Citation: QI Qi, WANG Yu-Qiao, WANG Sha-Sha, QI Hao-Nan, WEI Tao, SUN Yue-Ming. Preparation of Reduced Graphene Oxide/TiO₂ Nanocomposites and Their Photocatalytic Properties[J]. Acta Physico-Chimica Sinica, ;2015, 31(12): 2332-2340. doi: 10.3866/PKU.WHXB201510202 shu

Preparation of Reduced Graphene Oxide/TiO₂ Nanocomposites and Their Photocatalytic Properties

QI Qi ¹ ,
WANG Yu-Qiao ^1,, ,
WANG Sha-Sha ¹ ,
QI Hao-Nan ¹ ,
WEI Tao ² ,
SUN Yue-Ming ^1,,

1.
1School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P. R. China;
2.
2 School of Pharmaceutical Sciences, Wenzhou Medical University, Wenzhou 325035, Zhejiang Province, P. R. China

Corresponding author: WANG Yu-Qiao, SUN Yue-Ming,
Received Date: 21 August 2015
Available Online: 20 October 2015
Fund Project: 国家自然科学基金(21173042) (21173042) 国家重点基础研究发展规划项目(973) (2013CB932902) (973) (2013CB932902) 中央高校基本科研业务费(2242014K10025,3207045419) (2242014K10025,3207045419) 江苏省自然科学基金(BK20141338) (BK20141338) 江苏省工业支撑计划(BE2013118) (BE2013118) 江苏省科技成果转化专项资金(BA2014069) (BA2014069) 东南大学校级研讨课基金(1107041501) (1107041501)江苏省普通高校研究生实践创新计划项目(SJLX150047)资助 (SJLX150047)

