Citation: FAN Ya-Xun, HAN Yu-Chun, WANG Yi-Lin. Effects of Molecular Structures on Aggregation Behavior of Gemini Surfactants in Aqueous Solutions[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 214-226. doi: 10.3866/PKU.WHXB201511022 shu

Effects of Molecular Structures on Aggregation Behavior of Gemini Surfactants in Aqueous Solutions

1.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Corresponding author: WANG Yi-Lin,
Received Date: 2 October 2015
Available Online: 2 November 2015
Fund Project: 国家自然科学基金(21361140353,21321063)资助项目 (21361140353,21321063)

Gemini surfactants consist of two amphiphilic moieties covalently connected by a spacer at the level of the head groups. Compared with the corresponding monomeric surfactants, gemini surfactants exhibit higher surface activity, possess unique structural variations, display special aggregate transitions, and form variable aggregate structures. Their aggregation ability and aggregate structures can be effectively adjusted by varying their molecular structures, which results in different intra- or intermolecular interactions. This short review is focused on the behavior of gemini surfactants in aqueous solutions reported in recent years, and summarizes the effects of different molecular structures, including spacers, hydrophobic chains, hydrophilic headgroups, counterions, and functional groups. The mechanisms and trends of the interactions in gemini surfactants are also presented.
- Gemini surfactant,
- Molecular structure,
- Aggregation behavior,
- Aggregate structure
1. [1]
  (1) Kirby, A. J.; Camilleri, P.; Engberts, J. B. F. N.; Feiters, M. C.; Nolte, R. J. M.; Söderman, O.; Bergsma, M.; Bell, P. C.; Fielden, M. L.; Rodríguez, C. L. G.; Guédat, P.; Kremer, A.; McGregor, C.; Perrin, C.; Ronsin G.; van Eijk, M. C. P. Angew. Chem. Int. Edit. 2003, 42, 1448. doi: 10.1002/anie.200201597
2. [2]
  (2) Bombelli, C.; Caracciolo, G.; Di Profio, P.; Diociaiuti, M.; Luciani, P.; Mancini, G.; Mazzuca, C.; Marra, M.; Molinari, A.; Monti, D.; Toccacieli, L.; Venanzi, M. J. Med. Chem. 2005, 48, 4882. doi: 10.1021/jm050182d
3. [3]
  (3) Xia, J.; Zana, R. Applications of Gemini Surfactants. In Gemini Surfactants: Synthesis, Interfacial and Solution Phase Behavior and Applications; Zana, R., Xia, J. Eds.; Marcel Dekker Inc.: New York, 2004; pp 301–321.
4. [4]
  (4) Macián, M.; Seguer, J.; Infante, M. R.; Selve, C.; Vinardell, M. P. Toxicology 1996, 106, 1. doi: 10.1016/0300-483X(95)03131-X
5. [5]
  (5) Borde, C.; Nardello, V.; Wattebled, L.; Laschewsky, A.; Aubry, J. M. J. Phys. Org. Chem. 2008, 21, 652. doi: 10.1002/poc.1344
6. [6]
  (6) Páhi, A. B.; Király, Z.; Mastalir, Á.; Dudás, J.; Puskás, S.; Vágó, Á. J. Phys. Chem. B 2008, 112, 15320. doi: 10.1021/jp806522h
