Sb<SUB>2</SUB>S<SUB>3</SUB>纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能

引用本文: 郝彦忠, 郭志敏, 孙宝, 裴娟, 王尚鑫, 李英品. Sb₂S₃纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能[J]. 物理化学学报, 2015, 31(11): 2109-2116. doi: 10.3866/PKU.WHXB201509151 shu

Citation: HAO Yan-Zhong, GUO Zhi-Min, SUN Bao, PEI Juan, WANG Shang-Xin, LI Ying-Pin. Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles[J]. Acta Physico-Chimica Sinica, 2015, 31(11): 2109-2116. doi: 10.3866/PKU.WHXB201509151 shu

Sb₂S₃纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能

郝彦忠 ^{1,2,
,} ,
郭志敏 ^1, ,
孙宝 ^2, ,
裴娟 ^2, ,
王尚鑫 ^2, ,
李英品 ^2,

1.
1 河北科技大学化学与制药工程学院, 石家庄 050018;
2.
2 河北科技大学理学院, 石家庄 050018

通讯作者: 郝彦忠

基金项目:
国家自然科学基金(21173065) (21173065)

河北省自然科学基金(B2014208062, B2014208066, B2010000856)资助项目 (B2014208062, B2014208066, B2010000856)

摘要: 采用恒电位方法, 选择氯化钾和乙二胺(EDA)为添加剂, 在氧化铟锡(ITO)导电玻璃上制备了高度有序的ZnO纳米片阵列, 通过二次电沉积得到了ZnO纳米片上生长纳米棒的微纳分级结构. 利用化学浴沉积法在ZnO基底上沉积Sb₂S₃纳米粒子制备出了Sb₂S₃/ZnO纳米片壳核结构和Sb₂S₃/ZnO微纳分级壳核结构. 利用扫描电子显微镜(SEM)、X射线衍射(XRD)、紫外-可见(UV-Vis)吸收光谱、瞬态光电流等对其形貌、结构组成和光电化学性能进行了表征和分析. 结果表明, Sb₂S₃/ZnO纳米片上生长纳米棒分级壳核结构的光电流明显高于Sb₂S₃/ZnO纳米片壳核结构. 在Sb₂S₃/ZnO纳米片壳核结构和Sb₂S₃/ZnO微纳分级壳核结构的基础上旋涂一层P3HT薄膜形成P3HT/Sb₂S₃/ZnO复合结构, 以上述复合结构薄膜为光活性层组装成杂化太阳电池, 其中,P3HT/Sb₂S₃/ZnO分级壳核结构杂化太阳电池的能量转换效率最高, 达到了0.81%.

关键词:

English

Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles

1.
1 College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China;
2.
2 College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, P. R. China

Corresponding author: 郝彦忠

Received Date: 08 April 2015
Fund Project:
国家自然科学基金(21173065)

河北省自然科学基金(B2014208062, B2014208066, B2010000856)资助项目

Abstract: We fabricated highly ordered ZnO nanosheet arrays on ITO substrates by adding KCl and ethylenediamine(EDA) through potentiostatic deposition, then produced a hierarchical structure of ZnO nanorods on the nanosheets by using secondary electrodeposition. Shell-core Sb₂S₃/ZnO nanostructures were prepared from ZnO nanosheets and ZnO nanorods on nanosheets by chemical bath deposition. The nanostructures were characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD), and their photoelectrochemical properties were investigated using ultraviolet-visible spectroscopy (UV-Vis) and photocurrent measurements. The shell-core Sb₂S₃/ZnO based on the hierarchical micronanostructure had higher photocurrent than did the shell-core Sb₂S₃/ZnO nanosheets. A hybrid solar cell was fabricated with a P3HT/Sb₂S₃/ZnO film as the photoactive layer. The P3HT/Sb₂S₃/ZnO hierarchical electrode exhibited an energy conversion efficiency as high as 0.81%.

Key words:

Sb₂S₃ nanoparticle
/ ZnO nanosheet
/ Hierarchical ZnO micro-nanostructure of nanorods on nanosheets
/ Shell-core structure
/ Hybrid solar cell

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Sb₂S₃纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能

通讯作者: 郝彦忠

English

Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles

Corresponding author: 郝彦忠

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Sb2S3纳米粒子修饰ZnO纳米片微纳分级结构的光电化学性能

通讯作者: 郝彦忠

English

Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb2S3 Nanoparticles

Corresponding author: 郝彦忠

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