Citation: LUO Liu-Xuan, SHEN Shui-Yun, ZHU Feng-Juan, ZHANG Jun-Liang. Formic Acid Oxidation by Pd Monolayers on Pt₃Ni Nanocubes[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 337-342. doi: 10.3866/PKU.WHXB201509144 shu

Formic Acid Oxidation by Pd Monolayers on Pt₃Ni Nanocubes

1.
Institute of Fuel Cells, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Corresponding author: ZHANG Jun-Liang,
Received Date: 24 August 2015
Available Online: 11 September 2015
Fund Project: 国家自然科学基金(21373135) (21373135)中国教育部科学基金(413064) (413064)高等学校学科创新引智计划(B13018)资助 (B13018)

We designed and synthesized carbon-supported cubic Pt₃Ni nanoparticles (NPs) with Pd monolayer shells (Pt₃Ni@Pd/C) by a two-step method: generally, CO-assisted preparation of cubic Pt₃Ni NPs, Pd monolayer deposition through underpotential deposition of a Cu monolayer, and displacement of Cu with Pd. The as-synthesized Pt₃Ni@Pd/C catalyst was characterized with inductively coupled plasma elemental analysis, X-ray diffraction, and transmission electron microscopy. Most Pt₃Ni NPs had a cubic nanostructure enclosed by {100} facets, on which the Pd monolayer shells were deposited epitaxially via electrodeposition, by which the Pd monolayers gained the crystallographic orientation of the {100} facets. We then used Pt₃Ni@Pd/C as an electrocatalyst for formic acid oxidation (FAO), comparing it with commercial Pd/C and the pristine Pt₃Ni/C catalysts. The Pt₃Ni@Pd/C exhibited superior electrocatalytic performance because of its monolayer structure and exposed Pd{100} facets. The noble-metal mass activity of the Pt₃Ni/C with the deposited Pd monolayer shell was 7.5 times greater than that of the Pt₃Ni/C catalyst alone. Moreover, the area-specific and Pd mass activities of Pt₃Ni@Pd/C were 2.5 and 8.3 times greater than those of the commercial Pd/C catalyst, respectively.
- Electrocatalyst,
- Formic acid oxidation,
- Palladium monolayer,
- Cubic structure,
- Core-shell structure
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沈阳化工大学材料科学与工程学院沈阳 110142

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Formic Acid Oxidation by Pd Monolayers on Pt₃Ni Nanocubes