P25-reduced graphene oxide nanocomposites (RGO-P25) are prepared by using a facile one-step hydrothermal method. Their structure and photoelectrical properties are characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS). The degradation effect of different addition ratios of the RGO-P25 nanocomposite on the photocatalytic degradation of methylene blue (MB) is investigated under UV and visible illumination. Results show that graphene oxide can be reduced during the hydrothermal reaction and thus, a mixed high defect P25 particles and RGO sheet composite is formed by electrostatic attraction. Band gaps of nanocomposites decreased from 3.00 to 2.27 eV with an increase in the amount of the RGO content. The electrical conductivities of the nanocomposites enhanced with an increased RGO amount. Over 80% of the initial methylene blue dye is decomposed by 1% (w, mass fraction) RGO-P25 after 30 min under either visible light or ultraviolet light. Under UV light illumination, 63% (molar fraction) of the N3 dye, cis-Ru(H₂dcbpy)₂(NCS)₂ (H₂dcbpy = 4,4'- dicarboxy-2,2'-bipyridyl), is decomposed by the 1% RGO-P25 nanocomposite. Compared with the bare P25 (75% anatase; 25% rutile), the continual addition of RGO enhances the photocatalytic activity and gives rise to the more effective separation of photogenerated electron-hole pairs.
- Graphene,
- TiO₂,
- Nanocomposite,
- Hydrothermal method,
- Photocatalysis property
1. [1]
  (1) Li, D.; Chen, H. C.; Li, J. H.; Zhou, B. X.; Cai, W. M. Acta Phys. -Chim. Sin. 2011, 27 (9), 2153. [李迪, 陈红冲, 李金花, 周保学, 蔡伟民. 物理化学学报, 2011, 27 (9), 2153.] doi: 10.3866/PKU.WHXB20110910
2. [2]
  (2) Wu, Y. Q.; Lü, G. X.; Li, S. B. Acta Phys. -Chim. Sin. 2004, 20 (7), 755. [吴玉琪, 吕功煊, 李树本. 物理化学学报, 2004, 20 (7), 755.] doi: 10.3866/PKU.WHXB20040718
3. [3]
  (3) Chu, D. B.; Yin, X. J.; Feng, D. X.; Lin, H. S.; Tian, Z. W. Acta Phys. -Chim. Sin. 2006, 22 (10), 1238. [褚道葆, 尹晓娟, 冯德香, 林华水, 田昭武. 物理化学学报, 2006, 22 (10), 1238.] doi: 10.3866/PKU.WHXB20061013
4. [4]
  (4) Xu, P. C.; Liu, Y.; Wei, J. H.; Xiong, R.; Pan, C. X.; Shi, J. Acta Phys. -Chim. Sin. 2010, 26 (8), 2261. [许平昌, 柳阳, 魏建红, 熊锐, 潘春旭, 石兢. 物理化学学报, 2010, 26 (8), 2261.] doi: 10.3866/PKU.WHXB20100815
5. [5]
  (5) Wang, Y. Q.; Wang, P. P.; Lu, J.; Bai, Y. C.; Gu, Y. L.; Sun, Y. M. Acta Phys. -Chim. Sin. 2015, 31 (3), 448. [王育乔, 王盼盼, 卢静, 白一超, 顾云良, 孙岳明. 物理化学学报, 2015, 31 (3), 448.] doi: 10.3866/PKU.WHXB201412302
6. [6]
  (6) Yu, J. H.; Fan, M. G.; Li, B.; Dong, L. H.; Zhang, F. Y. Acta Phys. -Chim. Sin. 2015, 31 (3), 519. [于建华, 范闽光, 李斌, 董丽辉, 张飞跃. 物理化学学报, 2015, 31 (3), 519.] doi: 10.3866/PKU.WHXB201412291
7. [7]
  (7) Liang, Y.; Wang, H.; Casalongue, H. S.; Chen Z.; Dai, H. J. Nano Research 2010, 3 (10), 701. doi: 10.1007/s12274-010-0033-5
8. [8]
  (8) Chen, C.; Cai, W.; Long, M.; Zhou, B. X.; Wu, Y. H.; Wu, D. Y.; Feng, Y. J. ACS Nano 2010, 4 (11), 6425
9. [9]
  (9) Yoo, D. H.; Cuong, T. V.; Pham, V. H.; Chuang, J. S.; Hhoa, N. T.; Kim, E. J.; Hahn, S. H. Curr. Appl. Phys. 2011, 11 (3), 805. doi: 10.1016/j.cap.2010.11.077
10. [10]
  (10) Gan, Y. P.; Qin, H. P.; Huang, H.; Tao, X. Y.; Fang, J. W.; Zhang, W. Q. Acta Phys. -Chim. Sin. 2013, 29 (2), 403. [甘永平, 秦怀鹏, 黄辉, 陶新永, 方俊武, 张文魁. 物理化学学报, 2013, 29 (2), 403.] doi: 10.3866/PKU.WHXB201211022
11. [11]
  (11) Loh, K. P.; Bao, Q.; Eda, G., Chhowalla, M. Nat. Chem. 2010, No. 2, 1015.
12. [12]
  (12) Jahan, M.; Bao, Q.; Yang, J. X.; Loh, K. P. J. Am. Chem. Soc. 2010, 132 (41), 14487. doi: 10.1021/ja105089w
13. [13]
  (13) Sakthive, S.; Kisch, H. Angew. Chem. -Int. Edit. 2003, 42 (40), 4908.
14. [14]
  (14) Williams, G.; Seger, B.; Kamat, P. V. ACS Nano 2008, 2 (7), 1487. doi: 10.1021/nn800251f
15. [15]
  (15) Zhang, X. Y.; Li, H. P.; Cui, X. L.; Lin, Y. H. J. Mater. Chem. 2010, No. 20, 2801.
16. [16]
  (16) Dresselhaus, M. S.; Jorio, A.; Hofmann, M.; Dresselhaus, G.; Saito, R. Nano Lett. 2010, 10 (3), 751. doi: 10.1021/nl904286r
17. [17]
  (17) Zhang, W. X.; Cui, J. C.; Tao, C. A.; Wu, Y. G.; Li, Z. P.; Li, M.; Wen, Y. Q.; Li, G. T. Angew. Chem. -Int. Edit. 2009, 48 (32), 5864. doi: 10.1002/anie.v48:32
18. [18]
  (18) Lu, J.; Yang, J. X.; Wang, J.; Lim, A.; Wang, S.; Loh, K. P. ACS Nano 2009, 3 (8), 2367. doi: 10.1021/nn900546b
19. [19]
  (19) Zhou, Y.; Bao, Q.; Tang, L. A. L.; Zhong, Y. L.; Loh, K. P. Chem. Mat. 2009, 21 (13), 2950. doi: 10.1021/cm9006603
20. [20]
  (20) Zhang, H.; Lv, X. J.; Li, Y. M.; Li, J. H. ACS Nano 2010, 4 (1), 380. doi: 10.1021/nn901221k
21. [21]
  (21) Lv, X. J.; Fu, W. F.; Chang, H. X.; Zhao, H.; Cheng, J. S.; Zhang, G. J.; Song, Y.; Hu, C. Y.; Li, J. H. J. Math. Chem. 2012, 22 (4), 1539. doi: 10.1039/C1JM14502A
22. [22]
  (22) Zhang, Y. H.; Tang, Z. R.; Fu, X. Z.; Xu, Y. J. ACS Nano. 2010, 4 (12), 7303. doi: 10.1021/nn1024219
23. [23]
  (23) Akhavan, O.; Ghaderi, E. J. Phys. Chem. C 2009, 113 (47), 20214 doi: 10.1021/jp906325q
24. [24]
  (24) Cheng, P.; Yang, Z.; Wang, H.; Cheng, W.; Chen, M. X.; Shangguan, W. F.; Ding, G. F. Int. J. Hydrog. Energy 2012, 37 (3), 2224. doi: 10.1016/j.ijhydene.2011.11.004
25. [25]
  (25) Ren, L.; Qi, X.; Liu, Y. D.; Huang, Z. Y.; Wei, X. L.; Li, J.; Yang, L. W.; Zhong, J. X. J. Mater. Chem. 2012, 22 (23), 11765. doi: 10.1039/c2jm30457k
26. [26]
  (26) Long, M.; Cong, Y.; Li, X. K.; Cui, Z. W.; Dong, Z. J.; Yuan, G. M. Acta Phys. -Chim. Sin. 2013, 29 (6), 1344. [龙梅, 丛野, 李轩科, 崔正威, 董志军, 袁观明. 物理化学学报, 2013, 29 (6), 1344.] doi: 10.3866/PKU.WHXB201303263
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Preparation of Reduced Graphene Oxide/TiO2 Nanocomposites and Their Photocatalytic Properties

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通讯作者: 陈斌, bchen63@163.com

Preparation of Reduced Graphene Oxide/TiO₂ Nanocomposites and Their Photocatalytic Properties