Citation: SHEN Huan, ZHANG Bing. Ultrafast Dynamics of Benzene on the S₂ State Investigated by Femtosecond Time-Resolved Photoelectron Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1662-1666. doi: 10.3866/PKU.WHXB201507061 shu

Ultrafast Dynamics of Benzene on the S₂ State Investigated by Femtosecond Time-Resolved Photoelectron Spectroscopy

SHEN Huan ^1, ,
ZHANG Bing ²

1.
1 College of Science, Huazhong Agricultural University, Wuhan 430070, P. R. China;
2 State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, P. R. China

Received Date: 10 April 2015
Available Online: 6 July 2015
Fund Project: 国家自然科学基金(21403080)资助项目 (21403080)

The ultrafast dynamics of benzene on the S₂ state have been investigated by femtosecond time-resolved mass spectroscopy coupled with photoelectron imaging. The benzene molecule was excited to the S₂ state by two 400 nm photons, and subsequently probed by one 267 nm photon. The timedependent ion yield of the parent ion consists of two components with different lifetimes. The first component at (90 ± 1) fs is because of internal conversion from the S₂ state to the S₁/S₀ state. The second one, i.e., (5.0 ± 0.2) ps, is due to decay of the S₁ state. The observed lifetime of the second component is shorter than previous results, indicating the existence of an additional decay process. With photoelectron spectra extracted from the time-resolved photoelectron imaging, this newly found deactivated process is assigned to intersystem crossing from the vibrational excited S₁ state to the hot triplet state T₃.
- Time-resolved,
- Photoelectron spectroscopy,
- Benzene molecule,
- Internal conversion,
- Intersystem crossing
1. [1]
  
