highly valuable chemicals, which can both expedite the development of the biodiesel process and save abundant petroleum resources. In this context, one of the most promising approaches is the catalytic hydrogenolysis of glycerol to synthesize 1,2- propanediol (1,2-PDO), 1,3-propanediol (1,3-PDO), ethylene glycol (EG), and propanols, because these target products have higher selectivity, economic value and potential for industrial application. In this paper, glycerol chemistry will be briefly introduced and then the reaction mechanisms, including dehydration-hydrogenation, dehydrogenation-dehydration-hydrogenation, direct hydrogenolysis, and ionic hydrogenation, will be discussed because of their importance for understanding the catalytic chemistry. Subsequently, the catalytic applications of glycerol hydrogenolysis to obtain 1,2-PDO, 1,3-PDO, EG, and propanols will be reviewed in detail based on various catalysts. In the end, we will provide a short summary and an outlook on the future prospects for glycerol hydrogenolysis.
- Glycerol,
- Hydrogenolysis,
- Propanediol,
- Biodiesel,
- Biomass
1. [1]
  (1) Rahmat, N.; Abdullah, A. Z.; Mohamed, A. R. Renew. Sust. Energ. Rev. 2010, 14, 987. doi: 10.1016/j.rser.2009.11.010
2. [2]
  (2) Bagheri, S.; Julkapli, N. M.; Yehye, W. A. Renew. Sust. Energ. Rev. 2015, 41, 113. doi: 10.1016/j.rser.2014.08.031
3. [3]
  (3) Katryniok, B.; Paul, S.; Paul, S. B.; Dumeignil, F. ACS Catal. 2013, 3, 1819. doi: 10.1021/cs400354p
4. [4]
  (4) Katryniok, B.; Paul, S.; Belliere-Baca, V.; Rey, P.; Dumeignil, F. Green Chem. 2010, 12, 2079. doi: 10.1039/c0gc00307g
5. [5]
  (5) Werpy, T.; Petersen, G. Top Value Added Chemicals from Biomass; U.S. Department of Energy: Springfield, 2004; Vol.1, pp 52–57.
6. [6]
  (6) Pagliaro, M.; Ciriminna, R.; Kimura, H.; Rossi, M.; Della Pina, C. Angew. Chem. Int. Edit. 2007, 46, 4434.
7. [7]
  (7) Zhou, C. H. C.; Beltramini, J. N.; Fan, Y. X.; Lu, G. Q. M. Chem. Soc. Rev. 2008, 37, 527. doi: 10.1039/B707343G
8. [8]
  (8) Ruppert, A. M.; Weinberg, K.; Palkovits, R. Angew. Chem. Int. Edit. 2012, 51, 2564. doi: 10.1002/anie.201105125
9. [9]
  (9) Corma, A.; Iborra, S.; Velty, A. Chem. Rev. 2007, 107, 2411. doi: 10.1021/cr050989d
10. [10]
  (10) Liu, S. S.; Sun, K. Q.; Xu, B. Q. ACS Catal. 2014, 4, 2226. doi: 10.1021/cs5005568
11. [11]
  (11) Liang, D.; Gao, J.; Sun, H.; Chen, P.; Hou, Z.; Zheng, X. Appl. Catal. B: Environ. 2011, 106, 423. doi: 10.1016/j.apcatb. 2011.05.050
12. [12]
  (12) Tsuji, A.; Rao, K. T. V.; Nishimura, S.; Takagaki, A.; Ebitani, K. ChemSusChem 2011, 4, 542. doi: 10.1002/cssc.201000359
13. [13]
  (13) Zhu, S.; Zhu, Y.; Hao, S.; Chen, L.; Zhang, B.; Li, Y. Catal. Lett. 2012, 142, 267. doi: 10.1007/s10562-011-0757-1
14. [14]
  (14) Nakagawa, Y.; Tomishige, K. Catal. Sci. Technol. 2011, 1, 179. doi: 10.1039/c0cy00054j
15. [15]
  (15) Chheda, J. N.; Huber, G. W.; Dumesic, J. A. Angew. Chem. Int. Edit. 2007, 46, 7164.
