Citation: CHANG Xiao-Xia, GONG Jin-Long. On the Importance of Surface Reactions on Semiconductor Photocatalysts for Solar Water Splitting[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 2-13. doi: 10.3866/PKU.WHXB201510192 shu

On the Importance of Surface Reactions on Semiconductor Photocatalysts for Solar Water Splitting

CHANG Xiao-Xia ,
GONG Jin-Long ^,

1.
Collaborative Innovation Center of Chemical Science and Engineering, Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China

Corresponding author: GONG Jin-Long,
Received Date: 1 September 2015
Available Online: 19 October 2015
Fund Project: 国家自然科学基金(U1463205,21222604,51302185,21525626)资助项目 (U1463205,21222604,51302185,21525626)

One of the most appealing ways to resolve the worldwide energy crisis and environmental pollution is by converting solar energy into storable chemical energy as hydrogen through solar water splitting. The redox reactions of photogenerated charge carriers occurring on the surface of photocatalysts during the process of solar water splitting are particularly complex. Owing to the high reaction overpotentials and sluggish desorption kinetics of gas products, surface reaction is the rate-determining step in the solar water splitting process. Therefore, a great deal of attention has been focused on this specific research area. The recent advances and prospects for future directions regarding the importance of surface reactions for solar water splitting are presented. The main strategies to enhance the surface water splitting reaction kinetics are summarized. The roles and classifications of surface cocatalysts, as well as the effects of passivating the surface states and coating surface protective layers, are discussed by integrating the principles of photocatalysis. Prospects for the future development of surface reaction research are also proposed.
- Photocatalytic water splitting,
- Surface reaction,
- Photocatalyst,
- Cocatalyst,
- Surface state,
- Protective layer
1. [1]
  (1) Osterloh, F. E. Chem. Soc. Rev. 2013, 42, 2294. doi: 10.1039/C2CS35266D
2. [2]
  (2) Das, D.; Veziroglu, T. N. Int. J. Hydrog. Energy 2001, 26, 13. doi: 10.1016/S0360-3199(00)00058-6
3. [3]
  (3) Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
4. [4]
  (4) Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/B800489G
5. [5]
  (5) Walter, M. G.; Warren, E. L.; McKone, J. R.; Boettcher, S. W.; Mi, Q.; Santori, E. A.; Lewis, N. S. Chem. Rev. 2010, 110, 6446. doi: 10.1021/cr1002326
6. [6]
  (6) Kubacka, A.; Fernández-García, M.; Colón, G. Chem. Rev. 2012, 112, 1555. doi: 10.1021/cr100454n
7. [7]
  (7) Ran, J. R.; Zhang, J.; Yu, J. G.; Jaroniec, M.; Qiao, S. Z. Chem. Soc. Rev. 2014, 43, 7787. doi: 10.1039/C3CS60425J
