Citation: NIE Long-Hui, TAN Qiao, ZHU Wei, WEI Qi, LIN Zhi-Kui. Fast Adsorption Removal of Con Red on Hierarchically Porous γ-Al₂O₃ Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1815-1822. doi: 10.3866/PKU.WHXB201507201 shu

Fast Adsorption Removal of Con Red on Hierarchically Porous γ-Al₂O₃ Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method

NIE Long-Hui ^1,2, ,
TAN Qiao ¹ ,
ZHU Wei ¹ ,
WEI Qi ¹ ,
LIN Zhi-Kui ¹

1.
1 School of Chemistry and Chemical Engineering, Hubei University of Technology, Wuhan 430068, P. R. China;
2 The Synergistic Innovation Center of Catalysis Materials of Hubei Province, Wuhan 430068, P. R. China

Received Date: 3 April 2015
Available Online: 20 July 2015
Fund Project: 国家自然科学基金(51572074) (51572074) 湖北省自然科学基金(2011CDB079) (2011CDB079) 湖北省大学生创新训练项目(201310500017) (201310500017)中南民族大学催化与材料科学重点实验室开放基金(CHCL12003)资助 (CHCL12003)

Hierarchical nanostructured γ-Al₂O₃ hollow microspheres were synthesized from KAl(SO₄)₂ and urea precursors by the microwave-assisted hydrothermal (MAH) method at 180 ℃ for 20 min followed by calcination at 600 ℃ for 2 h. The as-prepared sample was used to remove the organic dye Con red (CR) from aqueous solution. The results showed that the obtained γ-Al₂O₃ hollow microspheres are about 0.8-1.0 μm in diameter with a shell thickness of approximately 200 nm. The γ-Al₂O₃ hollow microspheres have a high surface area of 243 m²·g^-1 and a hierarchical meso-macroporous structure, which is beneficial for mass transfer in liquid processes. Therefore, the prepared γ-Al₂O₃ hollow microspheres exhibit faster adsorption and enhanced adsorption performance for CR than particles prepared by the hydrothermal method and commercial γ-Al₂O₃. The adsorption kinetic data follow the pseudo-second-order equation and the equilibrium data fit well to the Langmuir model. The maximum adsorption capacity (q_max) of the obtained γ-Al₂O₃ hollow microspheres calculated by the Langmuir model is up to 515.4 mg·g^-1 at 25 ℃. The γ-Al₂O₃ hollow microspheres prepared by the microwave-assisted hydrotherm method show promise as an adsorbent for environmental applications due to their hierarchical porous structure, high surface area, large pore volume, and adsorption capacity.
- Hierarchically porous material,
- γ-Al₂O₃,
- Con red,
- Adsorption kinetics
1. [1]
  