16. [16]
  (16) Tao, L. Z.; Yan, B.; Liang, Y.; Xu, B. Q. Green Chem. 2013, 15, 696. doi: 10.1039/c2gc16483c
17. [17]
  (17) Chai, S. H.; Tao, L. Z.; Yan, B.; Vedrine, J. C.; Xu, B. Q. RSC Adv. 2014, 4, 4619. doi: 10.1039/C3RA46511J
18. [18]
  (18) Pan, W. Y.; Huang, L.; Qin, F.; Zhuang, Y.; Li, X. M.; Ma, J. X.; Shen, W.; Xu, H. L. Acta Phys. -Chim. Sin. 2015, 31, 965. [潘文雅, 黄亮, 秦枫, 庄岩, 李雪梅, 马建学, 沈伟, 徐华龙. 物理化学学报, 2015, 31, 965.] doi: 10.3866/PKU.WHXB201503024
19. [19]
  (19) Ayoub, M.; Khayoon, M. S.; Abdullah, A. Z. Bioresour. Technol. 2012, 112, 308. doi: 10.1016/j.biortech.2012.02.103
20. [20]
  (20) Zhu, S.; Gao, X.; Dong, F.; Zhu, Y.; Zheng, H.; Li, Y. J. Catal. 2013, 306, 155. doi: 10.1016/j.jcat.2013.06.026
21. [21]
  (21) Zhu, S.; Zhu, Y.; Gao, X.; Mo, T.; Zhu, Y.; Li, Y. Bioresour. Technol. 2013, 130, 45. doi: 10.1016/j.biortech.2012.12.011
22. [22]
  (22) Behr, A.; Eilting, J.; Irawadi, K.; Leschinski, J.; Lindner, F. Green Chem. 2008, 10, 13. doi: 10.1039/B710561D
23. [23]
  (23) Gao, X.; Zhu, S.; Li, Y. Catal. Commun. 2015, 62, 48. doi: 10.1016/j.catcom.2015.01.007
24. [24]
  (24) Martin, A.; Armbruster, U.; Gandarias, I.; Arias, P. L. Eur. J. Lipid Sci. Technol. 2013, 115, 9. doi: 10.1002/ejlt.201200207
25. [25]
  (25) Kraus, G. A. Clean-Soil Air Water 2008, 36, 648. doi: 10.1002/clen.v36:8
26. [26]
  (26) Ten, D., Jeroen; Hanefeld, U. ChemSusChem 2011, 4, 1017. doi: 10.1002/cssc.201100162
27. [27]
  (27) Nakagawa, Y.; Tamura, M.; Tomishige, K. J. Mater. Chem. A 2014, 2, 6688. doi: 10.1039/c3ta15384c
28. [28]
  (28) Miyazawa, T.; Koso, S.; Kunimori, K.; Tomishige, K. Appl. Catal. A: Gen. 2007, 318, 244. doi: 10.1016/j.apcata. 2006.11.006
29. [29]
  (29) Chaminand, J.; Djakovitch, L.; Gallezot, P.; Marion, P.; Pinel, C.; Rosier, C. Green Chem. 2004, 6, 359. doi: 10.1039/b407378a
30. [30]
  (30) Gandarias, I.; Arias, P. L.; Requies, J.; Guemez, M. B.; Fierro, J. L. G. Appl. Catal. B: Environ. 2010, 97, 248. doi: 10.1016/j.apcatb.2010.04.008
31. [31]
  (31) Miyazawa, T.; Koso, S.; Kunimori, K.; Tomishige, K. Appl. Catal. A: Gen. 2007, 329, 30. doi: 10.1016/j.apcata. 2007.06.019
32. [32]
  (32) Zhu, S.; Gao, X.; Zhu, Y.; Zhu, Y.; Xiang, X.; Hu, C.; Li, Y. Appl. Catal. B: Environ. 2013, 140–141, 60.
