Citation: HAN Xiao-Mei, WU Yan-Bo, ZHAO Heng-Yan, BI Jun, WEI Bin-Bin. Preparation and Supercapacitor Properties of Carbon-Coated SnO₂ Hollow Fibers[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2220-2228. doi: 10.3866/PKU.WHXB201510131 shu

Preparation and Supercapacitor Properties of Carbon-Coated SnO₂ Hollow Fibers

1.
1 College of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, P. R. China;
2.
2 College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, P. R. China

Corresponding author: WU Yan-Bo,
Received Date: 27 April 2015
Available Online: 12 October 2015
Fund Project: 国家自然科学基金(21076028) (21076028)国家级大学生创新创业训练计划项目(201410150016)资助 (201410150016)

A new carbon-coated SnO₂ hollow fiber was successfully prepared by coaxial electrospinning, and its supercapacitor properties were well studied. The surface morphology and structure were examined using X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and the Brunauer-Emmett-Teller (BET) method. The results showed hollow fibers of average diameter 1 μm and carbon-coated SnO₂ particles of average size 3-15 nm uniformly distributed on the fiber shell. The surface area was 565 m²·g^-1. In a three-electrode system, the electrode achieved a respectable specific capacitance of 397.5 F·g^-1 at 0.25 A·g^-1, and the capacitance retained ratio was still 88% of the initial value after 3000 cycles at 1.0 A·g^-1. In the case of a symmetrical two-electrode system, the electrode achieved a specific capacitance of 162.0 F·g^-1 at 0.25 A·g^-1 current density, and the capacitance retained ratio was 84% of the initial value after 3000 cycles at 1.0 A·g^-1.
- Coaxial electrospinning,
- Carbon-coated nano-SnO₂,
- Hollow structure,
- Supercapacitor
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Preparation and Supercapacitor Properties of Carbon-Coated SnO₂ Hollow Fibers