7. [7]
  (7) Caillier, L.; de Givenchy, E. T.; Levy, R.; Vandenberghe, Y.; Geribaldi, S.; Guittard, F. J. Colloid Interface Sci. 2009, 332, 201. doi: 10.1016/j.jcis.2008.12.038
8. [8]
  (8) Dreja, M.; Tieke, B. Berichte der Bunse-Gesellschaft 1998, 102, 1705. doi: 10.1002/bbpc.v102:11
9. [9]
  (9) Sakai, K.; Nakajima, E.; Takamatsu, Y.; Sharma, S. C.; Torigoe, K.; Yoshimura, T.; Esumi, K.; Sakai, H.; Abe, M. J. Oleo Sci. 2008, 8, 423. doi: 10.5650/jos
10. [10]
  (10) Bunton, C. A.; Robinson, L.; Schaak, J.; Stam, M. F. J. Org. Chem. 1971, 36, 2346. doi: 10.1021/jo00815a033
11. [11]
  (11) Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7, 1072. doi: 10.1021/la00054a008
12. [12]
  (12) Alami, E.; Beinert, G.; Marie, P.; Zana, R. Langmuir 1993, 9, 1465. doi: 10.1021/la00030a006
13. [13]
  (13) Danino, D.; Talmon, Y.; Zana, R. Langmuir 1995, 11, 1448. doi: 10.1021/la00005a008
14. [14]
  (14) Frindi, M.; Michels, B.; Levy, H.; Zana, R. Langmuir 1994, 10, 1140. doi: 10.1021/la00016a028
15. [15]
  (15) Zana, R. Langmuir 1996, 12, 1208. doi: 10.1021/la950691q
16. [16]
  (16) Zana, R.; In, M.; Lévy, H.; Duportail, G. Langmuir 1997, 13, 5552. doi: 10.1021/la970369a
17. [17]
  (17) In, M.; Bec, V.; Aguerre-Chariol, O.; Zana, R. Langmuir 2000, 16, 141. doi: 10.1021/la990645g
18. [18]
  (18) Stathatos, E.; Lianos, P.; Rakotoaly, R. H.; Laschewsky A.; Zana, R. J. Colloid Interface Sci. 2000, 227, 476. doi: 10.1006/jcis.2000.6903
19. [19]
  (19) Grosmaire, L.; Chorro, C.; Chorro, M.; Partyka, S.; Zana, R. J. Colloid Interface Sci. 2001, 243, 525. doi: 10.1006/jcis.2001.7943
20. [20]
  (20) Paddon-Jones, G.; Regismond, S.; Kwetkat, K.; Zana, R. J. Colloid Interface Sci. 2001, 243, 496. doi: 10.1006/jcis.2001.7849
21. [21]
  (21) Zana, R. J. Colloid Interface Sci. 2002, 246, 182. doi: 10.1006/jcis.2001.7921
22. [22]
  (22) Menger, F. M.; Littau, C. A. J. Am. Chem. Soc. 1991, 113, 1451. doi: 10.1021/ja00004a077
23. [23]
  (23) Menger, F. M.; Migulin, V. A. J. Org. Chem. 1999, 64, 8916. doi: 10.1021/jo9912350
24. [24]
  (24) Menger, F. M.; Keiper, J. S.; Azov, V. Langmuir 2000, 16, 2062. doi: 10.1021/la9910576
25. [25]
  (25) Menger, F. M.; Keiper, J. S.; Mbadugha, B. N. A.; Caran, K. L.; Romsted, L. S. Langmuir 2000, 16, 9095. doi: 10.1021/la0003692
26. [26]
  (26) Menger, F. M.; Mbadugha, B. N. A. J. Am. Chem. Soc. 2001, 123, 875. doi: 10.1021/ja0033178
27. [27]
  (27) Seredyuk, V.; Alami, E.; Nydén, M.; Holmberg, K.; Peresypkin, A. V.; Menger, F. M. Langmuir 2001, 17, 5160. doi: 10.1021/la010182q
28. [28]
  (28) Song, L. D.; Rosen, M. J. Langmuir 1996, 12, 1149. doi: 10.1021/la950508t
29. [29]