33. [33]
  (33) Zhu, S.; Qiu, Y.; Zhu, Y.; Hao, S.; Zheng, H.; Li, Y. Catal. Today 2013, 212, 120. doi: 10.1016/j.cattod.2012.09.011
34. [34]
  (34) Zhu, S.; Gao, X.; Zhu, Y.; Li, Y. J. Mol. Catal. A: Chem. 2015, 398, 391. doi: 10.1016/j.molcata.2014.12.021
35. [35]
  (35) Zhu, S.; Gao, X.; Zhu, Y.; Cui, J.; Zheng, H.; Li, Y. Appl. Catal. B: Environ. 2014, 158–159, 391.
36. [36]
  (36) Falcone, D. D.; Hack, J. H.; Klyushin, A. Y.; Knop-Gericke, A.; Schlögl, R.; Davis, R. J. ACS Catal. 2015, 5679.
37. [37]
  (37) Zhu, S.; Gao, X.; Zhu, Y.; Fan, W.; Wang, J.; Li, Y. Catal. Sci. Technol. 2015, 5, 1169. doi: 10.1039/C4CY01148A
38. [38]
  (38) Zhu, S.; Gao, X.; Zhu, Y.; Zhu, Y.; Zheng, H.; Li, Y. J. Catal. 2013, 303, 70. doi: 10.1016/j.jcat.2013.03.018
39. [39]
  (39) Montassier, C.; Ménézo, J. C.; Hoang, L. C.; Renaud, C.; Barbier, J. J. Mol. Catal. 1991, 70, 99. doi: 10.1016/0304-5102(91)85008-P
40. [40]
  (40) Montassier, C.; Giraud, D.; Barbier, J. Stud. Surf. Sci. Catal.; 1988, 41, 165. doi: 10.1016/S0167-2991(09)60811-9
41. [41]
  (41) Maris, E. P.; Davis, R. J. J. Catal. 2007, 249, 328. doi: 10.1016/j.jcat.2007.05.008
42. [42]
  (42) Maris, E. P.; Ketchie, W. C.; Murayama, M.; Davis, R. J. J. Catal. 2007, 251, 281. doi: 10.1016/j.jcat.2007.08.007
43. [43]
  (43) Auneau, F.; Michel, C.; Delbecq, F.; Pinel, C.; Sautet, P. Chem. Eur. J. 2011, 17, 14288. doi: 10.1002/chem.v17.50
44. [44]
  (44) Nakagawa, Y.; Shinmi, Y.; Koso, S.; Tomishige, K. J. Catal. 2010, 272, 191. doi: 10.1016/j.jcat.2010.04.009
45. [45]
  (45) Amada, Y.; Shinmi, Y.; Koso, S.; Kubota, T.; Nakagawa, Y.; Tomishige, K. Appl. Catal. B: Environ. 2011, 105, 117.
