Sb<SUB>2</SUB>S<SUB>3</SUB>纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能

引用本文: 郝彦忠, 郭志敏, 孙宝, 裴娟, 王尚鑫, 李英品. Sb₂S₃纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能[J]. 物理化学学报, 2015, 31(11): 2109-2116. doi: 10.3866/PKU.WHXB201509151 shu

Citation: HAO Yan-Zhong, GUO Zhi-Min, SUN Bao, PEI Juan, WANG Shang-Xin, LI Ying-Pin. Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles[J]. Acta Physico-Chimica Sinica, 2015, 31(11): 2109-2116. doi: 10.3866/PKU.WHXB201509151 shu

Sb₂S₃纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能

郝彦忠 ^{1,2,
,} ,
郭志敏 ^1, ,
孙宝 ^2, ,
裴娟 ^2, ,
王尚鑫 ^2, ,
李英品 ^2,

1.
1 河北科技大学化学与制药工程学院, 石家庄 050018;
2.
2 河北科技大学理学院, 石家庄 050018

通讯作者: 郝彦忠

基金项目:
国家自然科学基金(21173065) (21173065)

河北省自然科学基金(B2014208062, B2014208066, B2010000856)资助项目 (B2014208062, B2014208066, B2010000856)

摘要: 采用恒电位方法, 选择氯化钾和乙二胺(EDA)为添加剂, 在氧化铟锡(ITO)导电玻璃上制备了高度有序的ZnO纳米片阵列, 通过二次电沉积得到了ZnO纳米片上生长纳米棒的微纳分级结构. 利用化学浴沉积法在ZnO基底上沉积Sb₂S₃纳米粒子制备出了Sb₂S₃/ZnO纳米片壳核结构和Sb₂S₃/ZnO微纳分级壳核结构. 利用扫描电子显微镜(SEM)、X射线衍射(XRD)、紫外-可见(UV-Vis)吸收光谱、瞬态光电流等对其形貌、结构组成和光电化学性能进行了表征和分析. 结果表明, Sb₂S₃/ZnO纳米片上生长纳米棒分级壳核结构的光电流明显高于Sb₂S₃/ZnO纳米片壳核结构. 在Sb₂S₃/ZnO纳米片壳核结构和Sb₂S₃/ZnO微纳分级壳核结构的基础上旋涂一层P3HT薄膜形成P3HT/Sb₂S₃/ZnO复合结构, 以上述复合结构薄膜为光活性层组装成杂化太阳电池, 其中,P3HT/Sb₂S₃/ZnO分级壳核结构杂化太阳电池的能量转换效率最高, 达到了0.81%.

关键词:

English

Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles

1.
1 College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China;
2.
2 College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China

Corresponding author: 郝彦忠

Received Date: 08 April 2015
Fund Project:
国家自然科学基金(21173065)

河北省自然科学基金(B2014208062, B2014208066, B2010000856)资助项目

Abstract: We fabricated highly ordered ZnO nanosheet arrays on ITO substrates by adding KCl and ethylenediamine(EDA) through potentiostatic deposition, then produced a hierarchical structure of ZnO nanorods on the nanosheets by using secondary electrodeposition. Shell-core Sb₂S₃/ZnO nanostructures were prepared from ZnO nanosheets and ZnO nanorods on nanosheets by chemical bath deposition. The nanostructures were characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD), and their photoelectrochemical properties were investigated using ultraviolet-visible spectroscopy (UV-Vis) and photocurrent measurements. The shell-core Sb₂S₃/ZnO based on the hierarchical micronanostructure had higher photocurrent than did the shell-core Sb₂S₃/ZnO nanosheets. A hybrid solar cell was fabricated with a P3HT/Sb₂S₃/ZnO film as the photoactive layer. The P3HT/Sb₂S₃/ZnO hierarchical electrode exhibited an energy conversion efficiency as high as 0.81%.