  (29) Rosen, M. J.; Song, L. D. Langmuir 1996, 12, 4945. doi: 10.1021/la9602731
30. [30]
  (30) Pérez, L.; Pinazo, A.; Rosen, M. J.; Infante, M. R. Langmuir 1998, 14, 2307. doi: 10.1021/la971135u
31. [31]
  (31) Rosen, M. J.; Mathias, J. H.; Davenport, L. Langmuir 1999, 15, 7340. doi: 10.1021/la9904096
32. [32]
  (32) Mathias, J. H.; Rosen, M. J.; Davenport, L. Langmuir 2001, 17, 6148. doi: 10.1021/la010852s
33. [33]
  (33) Zhu, Y.; Masuyama, A.; Okahara, M. J. Am. Oil. Chem. Soc. 1990, 67, 459. doi: 10.1007/BF02638962
34. [34]
  (34) Zhu, Y.; Masuyama, A.; Okahara, M. J. Am. Oil. Chem. Soc. 1991, 68, 268. doi: 10.1007/BF02657622
35. [35]
  (35) Zhu, Y.; Masuyama, A.; Kirito, Y.; Okahara, M. J. Am. Oil. Chem. Soc. 1991, 68, 539. doi: 10.1007/BF02663831
36. [36]
  (36) Zhu, Y.; Masuyama, A.; Kirito, Y.; Okahara, M.; Rosen, M. J. Am. Oil. Chem. Soc. 1992, 69, 626. doi: 10.1007/BF02635800
37. [37]
  (37) Zhu, Y.; Masuyama, A.; Kobata, Y.; Nakatsuji, Y.; Okahara, M.; Rose, M. J. J. Colloid Interface Sci. 1993, 158, 40. doi: 10.1006/jcis.1993.1226
38. [38]
  (38) Oda, R.; Bourdieu, L.; Schmutz, M. J. Phys. Chem. B 1997, 101, 5913. doi: 10.1021/jp971545r
39. [39]
  (39) Oda, R.; Panizza, P.; Schmutz, M.; Lequeux, F. Langmuir 1997, 13, 6407. doi: 10.1021/la9621170
40. [40]
  (40) Oda, R.; Huc, I.; Candau, S. J. Chem. Commun. 1997, 2105. doi: 10.1039/A704069E
41. [41]
  (41) Oda, R.; Huc, I.; Homo, J. C.; Heinrich, B.; Schmutz, M.; Candau, S. J. Langmuir 1999, 15, 2384. doi: 10.1021/la9814889
42. [42]
  (42) Oda, R.; Huc, I.; Schmutz, M.; Candau, S. J.; MacKintosh, F. C. Nature 1999, 399, 566. doi: 10.1038/21154
43. [43]
  (43) Oda, R.; Huc, I.; Danino, D.; Talmon, Y. Langmuir 2000, 16, 9759. doi: 10.1021/la0008075
44. [44]
  (44) Duivenvoorde, F. L.; Feiters, M. C.; van der Gaast, S. J.; Engberts, J. B. F. N. Langmuir 1997, 13, 3737. doi: 10.1021/la9620420
45. [45]
  (45) Pestman, J. M.; Terpstra, K. R.; Stuart, M. C. A.; van Doren, H. A.; Brisson, A.; Kellogg, R. M.; Engberts, J. B. F. N. Langmuir 1997, 13, 6857. doi: 10.1021/la970681k
46. [46]
  (46) Buwalda, R. T.; Engberts, J. B. F. N. Langmuir 2001, 17, 1054. doi: 10.1021/la001277f
47. [47]
  (47) Johnsson, M.; Wagenaar, A.; Engberts, J. B. F. N. J. Am. Chem. Soc. 2002, 125, 757. doi: 10.1021/ja028195t
48. [48]
  (48) Johnsson, M.; Wagenaar, A.; Stuart, M. C. A.; Engberts, J. B. F. N. Langmuir 2003, 19, 4609. doi: 10.1021/la0343270
49. [49]
  (49) Rosen, M. J. Chemtech 1993, 3, 30.
50. [50]
  (50) Menger, F. M.; Keiper, J. S. Angew. Chem. Int. Edit. 2000, 39, 1906. doi: 10.3390/ijms14023140
51. [51]
  (51) Zana, R.; Xia, J. Gemini Surfactants: Synthesis, Interfacial and Solution Phase-Behavior and Applications; Marcel Dekker, Inc.: New York, 2004.