46. [46]
  (46) Shinmi, Y.; Koso, S.; Kubota, T.; Nakagawa, Y.; Tomishige, K. Appl. Catal. B: Environ. 2010, 94, 318. doi: 10.1016/j.apcatb. 2009.11.021
47. [47]
  (47) Qin, L. Z.; Song, M. J.; Chen, C. L. Green Chem. 2010, 12, 1466. doi: 10.1039/c0gc00005a
48. [48]
  (48) Miyazawa, T.; Kusunoki, Y.; Kunimori, K.; Tomishige, K. J. Catal. 2006, 240, 213. doi: 10.1016/j.jcat.2006.03.023
49. [49]
  (49) Wang, S.; Yin, K.; Zhang, Y.; Liu, H. ACS Catal. 2013, 3, 2112. doi: 10.1021/cs400486z
50. [50]
  (50) Wu, Z.; Mao, Y.; Wang, X.; Zhang, M. Green Chem. 2011, 13, 1311. doi: 10.1039/c0gc00809e
51. [51]
  (51) Furikado, I.; Miyazawa, T.; Koso, S.; Shimao, A.; Kunimori, K.; Tomishige, K. Green Chem. 2007, 9, 582. doi: 10.1039/b614253b
52. [52]
  (52) Ma, L.; He, D. H. Catal. Today 2010, 149, 148. doi: 10.1016/j.cattod.2009.03.015
53. [53]
  (53) Shimao, A.; Koso, S.; Ueda, N.; Shinmi, Y.; Furikado, I.; Tomishige, K. Chem. Lett. 2009, 38, 540. doi: 10.1246/cl.2009.540
54. [54]
  (54) Ma, L.; He, D. Top. Catal. 2009, 52, 834. doi: 10.1007/s11244-009-9231-3
55. [55]
  (55) Deng, C.; Duan, X.; Zhou, J.; Chen, D.; Zhou, X.; Yuan, W. Catal. Today 2014, 234, 208. doi: 10.1016/j.cattod.2014.02.023
56. [56]
  (56) Deng, C.; Duan, X.; Zhou, J.; Zhou, X.; Yuan, W.; Scott, S. L. Catal. Sci. Technol. 2015, 5, 1540. doi: 10.1039/C4CY01285B
57. [57]
  (57) Oberhauser, W.; Evangelisti, C.; Jumde, R. P.; Psaro, R.; Vizza, F.; Bevilacqua, M.; Filippi, J.; Machado, B. F.; Serp, P. J. Catal. 2015, 325, 111. doi: 10.1016/j.jcat.2015.03.003
58. [58]
  (58) Li, B.; Wang, J.; Yuan, Y.; Ariga, H.; Takakusagi, S.; Asakura, K. ACS Catal. 2011, 1, 1521. doi: 10.1021/cs200386q
59. [59]
  (59) Ge, J.; Zeng, Z.; Liao, F.; Zheng, W.; Hong, X.; Tsang, S. C. E. Green Chem. 2013, 15, 2064. doi: 10.1039/c3gc40712h
60. [60]
  (60) Musolino, M. G.; Scarpino, L. A.; Mauriello, F.; Pietropaolo, R. Green Chem. 2009, 11, 1511. doi: 10.1039/b915745j
61. [61]
  (61) Musolino, M. G.; Scarpino, L. A.; Mauriello, F.; Pietropaolo, R. ChemSusChem 2011, 4, 1143. doi: 10.1002/cssc.201100063
62. [62]
  (62) Mauriello, F.; Ariga, H.; Musolino, M. G.; Pietropaolo, R.; Takakusagi, S.; Asakura, K. Appl. Catal. B: Environ. 2015, 166&ndashndash;167, 121.
63. [63]
  (63) Dasari, M. A.; Kiatsimkul, P. P.; Sutterlin, W. R.; Suppes, G. J. Appl. Catal. A: Gen. 2005, 281, 225. doi: 10.1016/j.apcata. 2004.11.033