8. [8]
  (8) Valdés, Á.; Brillet, J.; Grätzel, M.; Gudmundsdóttir, H.; Hansen, H. A.; Jónsson, H.; Klüpfel, P.; Kroes, G.; Le Formal, F.; Man, I. C.; Martins, R. S.; Nörskov, J. K.; Rossmeisl, J.; Sivula, K.; Vojvodic, A.; Zäch, M. Phys. Chem. Chem. Phys. 2012, 14, 49. doi: 10.1039/C1CP23212F
9. [9]
  (9) Hope, G. A.; Bard, A. J. J. Phys. Chem. 1983, 87, 1979. doi: 10.1021/j100234a029
10. [10]
  (10) Wu, N. L.; Lee, M. S. Int. J. Hydrog. Energy 2004, 29, 1601. doi: 10.1016/j.ijhydene.2004.02.013
11. [11]
  (11) Tran, P. D.; Xi, L.; Batabyal, S. K.; Wong, L. H.; Barber, J.; Loo, J. S. C. Phys. Chem. Chem. Phys. 2012, 14, 11596. doi: 10.1039/c2cp41450c
12. [12]
  (12) Lin, K. Y.; Ma, B. J.; Su, W. G.; Liu, W. Y. Science & Technology Review 2013, 31, 103. [林克英, 马保军, 苏暐光, 刘万毅. 科技导报, 2013, 31, 103.]
13. [13]
  (13) Yamaguti, K.; Sato, S. J. Chem. Soc. Faraday Trans. 1 1985, 81, 1237. doi: 10.1039/f19858101237
14. [14]
  (14) Abe, R.; Sayama, K.; Arakawa, H. Chem. Phys. Lett. 2003, 371, 360. doi: 10.1016/S0009-2614(03)00252-5
15. [15]
  (15) Maeda, K.; Teramura, K.; Lu, D.; Saito, N.; Inoue, Y.; Domen, K. Angew. Chem. 2006, 118, 7970.
16. [16]
  (16) Li, Y. H.; Xing, J.; Chen, Z. J.; Li, Z.; Tian, F.; Zheng, L. R.; Wang, H. F.; Hu, P.; Zhao, H. J.; Yang, H. G. Nat. Commun. 2013, 4, 2500.
17. [17]
  (17) Zong, X.; Han, J.; Ma, G.; Yan, H.; Wu, G.; Li, C. J. Phys. Chem. C 2011, 115, 12202.
18. [18]
  (18) Sun, D. S.; Fu, B. Y.; Yang, W. L.; Wang, H. M.; Tian, M. K. Applied Chemical Industry 2015, 44, 720. [孙懂山, 付伯艳, 杨万亮, 王会敏, 田蒙奎. 应用化工, 2015, 44, 720.]
19. [19]
  (19) Xiang, Q.; Yu, J.; Jaroniec, M. J. Am. Chem. Soc. 2012, 134, 6575. doi: 10.1021/ja302846n
20. [20]
  (20) Artero, V.; Chavarot-Kerlidou, M.; Fontecave, M. Angew. Chem. Int. Edit. 2011, 50, 7238. doi: 10.1002/anie.v50.32
21. [21]
  (21) Sato, J.; Saito, N.; Yamada, Y.; Maeda, K.; Takata, T.; Kondo, J. N.; Hara, M.; Kobayashi, H.; Domen, K.; Inoue, Y. J. Am. Chem. Soc. 2005, 127, 4150. doi: 10.1021/ja042973v
22. [22]
  (22) Kanan, M. W.; Nocera, D. G. Science 2008, 321, 1072. doi: 10.1126/science.1162018
23. [23]
  (23) Zhong, D. K.; Choi, S.; Gamelin, D. R. J. Am. Chem. Soc. 2011, 133, 18370. doi: 10.1021/ja207348x
24. [24]
  (24) Liao, M.; Feng, J.; Luo, W.; Wang, Z.; Zhang, J.; Li, Z.; Yu, T.; Zou, Z. Adv. Funct. Mater. 2012, 22, 3066. doi: 10.1002/adfm.v22.14
25. [25]
  (25) Kim, T. W.; Choi, K. S. Science 2014, 343, 990. doi: 10.1126/science.1246913
26. [26]
  (26) Maeda, K.; Lu, D.; Domen, K. Chemistry 2013, 19, 4986. doi: 10.1002/chem.201300158
27. [27]
  (27) Lee, R.; Tran, P. D.; Pramana, S. S.; Chiam, S. Y.; Ren, Y.; Meng, S.; Wong, L. H.; Barber, J. Catal. Sci. Technol. 2013, 3, 1694. doi: 10.1039/c3cy00054k
