Citation: WANG Xiao-Chen, WANG Ying-Ming, LIU Wei, BAI Ruo-Peng, LIU Yan-Fang, XIAO Li, LU Jun-Tao, ZHUANG Lin. Influence of 12-Crown-4 on Oxygen Electrode of Aprotic Li-O₂ Battery[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 343-348. doi: 10.3866/PKU.WHXB201510133 shu

Influence of 12-Crown-4 on Oxygen Electrode of Aprotic Li-O₂ Battery

1.
College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan University, Wuhan 430072, P. R. China

Corresponding author: XIAO Li,
Received Date: 12 August 2015
Available Online: 9 October 2015
Fund Project: 国家重点基础研究发展规划项目(973)(2012CB932800,2012CB215500) (973)(2012CB932800,2012CB215500)国家自然科学基金(21125312,21203142,21573167) (21125312,21203142,21573167)国家教育部博士点专项基金(20110141130002) (20110141130002)中央高校基本科研业务费专项资金(2014203020207)资助 (2014203020207)

One of the major challenges with Li-O₂ batteries is that the discharge product, Li₂O₂, blocks the gas pathway because of its poor solubility in aprotic solvents. In this work, 12-crown-4 ether was used as an additive to capture Li⁺, and its influence on the solubility of the discharge products of the oxygen electrode was investigated. Multiple electrochemical methods, including cyclic voltammetry and rotatingring disk electrode, were used. The results show that the addition of only 5% of 12-crown-4 ether significantly improves the stability of the oxygen reduction product O₂^-, and decreases the formation of solid Li₂O₂. We used a combination of the hard-soft-acid-base theory and ab initio calculations to explain these observations.
- Li-O₂ battery,
- Oxygen electrode,
- Crown ether,
- Hard-soft-acid-base theory
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Influence of 12-Crown-4 on Oxygen Electrode of Aprotic Li-O2 Battery

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通讯作者: 陈斌, bchen63@163.com

Influence of 12-Crown-4 on Oxygen Electrode of Aprotic Li-O₂ Battery