64. [64]
  (64) Liang, C. H.; Ma, Z. Q.; Ding, L.; Qiu, J. S. Catal. Lett. 2009, 130, 169. doi: 10.1007/s10562-009-9844-y
65. [65]
  (65) Ma, Z.; Xiao, Z.; van Bokhoven, J. A.; Liang, C. J. Mater. Chem. 2010, 20, 755. doi: 10.1039/B917546F
66. [66]
  (66) Xiao, Z.; Ma, Z.; Wang, X.; Williams, C. T.; Liang, C. Ind. Eng. Chem. Res. 2011, 50, 2031. doi: 10.1021/ie101643b
67. [67]
  (67) Xiao, Z.; Li, C.; Xiu, J.; Wang, X.; Williams, C. T.; Liang, C. J. Mol. Catal. A: Chem. 2012, 365, 24. doi: 10.1016/j.molcata. 2012.08.004
68. [68]
  (68) Huang, Z. W.; Cui, F.; Kang, H. X.; Chen, J.; Zhang, X. Z.; Xia, C. G. Chem. Mater. 2008, 20, 5090. doi: 10.1021/cm8006233
69. [69]
  (69) Huang, Z.; Cui, F.; Xue, J.; Zuo, J.; Chen, J.; Xia, C. Catal. Today 2012, 183, 42. doi: 10.1016/j.cattod.2011.08.038
70. [70]
  (70) Toupance, T.; Kermarec, M.; Lambert, J. F.; Louis, C. J. Phys. Chem. B 2002, 106, 2277. doi: 10.1021/jp013153x
71. [71]
  (71) Grift, C. J. G.; Elberse, P. A.; Mulder, A.; Geus, J. W. Appl. Catal. 1990, 59, 275. doi: 10.1016/S0166-9834(00)82204-6
72. [72]
  (72) Wang, S. A.; Zhang, Y. C.; Liu, H. C. Chem. Asian J. 2010, 5, 1100. doi: 10.1002/asia.200900668
73. [73]
  (73) Wang, S.; Liu, H. C. Catal. Lett. 2007, 117, 62. doi: 10.1007/s10562-007-9106-9
74. [74]
  (74) Bienholz, A.; Schwab, F.; Claus, P. Green Chem. 2010, 12, 290. doi: 10.1039/B914523K
75. [75]
  (75) Bienholz, A.; Blume, R.; Knop-Gericke, A.; Girgsdies, F.; Behrens, M.; Claus, P. J. Phys. Chem. C 2010, 115, 999.
76. [76]
  (76) Yuan, Z.; Wang, L.; Wang, J.; Xia, S.; Chen, P.; Hou, Z.; Zheng, X. Appl. Catal. B: Environ. 2011, 101, 431. doi: 10.1016/j.apcatb.2010.10.013
77. [77]
  (77) Xia, S.; Nie, R.; Lu, X.; Wang, L.; Chen, P.; Hou, Z. J. Catal. 2012, 296, 1. doi: 10.1016/j.jcat.2012.08.007
78. [78]
  (78) Xia, S.; Yuan, Z.; Wang, L.; Chen, P.; Hou, Z. Appl. Catal. A: Gen. 2011, 403, 173. doi: 10.1016/j.apcata.2011.06.026
79. [79]
  (79) Xia, S.; Yuan, Z.; Wang, L.; Chen, P.; Hou, Z. Bioresour. Technol. 2012, 104, 814. doi: 10.1016/j.biortech.2011.11.031
80. [80]
  (80) Xia, S.; Zheng, L.; Ning, W.; Wang, L.; Chen, P.; Hou, Z. J. Mater. Chem. A 2013, 1, 11548. doi: 10.1039/c3ta12819a
81. [81]
  (81) Zhu, S.; Gao, X.; Zhu, Y.; Li, Y. Green Chem. 2016, doi: 10.1039/c5gc01766a.
