Citation: LIU Zhen-Zhen, SHI Yong, LI Chun-Yan, ZHAO Qi-Dong, LI Xin-Yong. Electrochemical Synthesis of Cu₃(BTC)₂-MOF for Selective Catalytic Reduction of NO with NH₃[J]. Acta Physico-Chimica Sinica, ;2015, 31(12): 2366-2374. doi: 10.3866/PKU.WHXB201510141 shu

Electrochemical Synthesis of Cu₃(BTC)₂-MOF for Selective Catalytic Reduction of NO with NH₃

1.
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), State Key Laboratory of Fine Chemicals, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Corresponding author: SHI Yong,
Received Date: 14 July 2015
Available Online: 12 October 2015
Fund Project: 国家重点基础研究发展规划项目(973) (2011CB936002) (973) (2011CB936002) 国家自然科学基金(51178076) (51178076)中央高校基本科研业务费专项基金(DUT14LK17)资助 (DUT14LK17)

A Cu₃(BTC)₂ (copper(Ⅱ) benzene 1,3,5-tricarboxylate) metal organic framework (MOF) catalyst was successfully prepared through an electrochemical route and used for selective catalytic reduction of nitrogen oxide (NO_x) with NH₃ for the first time. After systematically optimizing the reaction conditions such as solvents, voltage, electrolyte concentration, and reaction time, pure Cu₃(BTC)₂ with high crystallinity was obtained in 97.2% yield. The physicochemical properties of the catalyst were determined using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Raman spectroscopy, in situ Fourier transform infrared (FTIR) spectroscopy, temperature-programmed desorption (TPD), and X-ray photoelectron spectroscopy (XPS). TGA results indicated that the framework was stable up to 310 ℃. The catalytic activity of Cu₃(BTC)₂ was evaluated using NO conversion as a model reaction. The Cu₃(BTC)₂ activation temperature significantly affected the catalytic activity. The Cu₃(BTC)₂ sample activated at 240 ℃ had the best catalytic activity and gave NO conversion of 90% at 220-280 ℃. A reaction mechanism was proposed based on the in situ FTIR spectroscopy results.
- Electrochemical synthesis,
- Cu₃(BTC)₂,
- Metal-organic framework,
- NO,
- NH₃-selective catalytic reduction
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沈阳化工大学材料科学与工程学院沈阳 110142

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Electrochemical Synthesis of Cu₃(BTC)₂-MOF for Selective Catalytic Reduction of NO with NH₃