  (1) Jalil, A. A.; Triwahyono, S.; Adam, S. H.; Rahim, N. D.; Aziz, M. A.; Hairom, N. H.; Razali, N. A.; Abidin, M. A.; Mohamadiah, M. K. J. Hazard. Mater. 2010, 181, 755. doi: 10.1016/j.jhazmat.2010.05.078
2. [2]
  (2) Vimonsesa, V.; Lei, S.; Ji, B.; Chowd, C. W. K.; Saint, C. Chem. Eng. J. 2009, 148, 354. doi: 10.1016/j.cej.2008.09.009
3. [3]
  (3) Asencios, Y. J. O.; Sun-Kou, M. R. Appl. Surf. Sci. 2012, 258, 10002. doi: 10.1016/j.apsusc.2012.06.063
4. [4]
  (4) Cai, W. Q.; Yu, J. G.; Jaroniec, M. J. Mater. Chem. 2010, 20, 4587. doi: 10.1039/b924366f
5. [5]
  (5) Xu, J. S.; Zhu, Y. J. J. Colloid Interface Sci. 2012, 385, 58. doi: 10.1016/j.jcis.2012.06.082
6. [6]
  (6) Fei, J. B.; Cui, Y.; Zhao, J.; Gao, L.; Yang, Y.; Li, J. B. J. Mater. Chem. 2011, 21, 11742. doi: 10.1039/c1jm11950h
7. [7]
  (7) Yu, C.; Dong, X.; Guo, L.; Li, J.; Qin, F.; Zhang, L. Z.; Shi, J.; Yan, D. J. Phys. Chem. C 2008, 112, 13378. doi: 10.1021/jp8044466
8. [8]
  (8) Ai, L.; Zeng, Y.; Jiang, J. Chem. Eng. J. 2014, 235, 331. doi: 10.1016/j.cej.2013.09.046
9. [9]
  (9) Hu, J.; Song, Z.; Chen, L.; Yang, H.; Li, J.; Richards, R. J. Chem. Eng. Data 2010, 55, 3742. doi: 10.1021/je100274e
10. [10]
  (10) Yang, Z.; Wei, J.; Yang, H.; Liu, L.; Liang, H.; Yang, Y. Eur. J. Inorg. Chem. 2010, 5, 3354.
11. [11]
  (11) Ai, L.; Zeng, Y. Chem. Eng. J. 2013, 215-216, 269.
12. [12]
  (12) Fei, J.; Cui, Y.; Yan, X.; Qi, W.; Yang, Y.; Wang, K.; He, Q.; Li, J. Adv. Mater. 2008, 20, 452.
13. [13]
  (13) Cai, W. Q.; Hu, Y. Z.; Chen, J.; Zhang, G. X.; Xia, T. Cryst. Eng. Commun. 2012, 14, 972. doi: 10.1039/C1CE05975K
14. [14]
  (14) Zhang, C.; Zhang, H.; Du, B.; Hou, R.; Guo, S. J. Colloid Interface Sci. 2012, 368, 97. doi: 10.1016/j.jcis.2011.10.056
15. [15]
  (15) Kong, L.; Lu, X.; Bian, X.; Zhang, W.; Wang, C. J. Solid State Chem. 2010, 183, 2421. doi: 10.1016/j.jssc.2010.08.005
16. [16]
  (16) Nie, L. H.; Meng, A. Y.; Yu, J. G.; Jaroniec, M. Scientific Reports 2013, 3, 3215.
17. [17]
  (17) Cai, W. Q.; Yu, J. G.; Mann, S. Microporous Mesoporous Mat. 2009, 122, 42. doi: 10.1016/j.micromeso.2009.02.003
18. [18]
  (18) Wu, X. Y.; Zhang, B. Q.; Hu, Z. S. Mater. Lett. 2012, 73, 169. doi: 10.1016/j.matlet.2012.01.050
19. [19]
  (19) Wu, X. Y.; Wang, D. B.; Hu, Z. S.; Gu, G. H. Mater. Chem. Phys. 2008, 109, 560. doi: 10.1016/j.matchemphys.2008.01.004
20. [20]
  (20) Cai, W. Q.; Yu, J. G.; Cheng, B.; Su, B. L.; Jaroniec, M. J. Phys. Chem. C 2009, 113, 14739. doi: 10.1021/jp904570z
21. [21]
  (21) Feng, Y.; Zhang, L.; Gu, G. H.; Hu, Z. S. Rare Metal Mat. Eng. 2007, 36, 134.
22. [22]
  (22) Ren, T. Z.; Yuan, Z. Y.; Su, B. L. Langmuir 2004, 20, 1531. doi: 10.1021/la0361767
23. [23]
  (23) Nie, L.; Deng, K.; Yuan, S.; Zhang, W.; Tan, Q. Mater. Lett. 2014, 132, 369. doi: 10.1016/j.matlet.2014.06.095
24. [24]
  (24) Sing, K. S. W.; Everett, D. H.; Haul, R. A. W.; Moscou, L.; Pierotti, R. A.; Rouquerol, J.; Siemieniewska, T. Pure Appl. Chem. 1985, 57, 603.
25. [25]
  (25) Zhao, X.; Wang, W.; Zhang, Y.; Wu, S.; Li, F.; Liu, J. P. Chem. Eng. J. 2014, 250, 164. doi: 10.1016/j.cej.2014.03.113
26. [26]
  (26) Wang, L.; Li, J.; Wang, Y.; Zhao, L.; Jiang, Q. Chem. Eng. J. 2012, 181-182, 72.
27. [27]
  (27) Lan, S.; Guo, N.; Liu, L.; Wu, X.; Li, L.; Gan, S. Appl. Surf. Sci. 2013, 283, 1032. doi: 10.1016/j.apsusc.2013.07.064
28. [28]
  (28) Zhang, L.; Lian, J.; Wang, L.; Jiang, J.; Duan, Z.; Zhao, L. Chem. Eng. J. 2014, 241, 384. doi: 10.1016/j.cej.2013.10.071
29. [29]
  (29) Lorenc-Grabowska, E.; Gryglewicz, G. Dyes and Pigments 2007, 74, 34. doi: 10.1016/j.dyepig.2006.01.027
30. [30]
  (30) Du, Q.; Sun, J.; Li, Y.; Yang, X.; Wang, X.; Wang, Z.; Xia, L. Chem. Eng. J. 2014, 245, 99. doi: 10.1016/j.cej.2014.02.006
1. [1]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
2. [2]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
3. [3]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
4. [4]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
5. [5]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
6. [6]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
7. [7]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
8. [8]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
9. [9]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
10. [10]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
11. [11]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
12. [12]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
13. [13]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
14. [14]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
15. [15]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
16. [16]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
17. [17]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
18. [18]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
19. [19]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
20. [20]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957

Get Citation

PDF

XML

Metrics

PDF Downloads(212)
Abstract views(731)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fast Adsorption Removal of Con Red on Hierarchically Porous γ-Al2O3 Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method

Metrics

通讯作者: 陈斌, bchen63@163.com

Fast Adsorption Removal of Con Red on Hierarchically Porous γ-Al₂O₃ Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method