52. [52]
  (52) Alami, E.; Levy, H.; Zana, R.; Skoulios, A. Langmuir 1993, 9, 940. doi: 10.1021/la00028a011
53. [53]
  (53) De, S.; Aswal, V. K.; Goyal, P. S.; Bhattacharya, S. J. Phys. Chem. B 1998, 102, 6152. doi: 10.1021/jp980836c
54. [54]
  (54) Dreja, M.; Pyckhout-Hintzen, W.; Mays, H.; Tieke, B. Langmuir 1998, 15, 391. doi: 10.1021/la981354v
55. [55]
  (55) Wettig, S. D.; Verrall, R. E. J. Colloid Interface Sci. 2001, 235, 310. doi: 10.1006/jcis.2000.7348
56. [56]
  (56) Wettig, S. D.; Nowak, P.; Verrall, R. E. Langmuir 2002, 18, 5354. doi: 10.1021/la011782s
57. [57]
  (57) Zana, R. J. Colloid Interface Sci. 2002, 252, 259. doi: 10.1006/jcis.2002.8457
58. [58]
  (58) Sikirić, M.; Šmit, I.; Tušek-Božić, L.; Tomašić, V.; Pucić, I.; Primožič, I.; Filipović-Vinceković, N. Langmuir 2003, 19, 10044. doi: 10.1021/la034799e
59. [59]
  (59) Zana, R. J. Colloid Interface Sci. 2002, 248, 203. doi: 10.1006/jcis.2001.8104
60. [60]
  (60) Okano, T.; Egawa, N.; Fujiwara, M.; Fukuda, M. J. Am. Oil. Chem. Soc. 1996, 73, 31. doi: 10.1007/BF02523445
61. [61]
  (61) Wang, G.; Qu, W.; Du, Z.; Wang, W.; Li, Q. J. Phys. Chem. B 2013, 117, 3154. doi: 10.1021/jp310063d
62. [62]
  (62) Song, B.; Hu, Y.; Song, Y.; Zhao, J. J. Colloid Interface Sci. 2010, 341, 94. doi: 10.1016/j.jcis.2009.09.023
63. [63]
  (63) Xie, D.; Zhao, J. Langmuir 2013, 29, 545. doi: 10.1021/la304160s
64. [64]
  (64) Xie, D.; Zhao, J. Soft Matter 2013, 9, 6532. doi: 10.1039/c3sm50694k
65. [65]
  (65) Zhao, J.; Liu, F.; Xie, D. Colloid Polym. Sci. 2015, 293, 3545. doi: 10.1007/s00396-015-3668-7.
66. [66]
  (66) Hou, Y.; Han, Y.; Deng, M.; Xiang, J.; Wang, Y. L. Langmuir 2010, 26, 28. doi: 10.1021/la903672r
67. [67]
  (67) Fan, Y.; Hou, Y.; Xiang, J.; Yu, D.; Wu, C.; Tian, M.; Han, Y.; Wang, Y. L. Langmuir 2011, 27, 10570. doi: 10.1021/la202453c
68. [68]
  (68) Rosen, M. J.; Liu, L. J. Am. Oil. Chem. Soc. 1996, 73, 885. doi: 10.1007/BF02517990
69. [69]
  (69) Wang, X.; Wang, J.; Wang, Y. L.; Yan, H.; Li, P.; Thomas, R. K. Langmuir 2004, 20, 53. doi: 10.1021/la0351008
70. [70]
  (70) Li, Y.; Li, P.; Dong, C.; Wang, X.; Wang, Y. L.; Yan, H.; Thomas, R. K. Langmuir 2006, 22, 42. doi: 10.1021/la051544n
71. [71]
  (71) Zana, R. Gemini (Dimeric) Surfactants in Water: Solubility, cmc, Thermodynamics of Micellization, and Interaction with Water-Soluble Polymers. In Gemini Surfactants: Synthesis, Interfacial and Solution Phase-Behavior and Applications; Zana, R., Xia, J. Eds.; Marcel Dekker Inc.: New York, 2004; pp 108–139.