82. [82]
  (82) Yuan, Z. L.; Wang, J. H.; Wang, L. N.; Xie, W. H.; Chen, P.; Hou, Z. Y.; Zheng, X. M. Bioresour. Technol. 2010, 101, 7088. doi: 10.1016/j.biortech.2010.04.016
83. [83]
  (83) Balaraju, M.; Jagadeeswaraiah, K.; Prasad, P. S. S.; Lingaiah, N. Catal. Sci. Technol. 2012, 2, 1967. doi: 10.1039/c2cy20059g
84. [84]
  (84) Mallesham, B.; Sudarsanam, P.; Reddy, B. V. S.; Reddy, B. M. Appl. Catal. B: Environ. 2016, 181, 47. doi: 10.1016/j.apcatb. 2015.07.037
85. [85]
  (85) Vila, F.; López Granados, M.; Ojeda, M.; Fierro, J. L. G.; Mariscal, R. Catal. Today 2012, 187, 122. doi: 10.1016/j.cattod.2011.10.037
86. [86]
  (86) Mane, R. B.; Rode, C. V. Green Chem. 2012, 14, 2780. doi: 10.1039/c2gc35661a
87. [87]
  (87) Sato, S.; Akiyama, M.; Inui, K.; Yokota, M. Chem. Lett. 2009, 38, 560. doi: 10.1246/cl.2009.560
88. [88]
  (88) Akiyama, M.; Sato, S.; Takahashi, R.; Inui, K.; Yokota, M. Appl. Catal. A: Gen. 2009, 371, 60. doi: 10.1016/j.apcata. 2009.09.029
89. [89]
  (89) Guo, L. Y.; Zhou, J. X.; Mao, J. B.; Guo, X. W.; Zhang, S. G. Appl. Catal. A: Gen. 2009, 367, 93. doi: 10.1016/j.apcata. 2009.07.040
90. [90]
  (90) Mane, R. B.; Hengne, A. M.; Ghalwadkar, A. A.; Vijayanand, S.; Mohite, P. H.; Potdar, H. S.; Rode, C. V. Catal. Lett. 2010, 135, 141. doi: 10.1007/s10562-010-0276-5
91. [91]
  (91) Panyad, S.; Jongpatiwut, S.; Sreethawong, T.; Rirksomboon, T.; Osuwan, S. Catal. Today 2011, 174, 59.
92. [92]
  (92) Feng, Y.; Yin, H.; Wang, A.; Shen, L.; Yu, L.; Jiang, T. Chem. Eng. J. 2011, 168, 403. doi: 10.1016/j.cej.2011.01.049
93. [93]
  (93) Huang, L.; Zhu, Y. L.; Zheng, H. Y.; Li, Y. W.; Zeng, Z. Y. J. Chem. Technol. Biotechnol. 2008, 83, 1670.
94. [94]
  (94) Tan, H.; Hedhill, M. N.; Wang, Y.; Zhang, J.; Li, K.; Sioud, S.; Al-Talla, Z. A.; Amad, M. H.; Zhan, T.; Tall, O. E.; Han, Y. Catal. Sci. Technol. 2013, 3, 3360. doi: 10.1039/c3cy00661a
95. [95]
  (95) Gandarias, I.; Requies, J.; Arias, P. L.; Armbruster, U.; Martin, A. J. Catal. 2012, 290, 79. doi: 10.1016/j.jcat.2012.03.004
96. [96]
  (96) Gandarias, I.; Arias, P. L.; Requies, J.; El Doukkali, M.; Güemez, M. B. J. Catal. 2011, 282, 237. doi: 10.1016/j.jcat.2011.06.020
97. [97]
  (97) Yu, W.; Xu, J.; Ma, H.; Chen, C.; Zhao, J.; Miao, H.; Song, Q. Catal. Commun. 2010, 11, 493. doi: 10.1016/j.catcom. 2009.12.009
98. [98]
  (98) Yu, W.; Zhao, J.; Ma, H.; Miao, H.; Song, Q.; Xu, J. Appl. Catal. A: Gen. 2010, 383, 73. doi: 10.1016/j.apcata. 2010.05.023
99. [99]
  (99) Nimlos, M. R.; Blanksby, S. J.; Qian, X.; Himmel, M. E.; Johnson, D. K. J. Phys. Chem. A 2006, 110, 6145.
100. [100]
  (100) Kurosaka, T.; Maruyama, H.; Naribayashi, I.; Sasaki, Y. Catal. Commun. 2008, 9, 1360. doi: 10.1016/j.catcom.2007.11.034
101. [101]
  (101) Gong, L.; Lu, Y.; Ding, Y.; Lin, R.; Li, J.; Dong, W.; Wang, T.; Chen, W. Appl. Catal. A: Gen. 2010, 390, 119. doi: 10.1016/j.apcata.2010.10.002
102. [102]
  (102) Nakagawa, Y.; Ning, X.; Amada, Y.; Tomishige, K. Appl. Catal. A: Gen. 2012, 433–434, 128.