Key words:

Sb₂S₃ nanoparticle
/ ZnO nanosheet
/ Hierarchical ZnO micro-nanostructure of nanorods on nanosheets
/ Shell-core structure
/ Hybrid solar cell

1. [1]
  (1) Ueno, N.; Yamamoto, A.; Uchida, Y.; Egashira, Y.; Nishiyama, N. Materials Letters 2012, 86, 65. doi: 10.1016/j.matlet. 2012.07.033(1) Ueno, N.; Yamamoto, A.; Uchida, Y.; Egashira, Y.; Nishiyama, N. Materials Letters 2012, 86, 65. doi: 10.1016/j.matlet. 2012.07.033
2. [2]
  (2) Jiao, S. H.; Xu, D. S.; Xu, L. F.; Zhang, X. G. Acta Phys. -Chim. Sin. 2012, 28 (10), 2436. [焦淑红, 徐东升, 许荔芬, 张晓光. 物理化学学报, 2012, 28 (10), 2436.] doi: 10.3866/PKU. WHXB201209145(2) Jiao, S. H.; Xu, D. S.; Xu, L. F.; Zhang, X. G. Acta Phys. -Chim. Sin. 2012, 28 (10), 2436. [焦淑红, 徐东升, 许荔芬, 张晓光. 物理化学学报, 2012, 28 (10), 2436.] doi: 10.3866/PKU. WHXB201209145
3. [3]
  (3) Xu, L. F.; Chen, Q. W.; Xu, D. S. J. Phys. Chem. C 2007, 111, 11560. doi: 10.1021/jp071536a(3) Xu, L. F.; Chen, Q. W.; Xu, D. S. J. Phys. Chem. C 2007, 111, 11560. doi: 10.1021/jp071536a
4. [4]
  (4) Shi, Y. T.; Zhu, C.; Wang, L.; Zhao, C. Y.; Li, W.; Fung, K. K.; Ma, T. L.; Hagfeldt, A.; Wang, N. Chem. Mater. 2013, 25, 1000. doi: 10.1021/cm400220q(4) Shi, Y. T.; Zhu, C.; Wang, L.; Zhao, C. Y.; Li, W.; Fung, K. K.; Ma, T. L.; Hagfeldt, A.; Wang, N. Chem. Mater. 2013, 25, 1000. doi: 10.1021/cm400220q
5. [5]
  (5) Hao, Y. Z.; Cui, Y. Journal of Functional Materials 2008, 1 (39), 83. [郝彦忠, 崔玥. 功能材料, 2008, 1 (39), 83.](5) Hao, Y. Z.; Cui, Y. Journal of Functional Materials 2008, 1 (39), 83. [郝彦忠, 崔玥. 功能材料, 2008, 1 (39), 83.]
6. [6]
  (6) Zheng, Y. Z.; Ding, H. Y.; Liu, Y.; Tao, X.; Cao, G. Z.; Chen, J. F. Electrochimica Acta 2014, 145, 116. doi: 10.1016/j. electacta.2014.08.077(6) Zheng, Y. Z.; Ding, H. Y.; Liu, Y.; Tao, X.; Cao, G. Z.; Chen, J. F. Electrochimica Acta 2014, 145, 116. doi: 10.1016/j. electacta.2014.08.077
7. [7]
  (7) Zhang, H.; Wu, P.; Han, C. B.; Sheng, W.; Cui, Q.; Qiu, Z. L.; Liu, C. W.; Gao, F.; Wang, M. T. Chemical Journal of Chinese University 2013, 34 (10), 2401. [张慧, 吴璠, 韩昌报, 沈薇, 崔奇, 邱泽亮, 刘长文, 高锋, 王命泰. 高等学校化学学报, 2013, 34 (10), 2401.](7) Zhang, H.; Wu, P.; Han, C. B.; Sheng, W.; Cui, Q.; Qiu, Z. L.; Liu, C. W.; Gao, F.; Wang, M. T. Chemical Journal of Chinese University 2013, 34 (10), 2401. [张慧, 吴璠, 韩昌报, 沈薇, 崔奇, 邱泽亮, 刘长文, 高锋, 王命泰. 高等学校化学学报, 2013, 34 (10), 2401.]
8. [8]
  (8) Asogwa, P.; Ezugwu, U. S. S.; Ezema, F. I. Chalcogenide Letters 2009, 6 (7), 287.(8) Asogwa, P.; Ezugwu, U. S. S.; Ezema, F. I. Chalcogenide Letters 2009, 6 (7), 287.
