Citation: YANG Jie-Yang, HUANG Zhang-Gen, HAN Xiao-Jin, JING Wen, ZENG Ze-Quan. Effect of Activated Carbon Pore Structure on the Adsorption of Pb(II) from Aqueous Solution[J]. Acta Physico-Chimica Sinica, ;2015, 31(10): 1956-1962. doi: 10.3866/PKU.WHXB201508212 shu

Effect of Activated Carbon Pore Structure on the Adsorption of Pb(II) from Aqueous Solution

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China

Received Date: 2 July 2015
Available Online: 21 August 2015

Pb(II) adsorption by three activated carbons (ACs) with similar surface chemistry but different pore distributions was investigated by isothermal adsorption experiments. The ACs were characterized by scanning electron microscopy (SEM) and N₂ adsorption at 77 K, while the micropore and mesopore size distributions were obtained from the density functional theory (DFT) and the Barrett-Joyner-Halenda (BJH) method, respectively. The specific surface area and total volume were ranked in order of AC1, AC2, and AC3. The AC2 sample had a uniform distribution of open pores on the surface and the highest saturating adsorption capacity, while the capacity of AC3, which had more aggregated pores, was similar to that of AC1, which had a concentrated distribution of open pores on the surface. A correlation analysis of pore structure and adsorption capacity indicated that pores with diameters in the range of 0.4-0.6 nm were favorable for Pb(II) adsorption, whereas pores with diameters in the ranges of 10.5-20.6 nm, 20.6-55.6 nm, and 5.2-10.5 nm had an adverse effect.
- Activated carbon,
- Pore structure,
- Adsorption,
- Pb(II)
1. [1]
  
