Citation: FAN Ya-Xun, HAN Yu-Chun, WANG Yi-Lin. Effects of Molecular Structures on Aggregation Behavior of Gemini Surfactants in Aqueous Solutions[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 214-226. doi: 10.3866/PKU.WHXB201511022 shu

Effects of Molecular Structures on Aggregation Behavior of Gemini Surfactants in Aqueous Solutions

1.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Corresponding author: WANG Yi-Lin,
Received Date: 2 October 2015
Available Online: 2 November 2015
Fund Project: 国家自然科学基金(21361140353,21321063)资助项目 (21361140353,21321063)

Gemini surfactants consist of two amphiphilic moieties covalently connected by a spacer at the level of the head groups. Compared with the corresponding monomeric surfactants, gemini surfactants exhibit higher surface activity, possess unique structural variations, display special aggregate transitions, and form variable aggregate structures. Their aggregation ability and aggregate structures can be effectively adjusted by varying their molecular structures, which results in different intra- or intermolecular interactions. This short review is focused on the behavior of gemini surfactants in aqueous solutions reported in recent years, and summarizes the effects of different molecular structures, including spacers, hydrophobic chains, hydrophilic headgroups, counterions, and functional groups. The mechanisms and trends of the interactions in gemini surfactants are also presented.
- Gemini surfactant,
- Molecular structure,
- Aggregation behavior,
- Aggregate structure
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沈阳化工大学材料科学与工程学院沈阳 110142