9. [9]
  (9) Aousgi, F. M.; Kanzari. Journal of Optoelectronics and Advanced Materials 2010, 12 (2), 227.(9) Aousgi, F. M.; Kanzari. Journal of Optoelectronics and Advanced Materials 2010, 12 (2), 227.
10. [10]
  (10) Boix, P. P.; Lee, Y. H.; Fabregat-Santiago, F.; Im, S. H.; Mora-Seró , I.; Bisquert, J.; Seok, S. I. Nano Lett. 2012, 6 (1), 873.(10) Boix, P. P.; Lee, Y. H.; Fabregat-Santiago, F.; Im, S. H.; Mora-Seró , I.; Bisquert, J.; Seok, S. I. Nano Lett. 2012, 6 (1), 873.
11. [11]
  (11) Im, S. H.; Kim, H. J.; Rhee, J. H.; Lim, C. S.; Seok, S. I. Energy & Environmental Science 2011, 4, 2799. doi: 10.1039/c0ee00741b(11) Im, S. H.; Kim, H. J.; Rhee, J. H.; Lim, C. S.; Seok, S. I. Energy & Environmental Science 2011, 4, 2799. doi: 10.1039/c0ee00741b
12. [12]
  (12) Zhu, G. Q.; Huang, X. J.; Feng, B.; Ge, B.; Bian, X. B. Chinese Journal of Inorganic Chemistry 2010, 26 (11), 2041. [朱刚强, 黄锡金, 冯波, 葛宝, 边小兵. 无机化学学报, 2010, 26 (11), 2041.](12) Zhu, G. Q.; Huang, X. J.; Feng, B.; Ge, B.; Bian, X. B. Chinese Journal of Inorganic Chemistry 2010, 26 (11), 2041. [朱刚强, 黄锡金, 冯波, 葛宝, 边小兵. 无机化学学报, 2010, 26 (11), 2041.]
13. [13]
  (13) Rajpure, K. Y.; Bhosale, C. H. Materials Chemistry and Physics 2000, 63 (3), 263. doi: 10.1016/S0254-0584(99)00233-3(13) Rajpure, K. Y.; Bhosale, C. H. Materials Chemistry and Physics 2000, 63 (3), 263. doi: 10.1016/S0254-0584(99)00233-3
14. [14]
  (14) Jonas, W.; Florian, A.; Thomas, B.; Lukas, S. M. J. Phys. Chem. C 2011, 115, 15081. doi: 10.1021/jp203600z(14) Jonas, W.; Florian, A.; Thomas, B.; Lukas, S. M. J. Phys. Chem. C 2011, 115, 15081. doi: 10.1021/jp203600z
15. [15]
  (15) Juliano, C. C.; Craig, A.; Feng, X. J.; Zhang, X. Y.; Sridhar, K.; Maria, V. B. Z.; Bao, N. Z. Chem. Commun. 2012, 48, 2818. doi: 10.1039/c2cc17573h(15) Juliano, C. C.; Craig, A.; Feng, X. J.; Zhang, X. Y.; Sridhar, K.; Maria, V. B. Z.; Bao, N. Z. Chem. Commun. 2012, 48, 2818. doi: 10.1039/c2cc17573h
16. [16]
  (16) Chang, J. A.; Rhee, J. H.; Im, S. H.; Lee, Y. H.; Kim, H. J.; Seok, S. I.; Nazeeruddin, M. K.; Graetzel, M. Nano Lett. 2010, 10, 2609. doi: 10.1021/nl101322h(16) Chang, J. A.; Rhee, J. H.; Im, S. H.; Lee, Y. H.; Kim, H. J.; Seok, S. I.; Nazeeruddin, M. K.; Graetzel, M. Nano Lett. 2010, 10, 2609. doi: 10.1021/nl101322h
17. [17]