72. [72]
  (72) Li, Y.; Li, P.; Wang, J.; Wang, Y. L.; Yan, H.; Thomas, R. K. Langmuir 2005, 21, 6703. doi: 10.1021/la050343g
73. [73]
  (73) Huc, I.; Oda, R. Chem. Commun. 1999, 2025. doi: 10.1039/A906141J
74. [74]
  (74) Bai, G.; Wang, J.; Wang, Y. L.; Yan, H.; Thomas, R. K. J. Phys. Chem. B 2002, 106, 6614. doi: 10.1021/jp0143903
75. [75]
  (75) Wang, X.; Wang, J.; Wang, Y. L.; Ye, J.; Yan, H.; Thomas, R. K. J. Phys. Chem. B 2003, 107, 11428. doi: 10.1021/jp035198z
76. [76]
  (76) Fan, Y.; Li, Y.; Cao, M.; Wang, J.; Wang, Y. L.; Thomas, R. K. Langmuir 2007, 23, 11458. doi: 10.1021/la701493s
77. [77]
  (77) Devinsky, F.; Lacko, I. Tenside Surfact. Det. 1990, 27, 344.
78. [78]
  (78) Li, Y.; Li, P.; Wang, J.; Wang, Y. L.; Yan, H.; Dong, C.; Thomas, R. K. J. Colloid Interface Sci. 2005, 287, 333. doi: 10.1016/j.jcis.2005.01.108
79. [79]
  (79) Wang, G.; Zhang, D.; Du, Z.; Li, P. J. Ind. Eng. Chem. 2014, 20, 1247. doi: 10.1016/j.jiec.2013.09.032
80. [80]
  (80) Huang, X.; Han, Y.; Wang, Y.; Wang, Y. L. J. Phys. Chem. B 2007, 111, 12439. doi: 10.1021/jp0731046
81. [81]
  (81) Huang, X.; Wang, Y. L.; Dong, C.; Shen, H.; Thomas, R. K. J. Colloid Interface Sci. 2008, 325, 114. doi: 10.1016/j.jcis.2008.05.043
82. [82]
  (82) Ikeda, I. Synthesis of Gemini (Dimeric) and Related Surfactants. In Gemini Surfactants: Synthesis, Interfacial and Solution-Phase Behavior, and Applications; Zana, R., Xia, J. Eds.; Marcel Dekker Inc.: New York, 2004; pp 9–36.
83. [83]
  (83) Wang, Y.; Han, Y.; Huang, X.; Cao, M.; Wang, Y. L. J. Colloid Interface Sci. 2008, 319, 534. doi: 10.1016/j.jcis.2007.11.021
84. [84]
  (84) Wang, Y.; Huang, X.; Li, Y.; Wang, J.; Wang, Y. L. Colloids Surf. A: Physicochem. Eng. Asp. 2009, 333, 108. doi: 10.1016/j.colsurfa.2008.09.030
85. [85]
  (85) Huang, X.; Cao, M.; Wang, J.; Wang, Y. L. J. Phys. Chem. B 2006, 110, 19479. doi: 10.1021/jp0630121
86. [86]
  (86) Lu, T.; Han, F.; Mao, G.; Lin, G.; Huang, J.; Huang, X.; Wang, Y. L.; Fu, H. Langmuir 2007, 23, 2932. doi: 10.1021/la063435u
87. [87]
  (87) Li, B.; Zhang, Q.; Xia, Y.; Gao, Z. Colloids Surf. A: Physicochem. Eng. Asp. 2015, 470, 211. doi: 10.1016/j.colsurfa.2015.02.005
88. [88]
  (88) Huang, X.; Han, Y.; Wang, Y.; Cao, M.; Wang, Y. L. Colloids Surf. A: Physicochem. Eng. Asp. 2008, 325, 26. doi: 10.1016/j.colsurfa.2008.04.028
89. [89]
  (89) Bhadani, A.; Tani, M.; Endo, T.; Sakai, K.; Abe, M.; Sakai, H. Phys. Chem. Chem. Phys. 2015, 17, 19474. doi: 10.1039/C5CP02115D
90. [90]
  (90) Peresypkin, A. V.; Menger, F. M. Org. Lett. 1999, 1, 1347. doi: 10.1021/ol990205g
