Citation: LI Xiao-Kun, MA Dong-Dong, ZHENG Yan-Ping, ZHANG Hong, DING Ding, CHEN Ming-Shu, WAN Hui-Lin. Performance of CO Oxidation over Highly Dispersed ld Catalyst on TiO_x/SiO₂ Composite Supports[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1753-1760. doi: 10.3866/PKU.WHXB201507091 shu

Performance of CO Oxidation over Highly Dispersed ld Catalyst on TiO_x/SiO₂ Composite Supports

1.
College of Chemistry and Chemical Engineering, Xiamen University, State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, Xiamen 361005, Fujian Province, P. R. China

Received Date: 16 April 2015
Available Online: 9 July 2015
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB732303, 2013CB933102) (973) (2010CB732303, 2013CB933102) 教育部重大研究计划(309019) (309019) 国家自然科学基金(20923004,21033006, 21073149, 21273178) (20923004,21033006, 21073149, 21273178)教育部创新研究团队项目(IRT1036)资助 (IRT1036)

Supports have a significant effect on the dispersion and stability of Au nanoparticles because of the support-metal interaction. In the present work, TiO_x/SiO₂ composite supports were prepared by the surface sol-gel (SSG) method to enhance the binding strength between the metal and the support. The samples were characterized by low-energy ion scattering (LEIS) spectroscopy, X-ray photoelectron spectroscopy (XPS), Xray diffraction (XRD), transmission electron microscopy (TEM), and N₂ physisorption (BET). The results showed that the TiO_x species in TiO_x/SiO₂ were highly dispersed on SiO2 with the formation of Ti―O―Si linkages. The catalytic activity and stability for CO oxidation on Au/TiO_x/SiO₂ were significantly enhanced, because of the better dispersion of Au nanoparticles compared with Au/TiO₂.
- ld,
- Nanoparticle,
- TiO_x/SiO₂ composite support,
- CO oxidation,
- Titania
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沈阳化工大学材料科学与工程学院沈阳 110142

Performance of CO Oxidation over Highly Dispersed ld Catalyst on TiOx/SiO2 Composite Supports

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通讯作者: 陈斌, bchen63@163.com

Performance of CO Oxidation over Highly Dispersed ld Catalyst on TiO_x/SiO₂ Composite Supports