28. [28]
  (28) Wang, D.; Hisatomi, T.; Takata, T.; Pan, C.; Katayama, M.; Kubota, J.; Domen, K. Angew. Chem. Int. Edit. 2013, 52, 11252. doi: 10.1002/anie.v52.43
29. [29]
  (29) Li, R.; Zhang, F.; Wang, D.; Yang, J.; Li, M.; Zhu, J.; Zhou, X.; Han, H.; Li, C. Nat. Commun. 2013, 4, 1432. doi: 10.1038/ncomms2401
30. [30]
  (30) Klahr, B.; Gimenez, S.; Fabregat-Santiago, F.; Hamann, T.; Bisquert, J. J. Am. Chem. Soc. 2012, 134, 4294. doi: 10.1021/ja210755h
31. [31]
  (31) Formal, F. L.; Tétreault, N.; Cornuz, M.; Moehl, T.; Grätzel, M.; Sivula, K. Chem. Sci. 2011, 2, 737. doi: 10.1039/C0SC00578A
32. [32]
  (32) Hwang, Y. J.; Hahn, C.; Liu, B.; Yang, P. ACS Nano 2012, 6, 5060. doi: 10.1021/nn300679d
33. [33]
  (33) Zandi, O.; Hamann, T. W. J. Phys. Chem. Lett. 2014, 5, 1522. doi: 10.1021/jz500535a
34. [34]
  (34) Lee, M. H.; Takei, K.; Zhang, J.; Kapadia, R.; Zheng, M.; Chen, Y. Z.; Nah, J.; Matthews, T. S.; Chueh, Y. L.; Ager, J. W.; Javey, A. Angew. Chem. Int. Edit. 2012, 51, 10760. doi: 10.1002/anie.v51.43
35. [35]
  (35) Wang, T.; Gong, J. Angew. Chem. Int. Edit. 2015, 54, 2. doi: 10.1002/anie.201410932
36. [36]
  (36) Hu, S.; Shaner, M. R.; Beardslee, J. A.; Lichterman, M.; Brunschwig, B. S.; Lewis, N. S. Science 2014, 344, 1005. doi: 10.1126/science.1251428
37. [37]
  (37) Li, C.; Wang, T.; Luo, Z.; Zhang, D.; Gong, J. Chem. Commun. 2015, 51, 7290. doi: 10.1039/C5CC01015B
38. [38]
  (38) Bard, A. J.; Fox, M. A. Accounts Chem. Res. 1995, 28, 141. doi: 10.1021/ar00051a007
39. [39]
  (39) Trotochaud, L.; Mills, T. J.; Boettcher, S. W. J. Phys. Chem. Lett. 2013, 4, 931. doi: 10.1021/jz4002604
40. [40]
  (40) Morales-Guio, C. G.; Mayer, M. T.; Yella, A.; Tilley, S. D.; Grätzel, M.; Hu, X. J. Am. Chem. Soc. 2015, 137, 9927. doi: 10.1021/jacs.5b05544
41. [41]
  (41) Zhong, M.; Hisatomi, T.; Kuang, Y.; Zhao, J.; Liu, M.; Iwase, A.; Jia, Q.; Nishiyama, H.; Minegishi, T.; Nakabayashi, M.; Shibata, N.; Niishiro, R.; Katayama, C.; Shibano, H.; Katayama, M.; Kudo, A.; Yamada, T.; Domen, K. J. Am. Chem. Soc. 2015, 137, 5053. doi: 10.1021/jacs.5b00256
42. [42]
  (42) Chang, X.; Wang, T.; Zhang, P.; Zhang, J.; Li, A.; Gong, J. J. Am. Chem. Soc. 2015, 137, 8356. doi: 10.1021/jacs.5b04186
43. [43]
  (43) Liu, J.; Liu, Y.; Liu, N.; Han, Y.; Zhang, X.; Huang, H.; Lifshitz, Y.; Lee, S. T.; Zhong, J.; Kang, Z. Science 2015, 347, 970. doi: 10.1126/science.aaa3145
44. [44]
  (44) Barroso, M.; Pendlebury, S. R.; Cowan, A. J.; Durrant, J. R. Chem. Sci. 2013, 4, 2724. doi: 10.1039/c3sc50496d
45. [45]
  (45) Werner, D.; Furube, A.; Okamoto, T.; Hashimoto, S. J. Phys. Chem. C 2011, 115, 8503. doi: 10.1021/jp112262u
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