91. [91]
  (91) Menger, F. M.; Peresypkin, A. V. J. Am. Chem. Soc. 2001, 123, 5614. doi: 10.1021/ja003779l
92. [92]
  (92) Oda, R.; Huc, I.; Candau, S. J. Angew. Chem. Int. Edit. 1998, 37, 2689. doi: 10.1002/(SICI)1521-3773
93. [93]
  (93) Jiang, N.; Li, P.; Wang, Y. L.; Wang, J.; Yan, H.; Thomas, R. K. J. Phys. Chem. B 2004, 108, 15385. doi: 10.1021/jp0488057
94. [94]
  (94) Pei, X.; You, Y.; Zhao, J.; Deng, Y.; Li, E.; Li, Z. J. Colloid Interface Sci. 2010, 351, 457. doi: 10.1016/j.jcis.2010.07.076
95. [95]
  (95) Pei, X.; Zhao, J.; Ye, Y.; You, Y.; Wei, X. Soft Matter 2011, 7, 2953. doi: 10.1039/c0sm01071e
96. [96]
  (96) Tiwari, A. K.; Sonu; Sowmiya, M.; Saha, S. K. J. Mol. Liq. 2012, 167, 18. doi: 10.1016/j.molliq.2011.12.004
97. [97]
  (97) Tiwari, A. K.; Sonu; Saha, S. K. J. Phys. Chem. B 2014, 118, 3582. doi: 10.1021/jp4069703
98. [98]
  (98) He, C.; Han, Y.; Fan, Y.; Deng, M.; Wang, Y. L. Langmuir 2012, 28, 3391. doi: 10.1021/la2046146
99. [99]
  (99) Wang, M.; Han, Y.; Qiao, F.; Wang, Y. L. Soft Matter 2015, 11, 1517. doi: 10.1039/C4SM02668C
100. [100]
  (100) Chittimalla, C.; Zammut-Italiano, L.; Zuber, G.; Behr, J. P. J. Am. Chem. Soc. 2005, 127, 11436. doi: 10.1021/ja0522332
101. [101]
  (101) Eastoe, J.; Dominguez, M. S.; Wyatt, P.; Beeby, A.; Heenan, R. K. Langmuir 2002, 18, 7837. doi: 10.1021/la0257384
102. [102]
  (102) Takahashi, Y.; Fukuyasu, K.; Horiuchi, T.; Kondo, Y.; Stroeve, P. Langmuir 2014, 30, 41. doi: 10.1021/la4034782
103. [103]
  (103) Song, B.; Zhao, J.; Wang, B.; Jiang, R. Colloids Surf. A: Physicochem. Eng. Asp. 2009, 352, 24. doi: 10.1016/j.colsurfa.2009.09.044
104. [104]
  (104) Ahmad, R. K.; Faure, D.; Goddard, P.; Oda, R.; Bassani, D. M. Org. Biomol. Chem. 2009, 7, 3173. doi: 10.1039/b904390j
105. [105]
  (105) Yu, L.; Fang, B.; Jin, H.; Chen, J.; Li, K.; Tian, M.; Yang, M.; Jin, L. J. Dispersion Sci. Technol. 2015, 36, 1770. doi: 10.1080/01932691.2015.1015544
106. [106]
  (106) Kakizawa, Y.; Sakai, H.; Nishiyama, K.; Abe, M. Langmuir 1996, 12, 921. doi: 10.1021/la950600p
107. [107]
  (107) Kakizawa, Y.; Sakai, H.; Yamaguchi, A.; Kondo, Y.; Yoshino, N.; Abe, M. Langmuir 2001, 17, 8044. doi: 10.1021/la010772o
108. [108]
  (108) Gallardo, B. S.; Abbott, N. L. Langmuir 1997, 13, 203. doi: 10.1021/la960647q
109. [109]
  (109) Han, Y. C.; Fan, Y. X.; Wu, C. X.; Hou, Y. B.; Wang, Y. L. Sci. China Chem. 2015, 45, 327. [韩玉淳, 范雅珣, 伍春娴, 侯研博, 王毅琳. 中国科学: 化学, 2015, 45, 327.]
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沈阳化工大学材料科学与工程学院沈阳 110142