  (17) Heo, J. H.; Im, S. H.; Kim, H. J.; Boix, P. P.; Lee, S. J.; Seok, S. I.; Mora-Seró , I.; Bisquert, J. J. Phys. Chem. C 2012, 116, 20717. doi: 10.1021/jp305150s(17) Heo, J. H.; Im, S. H.; Kim, H. J.; Boix, P. P.; Lee, S. J.; Seok, S. I.; Mora-Seró , I.; Bisquert, J. J. Phys. Chem. C 2012, 116, 20717. doi: 10.1021/jp305150s
18. [18]
  (18) Moon, S. J.; Itzhaik, Y.; Yum, J. H.; Shaik, M.; Zakeeruddin, G. H.; Graetzel, M. J. Phys. Chem. Lett. 2010, 1, 1524. doi: 10.1021/jz100308q(18) Moon, S. J.; Itzhaik, Y.; Yum, J. H.; Shaik, M.; Zakeeruddin, G. H.; Graetzel, M. J. Phys. Chem. Lett. 2010, 1, 1524. doi: 10.1021/jz100308q
19. [19]
  (19) Chang, J. A.; Im, S. H.; Lee, Y. H.; Kim, H. J.; Lim, C. S.; Lim, J. H.; Seok, S. I. Nano Lett. 2012, 12, 1863. doi: 10.1021/nl204224v(19) Chang, J. A.; Im, S. H.; Lee, Y. H.; Kim, H. J.; Lim, C. S.; Lim, J. H.; Seok, S. I. Nano Lett. 2012, 12, 1863. doi: 10.1021/nl204224v
20. [20]
  (20) Flannan, T. F.; O'Mahony.; Thierry, L.; Nestor, G.; Roberto, G.; Saif, A. H. Energy & Environmental Science 2012, 10, 1039.(20) Flannan, T. F.; O'Mahony.; Thierry, L.; Nestor, G.; Roberto, G.; Saif, A. H. Energy & Environmental Science 2012, 10, 1039.
21. [21]
  (21) Itzhaik, Y.; Niitsoo, O.; Page, M.; Hodes, G. J. Phys. Chem. C 2009, 113, 4254. doi: 10.1021/jp900302b(21) Itzhaik, Y.; Niitsoo, O.; Page, M.; Hodes, G. J. Phys. Chem. C 2009, 113, 4254. doi: 10.1021/jp900302b
22. [22]
  (22) Messina, S.; Nair, M. T. S.; Nair, P. K. Thin Solid Films 2009, 517, 2503.(22) Messina, S.; Nair, M. T. S.; Nair, P. K. Thin Solid Films 2009, 517, 2503.
23. [23]
  (23) Im, S. H.; Lim, C. S.; Chang, J. A.; Lee, Y. H.; Maiti, N.; Kim, H. J.; Nazeeruddin, M. K.; Graetzel, M.; Seok, S. I. Nano Lett. 2011, 11, 4789. doi: 10.1021/nl2026184(23) Im, S. H.; Lim, C. S.; Chang, J. A.; Lee, Y. H.; Maiti, N.; Kim, H. J.; Nazeeruddin, M. K.; Graetzel, M.; Seok, S. I. Nano Lett. 2011, 11, 4789. doi: 10.1021/nl2026184
24. [24]
  (24) Salunkhe, D. B.; Gargote, S. S.; Dubal, D. P.; Kim, W. B.; Sankapal, B. R. Chemical Physical Letters 2012, 554, 150. doi: 10.1016/j.cplett.2012.10.032(24) Salunkhe, D. B.; Gargote, S. S.; Dubal, D. P.; Kim, W. B.; Sankapal, B. R. Chemical Physical Letters 2012, 554, 150. doi: 10.1016/j.cplett.2012.10.032
25. [25]
  (25) Wei, Y. Fabrication of Nano-Composited-Material and Study of Photronic Property. M. S. Dissertation, Hebei University of Science and Technology, Shijiazhuang, 2009. [魏垚. 纳米复合材料的制备及其光电性能的研究[D]. 石家庄: 河北科技大学, 2009.](25) Wei, Y. Fabrication of Nano-Composited-Material and Study of Photronic Property. M. S. Dissertation, Hebei University of Science and Technology, Shijiazhuang, 2009. [魏垚. 纳米复合材料的制备及其光电性能的研究[D]. 石家庄: 河北科技大学, 2009.]