103. [103]
  (103) Daniel, O. M.; DeLaRiva, A.; Kunkes, E. L.; Datye, A. K.; Dumesic, J. A.; Davis, R. J. ChemCatChem 2010, 2, 1107.
  doi: 10.1002/cctc.201000093
104. [104]
  (104) Dam, J.; Djanashvili, K.; Kapteijn, F.; Hanefeld, U. ChemCatChem 2013, 5, 497. doi: 10.1002/cctc.201200469
105. [105]
  (105) Arundhathi, R.; Mizugaki, T.; Mitsudome, T.; Jitsukawa, K.; Kaneda, K. ChemSusChem 2013, 6, 1345. doi: 10.1002/cssc.201300196
106. [106]
  (106) Wang, A.; Zhang, T. Accounts Chem. Res. 2013, 46, 1377.
  doi: 10.1021/ar3002156
107. [107]
  (107) Yin, A. Y.; Guo, X. Y.; Dai, W. L.; Fan, K. N. Green Chem. 2009, 11, 1514. doi: 10.1039/b913395j
108. [108]
  (108) Zhu, S.; Zhu, Y.; Hao, S.; Zheng, H.; Mo, T.; Li, Y. Green Chem. 2012, 14, 2607. doi: 10.1039/c2gc35564g
109. [109]
  (109) Priya, S. S.; Kumar, V. P.; Kantam, M. L.; Bhargava, S. K.; Periasamy, S.; Chary, K. V. R. Appl. Catal. A: Gen. 2015, 498, 88. doi: 10.1016/j.apcata.2015.03.025
110. [110]
  (110) Lin, X.; Lv, Y.; Xi, Y.; Qu, Y.; Phillips, D. L.; Liu, C. Energy Fuels 2014, 28, 3345. doi: 10.1021/ef500147k
1. [1]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
2. [2]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
3. [3]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
6. [6]
  Zhibei Qu , Changxin Wang , Lei Li , Jiaze Li , Jun Zhang . Organoid-on-a-Chip for Drug Screening and the Inherent Biochemistry Principles. University Chemistry, 2024, 39(7): 278-286. doi: 10.3866/PKU.DXHX202311039
7. [7]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
8. [8]
  Yang Liu , Peng Chen , Lei Liu . Chemistry “101 Plan”: Design and Construction of Chemical Biology Textbook. University Chemistry, 2024, 39(10): 45-51. doi: 10.12461/PKU.DXHX202407085
9. [9]
  Tianyu Feng , Guifang Jia , Peng Zou , Jun Huang , Zhanxia Lü , Zhen Gao , Chu Wang . Construction of the Chemistry Biology Experiment Course in the Chemistry “101 Program”. University Chemistry, 2024, 39(10): 69-77. doi: 10.12461/PKU.DXHX202409002
10. [10]
  Xinyi Hong , Tailing Xue , Zhou Xu , Enrong Xie , Mingkai Wu , Qingqing Wang , Lina Wu . Non-Site-Specific Fluorescent Labeling of Proteins as a Chemical Biology Experiment. University Chemistry, 2024, 39(4): 351-360. doi: 10.3866/PKU.DXHX202310010
11. [11]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
12. [12]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
13. [13]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
14. [14]
  Luhong Chen , Yan Zhang . Chem&Bio Interdisciplinary Graduates Training in Nanjing University Promoted by Chemistry and Biomedicine Innovation Center. University Chemistry, 2024, 39(6): 12-16. doi: 10.3866/PKU.DXHX202311089
15. [15]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
16. [16]
  Yuhang Jiang , Weijie Liu , Jiaqi Cai , Jiayue Chen , Yanping Ren , Pingping Wu , Liulin Yang . A Journey into the Science and Art of Sugar: “Dispersion of Light and Optical Rotation of Matter” Science Popularization Experiment. University Chemistry, 2024, 39(9): 288-294. doi: 10.12461/PKU.DXHX202401054
17. [17]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
18. [18]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
19. [19]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
20. [20]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(403)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142