Citation: HE Zhi-Qiao, TONG Li-Li, ZHANG Zhi-Peng, CHEN Jian-Meng, SONG Shuang. Ag/Ag₂WO₄ Plasmonic Catalyst for Photocatalytic Reduction of CO₂ under Visible Light[J]. Acta Physico-Chimica Sinica, ;2015, 31(12): 2341-2348. doi: 10.3866/PKU.WHXB201510151 shu

Ag/Ag₂WO₄ Plasmonic Catalyst for Photocatalytic Reduction of CO₂ under Visible Light

1.
College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Corresponding author: SONG Shuang,
Received Date: 31 July 2015
Available Online: 14 October 2015
Fund Project: 国家自然科学基金(21477117, 21177115) (21477117, 21177115)浙江省自然科学基金杰出青年项目(LR13B070002, LR14E080001)资助 (LR13B070002, LR14E080001)

The conversion of CO₂ into organic compounds is a promising method to mitigate global warming and assist in sustaining energy resources. A series of plasmonic photocatalysts, comprised of Ag supported on Ag₂WO₄ (Ag/Ag₂WO₄) with different crystalline phases, are fabricated by a facile ion-exchange method and subsequent reduction with hydrazine hydrate. The catalysts are characterized using X-ray diffraction (XRD) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), UV-Vis absorption spectroscopy, and Brunauer-Emmett-Teller analyses. Compared with Ag₂WO₄, the Ag/Ag₂WO₄ exhibits a markedly improved quantum yield (QY), energy returned on energy invested (EROEI), and turnover number (TON) for CO₂ reduction to CH₄ under visible-light irradiation. Among Ag/α-Ag₂WO₄, Ag/β-Ag₂WO₄, and Ag/γ-Ag₂WO₄ catalysts, the highest activity for CO₂ photoreduction to CH₄ is obtained for Ag/β-Ag₂WO₄ with an actual molar composition of 4% Ag and 96% Ag₂WO₄. Correspondingly the QY, EROEI, TON, and pseudo first-order rate constant are 0.145%, 0.067%, 9.61, and 1.96×10^-6 min^-1, respectively. Moreover, the plasmonic Ag/Ag₂WO₄ photocatalysts are stable after repeated reaction cycles under visible-light irradiation. It is proposed that the localized surface plasma resonance effect of surfacedeposited Ag contributed to the enhanced activities and stabilities of the Ag/Ag₂WO₄ photocatalysts.
- Photolysis,
- Carbon dioxide reduction,
- Methane,
- Silver tungstate,
- Localized surface plasma resonance
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Ag/Ag2WO4 Plasmonic Catalyst for Photocatalytic Reduction of CO2 under Visible Light

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Ag/Ag₂WO₄ Plasmonic Catalyst for Photocatalytic Reduction of CO₂ under Visible Light