Citation: GAO Hai-Li, LI Xiao-Long, HE Wei, GUO Rui-Ting, CHAI Bo. One-Step Synthesis of Reduced Graphene Oxide Supported Pt Nanoparticles and Its Electrocatalytic Activity for Methanol Oxidation[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2117-2123. doi: 10.3866/PKU.WHXB201509181 shu

One-Step Synthesis of Reduced Graphene Oxide Supported Pt Nanoparticles and Its Electrocatalytic Activity for Methanol Oxidation

GAO Hai-Li ^1,2,, ,
LI Xiao-Long ¹ ,
HE Wei ¹ ,
GUO Rui-Ting ¹ ,
CHAI Bo ¹

1.
1 Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, P. R. China;
2.
2 Henan Provincial Key Laboratory of Surface Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450001, P. R. China

Corresponding author: GAO Hai-Li,
Received Date: 8 May 2015
Available Online: 16 September 2015
Fund Project: 国家自然科学基金(U1404201) (U1404201) 全国大学生创新创业训练计划(201310462099) (201310462099) 郑州轻工业学院青年骨干教师培养计划(2013XGGJS007) (2013XGGJS007) 河南省教育厅重点项目(13A530362) (13A530362)郑州轻工业学院博士基金(2011BSJJ020)资助项目 (2011BSJJ020)

In this study, graphite oxide was prepared from natural graphite powder using a modified Hummers method. Well-dispersed Pt nanoparticles were synthesized on reduced graphene oxide (RGO) via a simple one-step chemical reduction method in ethylene glycol (EG) by simultaneous reduction of graphene oxide (GO) and chloroplatinic acid. The microstructure, composition, and morphology of the synthesized materials were characterized with Fourier-transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM). It is shown that the GO was reduced to RGO, and the Pt nanoparticles with an average particle size of 2.3 nm were well dispersed on the surface of RGO. The catalytic performance of the catalysts for methanol oxidation was investigated by cyclic voltammetry and amperometric method, which indicated that Pt/RGO catalyst had higher electrocatalytic activity and stability for the oxidation of methanol than the Pt/C and Pt/CNT catalysts. The I_f/I_b of Pt/RGO reached 1.3, which was 2.2 and 1.9 times as high as those of Pt/C and Pt/CNT catalysts, respectively, revealing that Pt/RGO had high poisoning tolerance to the CO_ad intermediate species produced in the methanol oxidation reaction.
- Pt nanoparticle,
- Graphene,
- Chemical reduction,
- Methanol oxidation,
- Poisoning tolerance
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