  (1) Qin, H. F.; Liu, T. F.; Zhou, J. B. Chinese Journal of Environmental Engineering 2011, 5 (2), 306. [秦恒飞, 刘婷逢, 周建斌. 环境工程学报, 2011, 5 (2), 306.]
2. [2]
  (2) Netzer, A.; Hughes, D. E. Water Res. 1984, 18 (8), 927. doi: 10.1016/0043-1354(84)90241-0
3. [3]
  (3) Riverautrilla, J.; Ferrogarcia, M. A.; Min rance, M. D.; Bautistatoledo, I. J. Chem. Technol. Biotechnol. 1986, 36 (2), 47.
4. [4]
  (4) Ferrogarcia, M. A.; Riverautrilla, J.; Bautistatoledo, I.; Min rance, M. D. Carbon 1990, 28 (4), 545. doi: 10.1016/0008-6223(90)90051-Y
5. [5]
  (5) Cheng, J. G.; Subramanian, K. S.; Chakrabarti, C. L.; Guo, R. D.; Ma, X. J.; Lu, Y. J.; Pickering, W. F. Journal of Environmental Science and Health Part A: Toxic/Hazardous Substances & Environmental Engineering 1993, A28 (1), 51.
6. [6]
  (6) Li, K. L.; Wang, X. H. Bioresour. Technol. 2009, 100 (11), 2810. doi: 10.1016/j.biortech.2008.12.032
7. [7]
  (7) Sakthi, V.; Andal, N. M.; Rengaraj, S.; Sillanpaa, M. Desalin. Water Treat. 2010, 16 (1-3), 262. doi: 10.5004/dwt.2010.1074
8. [8]
  (8) Jiang, L. Q.; Zhang, R. J.; Deng, H. P. Environmental Science & Technology 2014, 37 (12), 178. [蒋立群, 张瑞金, 邓惠萍. 环境科学与技术, 2014, 37 (12), 178.]
9. [9]
  (9) Fan, M. X.; Tong, S. T.; Chen, D. D. Chinese Journal of Environmental Engineering 2014, 8 (12), 5197. [范明霞, 童仕唐, 陈东东. 环境工程学报, 2014, 8 (12), 5197.]
10. [10]
  (10) Cechinel, M. A. P.; de Souza, S.; de Souza, A. A. U. J. Cleaner Prod. 2014, 65, 342. doi: 10.1016/j.jclepro.2013.08.020
11. [11]
  (11) Machida, M.; Fotoohi, B.; Amamo, Y.; Mercier, L. Appl. Surf. Sci. 2012, 258 (19), 7389. doi: 10.1016/j.apsusc.2012.04.042
12. [12]
  (12) Mu, G. N.; Yang, C. F. Acta Phys. -Chim. Sin. 1995, 11 (2), 157. [木冠南, 杨春芬. 物理化学学报, 1995, 11 (2), 157.] doi: 10.3866/PKU.WHXB19950212
13. [13]
  (13) Boudrahem, F.; Soualah, A.; Aissani-Benissad, F. J. Chem. Eng. Data 2011, 56 (5), 1946. doi: 10.1021/je1009569
14. [14]
  (14) Momcilovic, M.; Purenovic, M.; Bojic, A.; Zarubica, A.; Randelovic, M. Desalination 2011, 276 (1-3), 53. doi: 10.1016/j.desal.2011.03.013
15. [15]
  (15) Ghaedi, M.; Mazaheri, H.; Khodadoust, S.; Hajati, S.; Purkait, M. K. Spectrochim. Acta Part A 2015, 135, 479.
16. [16]
  (16) Lopez-Ramon, M. V.; Stoeckli, F.; Moreno-Castilla, C.; Carrasco-Marin, F. Carbon 1999, 37 (8), 1216.
17. [17]
  (17) Zhao, Z. G. The Principle and Application of Adsorption; Chemical Industry Press: Beijing, 2005; pp 91-193. [赵振国. 吸附作用应用原理. 北京: 化学工业出版社, 2005: 91-193.]
18. [18]
  (18) Konndou, S.; Ishikawa, T.; Abe, I. Adsorption Science; Chemical Industry Press: Beijing, 2006; pp 115-137; translated by Li, G. X. [近藤精一, 石川达雄, 安部郁夫. 吸附科学. 李国希, 译. 北京: 化学工业出版社, 2006: 115-137.]
19. [19]
  (19) Garcia-Bordeje, E.; Lazaro, M. J.; Moliner, R.; Alvarez, P. M.; mez-Serrano, V.; Fierro, J. L. G. Carbon 2006, 44 (3), 410.
20. [20]
  (20) Liu, L. H.; Gu, M.; Xian, X. F. Chinese Journal of Environmental Engineering 2012, 6 (4), 1301. [刘立恒, 辜敏, 鲜学福. 环境工程学报, 2012, 6 (4), 1301.]
21. [21]
  (21) Zhang, Z.; Xu, M.; Wang, H.; Li, Z. Chem. Eng. J. 2010, 160 (2), 574.
22. [22]
  (22) Tseng, H. H.; Wey, M. Y. Chemosphere 2006, 62 (5), 764.
23. [23]
  (23) Wu, J. Study on the Activated Carbon Produced with Sewage Sludge. Master Dissertation. Shandong University, Jinan, 2006. [吴娟. 城市污水处理厂污泥制备活性炭的研究[D]. 济南: 山东大学, 2006.]
24. [24]
  (24) Karatepe, N.; Orbak, ?.; Yavuz, R.; Özyu?uran, A. Fuel 2008, 87 (15-16), 3214.
25. [25]
  (25) Macías-García, A.; Díaz-Díez, M. A.; Cuerda-Correa, E. M.; Olivares-Marín, M.; Gañan-Gómez, J. Appl. Surf. Sci. 2006, 252 (17), 5973.
26. [26]
  (26) Wu, M. B.; Zheng, J. T.; Qiu, J. S. Chem. Online 2011, 74 (7), 622. [吴明铂, 郑经堂, 邱介山. 化学通报, 2011, 74 (7), 622.]
27. [27]
  (27) Mohammadi, S. Z.; Karimi, M. A.; Afzali, D.; Mansouri, F. Desalination 2010, 262 (1-3), 88.
28. [28]
  (28) Ahmad, F.; Daud, W.; Ahmad, M. A.; Radzi, R. Chem. Eng. Res. Des. 2013, 91 (6), 1033.
29. [29]
  (29) Weng, S. F. Fourier Transform Infrared Spectrometry; Chemical Industry Press: Beijing, 2010; pp 291-358. [翁诗甫. 傅里叶变换红外光谱分析. 北京: 化学工业出版社, 2010: 291-358.]
30. [30]
  (30) Li, L. Q.; Song, J. F.; Yao, X. L.; Huang, G. J.; Liu, Z.; Tang, L. J. Cent. South Univ. 2012, 19 (12), 3532.
31. [31]
  (31) Li, X. Q.; Lan, L. J. Jiangsu Agric. Sci. 2013, 41 (6), 288. [李晓强, 兰丽娟. 江苏农业科学, 2013, 41 (6), 288.]
32. [32]
  (32) Tang, J.; Zeng, Q.; Chen, Z. D.; Huang, X. Q. Acta Phys. -Chim. Sin. 2012, 28 (5), 1269. [汤儆, 曾峤, 陈振东, 黄向前. 物理化学学报, 2012, 28 (5), 1269.] doi:10.3866/PKU.WHXB201202242
33. [33]
  (33) Chen, Y. J.; Hu, Z. H.; Wang, X. J.; Zhao, G. H.; Liu, Y. F.; Liu, W. Acta Phys. -Chim.Sin. 2008, 24 (9), 1592. [陈玉娟, 胡中华, 王晓静, 赵国华, 刘亚菲, 刘巍. 物理化学学报, 2008, 24 (9), 1592.] doi: 10.3866/PKU.WHXB20080911
34. [34]
  (34) Chen, Q. J.; Wang, Z.; Long, D. H.; Liu, X. J.; Zhan, L.; Liang, X. Y.; Qiao, W. M.; Ling, L. C. Ind. Eng. Chem. Res. 2010, 49 (7), 3153.
35. [35]
  (35) Gun'ko, V. M.; Palijczuk, D.; Leboda, R.; Skubiszewska-Zieba, J.; Smigielski, R.; Zietek, S. J. Colloid Interface Sci. 2006, 294 (1), 62.
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