Citation: LU Jian-Jian, YING Zong-Rong, LIU Xin-Dong, ZHAO Shuang-Sheng. Preparation of Cross-Linked Porous Carbon Nanofiber Networks by Electrospinning Method and Their Electrochemical Capacitive Behaviors[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2099-2108. doi: 10.3866/PKU.WHXB201510081 shu

Preparation of Cross-Linked Porous Carbon Nanofiber Networks by Electrospinning Method and Their Electrochemical Capacitive Behaviors

1.
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

Corresponding author: YING Zong-Rong,
Received Date: 19 May 2015
Available Online: 8 October 2015

Cross-linked porous carbon nanofiber networks were successfully prepared by electrospinning followed by preoxidation and carbonization using low-cost melamine and polyacrylonitrile (PAN) as precursors. The structures and morphologies of the nanofiber networks were investigated using Fourier-transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy, and N₂ adsorption/desorption. The carbon fibers had an interconnected nanofibrous morphology with a well-developed porous structure including micropores, mesopores and macropores, high-level nitrogen doping (up to 14.3%), and a small average diameter (about 89 nm). Without activation, the carbon nanofibers had a high specific capacitance of 194 F·g^-1 at a current density of 0.05 A·g^-1. Cycling experiments showed that the specific capacitance retained approximately 99.2% of the initial capacitance after 1000 cycles at a current density of 2 A·g^-1, indicating an excellent electrochemical performance.
- Melamine,
- Electrospinning,
- Carbon nanofiber,
- Cross-linked network,
- Supercapacitor
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