26. [26]
  (26) Hao, Y. Z.; Sun, B.; Luo, C.; Fan, L. X.; Pei, J.; Li, Y. P. Chemical Journal of Chinese University 2014, 35 (1), 127. [郝彦忠, 孙宝, 罗冲, 范龙雪, 裴娟, 李英品. 高等学校化学学报, 2014, 35 (1), 127.](26) Hao, Y. Z.; Sun, B.; Luo, C.; Fan, L. X.; Pei, J.; Li, Y. P. Chemical Journal of Chinese University 2014, 35 (1), 127. [郝彦忠, 孙宝, 罗冲, 范龙雪, 裴娟, 李英品. 高等学校化学学报, 2014, 35 (1), 127.]
27. [27]
  (27) Li, Y. B. Research on the Construction and Properties of Photoeletic ZnO/CuInS₂ and ZnO/CuInS₂/CuSCN Heterostructures. M. S. Dissertation, Tianjin Institute of Urban Construction, Tianjin, 2012. [李亚彬. ZnO/CuInS₂及ZnO/CuInS₂/CuSCN 异质结构的构筑及性能研究[D]. 天津: 天津城市建设学院, 2012.](27) Li, Y. B. Research on the Construction and Properties of Photoeletic ZnO/CuInS₂ and ZnO/CuInS₂/CuSCN Heterostructures. M. S. Dissertation, Tianjin Institute of Urban Construction, Tianjin, 2012. [李亚彬. ZnO/CuInS₂及ZnO/CuInS₂/CuSCN 异质结构的构筑及性能研究[D]. 天津: 天津城市建设学院, 2012.]
28. [28]
  (28) Hao, Y. Z. Photoelectrochemical Studies on Charge Transport Properties of Nanostructured Semiconductor Electrode and Its Photosensitization with Sensitizers. Ph. D. Dissertation, Peking University, Beijing, 1999. [郝彦忠. 半导体纳米结构电极及敏化层电荷传输特性的光电化学研究[D]. 北京: 北京大学, 1999.](28) Hao, Y. Z. Photoelectrochemical Studies on Charge Transport Properties of Nanostructured Semiconductor Electrode and Its Photosensitization with Sensitizers. Ph. D. Dissertation, Peking University, Beijing, 1999. [郝彦忠. 半导体纳米结构电极及敏化层电荷传输特性的光电化学研究[D]. 北京: 北京大学, 1999.]
29. [29]
  (29) Hao, Y. Z.; Fan, L. X.; Sun, B.; Sun, S.; Pei, J. Acta Chim. Sin. 2014, 72, 114. [郝彦忠, 范龙雪, 孙宝, 孙硕, 裴娟. 化学学报, 2014, 72, 114.] doi: 10.6023/A13080901(29) Hao, Y. Z.; Fan, L. X.; Sun, B.; Sun, S.; Pei, J. Acta Chim. Sin. 2014, 72, 114. [郝彦忠, 范龙雪, 孙宝, 孙硕, 裴娟. 化学学报, 2014, 72, 114.] doi: 10.6023/A13080901

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Sb₂S₃纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能

通讯作者: 郝彦忠

English

Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles

Corresponding author: 郝彦忠

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Sb2S3纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能

通讯作者: 郝彦忠

English

Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb2S3 Nanoparticles

Corresponding author: 郝彦忠

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