  (1) Callomon, J. H.; Dunn, T. M.; Mills, I. M. Philos. Trans. R. Soc. London A 1966, 259, 499. doi: 10.1098/rsta.1966.0023
2. [2]
  (2) Spears, G. K.; Rice, S. J. Chem. Phys. 1971, 55, 5561. doi: 10.1063/1.1675724
3. [3]
  (3) Wunsch, L.; Neusser, H. J.; Schlag, E. W. Chem. Phys. Lett. 1975, 32, 210. doi: 10.1016/0009-2614(75)85105-0
4. [4]
  (4) Palmer, I. J.; Ragazos, I. N.; Bernardi, F.; Olivucci, M.; Robb, M. A. J. Am. Chem. Soc. 1993, 115, 673. doi: 10.1021/ja00055a042
5. [5]
  (5) Sauer, P.; Xie, J. R.; Dou, Y. J. Mod. Optic. 2006, 53, 2099. doi: 10.1080/09500340600917674
6. [6]
  (6) Worth, G. A.; Carley, R. E.; Fielding, H. H. Chem. Phys. 2007, 338, 220. doi: 10.1016/j.chemphys.2007.03.005
7. [7]
  (7) Kuzmin, S. L.; Wesolowski, M. J.; Duley, W. W. Applied Optics 2013, 52, 8169. doi: 10.1364/AO.52.008169
8. [8]
  (8) Qiu, X. J.; Qin, C. C.; W, J.; Zhang, B. Phys. Rev. A 2012, 86, 032505.
9. [9]
  (9) Yin, S. H.; Liu, H. P.; Zhang, J. Y.; Jiang, B.; Wang, L.; Sha, G. H.; Lou, N. Q. Chinese Journal of Chemical Physics 2003, 16, 171.
10. [10]
  (10) Yuan, L. W.; Zhu, J. Y.; Wang, Y. Q.; Wang, L.; Bai, J. L.; He, G. Z. Chem. Phys. Lett. 2005, 410, 352. doi: 10.1016/j.cplett. 2005.05.103
11. [11]
  (11) Clara, M.; Hellerer, T.; Neusser, H. J. Applied Physics B-Lasers and Optics 2000, 71, 431. doi: 10.1007/s003400000347
12. [12]
  (12) Cogan, S.; Haas, Y.; Zilberg, S. J. Photochem. Photobiol. A 2007, 190, 200. doi: 10.1016/j.jphotochem.2007.02.005
13. [13]
  (13) Minns, R. S.; Parker, D. S. N.; Penfold, T. J.; Worth, G. A.; Fielding, H. H. Phys. Chem. Chem. Phys. 2010, 12, 15607.
14. [14]
  (14) Radloff, W.; Freudenberg, T.; Ritze, H.; Stert, V.; Noack, F.; Hertel, I. V. Chem. Phys. Lett. 1996, 261, 301. doi: 10.1016/0009-2614(96)00972-4
15. [15]
  (15) Radloff, W.; Stert, V.; Freudenberg, T.; Hertel, I. V.; Jouvet, C.; Dedonder-Lardeux, C.; Solgadi, D. Chem. Phys. Lett. 1997, 281, 20. doi: 10.1016/S0009-2614(97)01142-1
16. [16]
  (16) Suzuki, Y. I.; Horio, T.; Fuji, T.; Suzuki, T. J. Chem. Phys. 2011, 134, 184313_1. doi: 10.1063/1.3586809
17. [17]
  (17) Hiraya, A.; Shobatake, K. J. Chem. Phys. 1991, 94, 7700. doi: 10.1063/1.460155
18. [18]
  (18) Swiderek, P.; Michaud, M.; Sanche, L. J. Chem. Phys. 1996, 105, 6724. doi: 10.1063/1.471852
19. [19]
  (19) Penfold, T. J.; Spesyvtsev, R.; Kirkby, O. M. J. Chem. Phys. 2012, 137, 204310. doi: 10.1063/1.4767054
20. [20]
  (20) Eppink, A. T. J. B.; Parker, D. H. Rev. Sci. Instrum. 1997, 68, 3477. doi: 10.1063/1.1148310
21. [21]
  (21) Hua, L. Q.; Shen, H.; Hu, C. J.; Zhang, B. J. Chem. Phys. 2008, 129, 244308. doi: 10.1063/1.3047756
22. [22]
  (22) Shen, H.; Hua, L.; Hu, C.; Zhang, B. Journal of Molecular Spectroscopy 2009, 257, 200. doi: 10.1016/j.jms.2009.08.003
23. [23]
  (23) Nemeth, G. I.; Selzle, H. L.; Schlag, E. W. Chem. Phys. Lett. 1993, 215, 151. doi: 10.1016/0009-2614(93)89279-Q
24. [24]
  (24) Dribinski, V.; Ossadtchi, A.; Mandelshtam, V. A.; Reisler, H. Rev. Sci. Instrum. 2002, 73, 2634. doi: 10.1063/1.1482156
25. [25]
  (25) Parker, D. S. N.; Minns, R. S.; Phefold, T. J.; Worth, G. A.; Fielding, H. H. Chem. Phys. Lett. 2009, 469, 43. doi: 10.1016/j.cplett.2008.12.069
1. [1]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
2. [2]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
3. [3]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
4. [4]
  Yanan Jiang , Yuchen Ma . Brief Discussion on the Electronic Exchange Interaction in Quantum Chemistry Computations. University Chemistry, 2025, 40(3): 10-15. doi: 10.12461/PKU.DXHX202402058
5. [5]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
6. [6]
  Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
7. [7]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
8. [8]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
9. [9]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
10. [10]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
11. [11]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
12. [12]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
13. [13]
  Feng Sha , Xinyan Wu , Ping Hu , Wenqing Zhang , Xiaoyang Luan , Yunfei Ma . Design of Course Ideology and Politics for the Comprehensive Organic Synthesis Experiment of Benzocaine. University Chemistry, 2024, 39(2): 110-115. doi: 10.3866/PKU.DXHX202307082
14. [14]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
15. [15]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
16. [16]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
17. [17]
  Qun Wang , Yang Li , Songtao Lu , Hongjun Kang , Yang Hong , Xiaohong Wu . Exploration for the Chemistry Innovative Talent Cultivation from an Interdisciplinary Perspective. University Chemistry, 2024, 39(8): 132-135. doi: 10.3866/PKU.DXHX202401052
18. [18]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
19. [19]
  Shahua Huang , Xiaoming Guo , Lin Lin , Guangping Chang , Sheng Han , Zuxin Zhou . Application of “Integration of Industry and Education” in Engineering Chemistry: Improvement of the Pesticide Fipronil Production. University Chemistry, 2024, 39(3): 199-204. doi: 10.3866/PKU.DXHX202309064
20. [20]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028

Get Citation

PDF

XML

Metrics

PDF Downloads(199)
Abstract views(698)
HTML views(121)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ultrafast Dynamics of Benzene on the S2 State Investigated by Femtosecond Time-Resolved Photoelectron Spectroscopy

Metrics

通讯作者: 陈斌, bchen63@163.com

Ultrafast Dynamics of Benzene on the S₂ State Investigated by Femtosecond Time-Resolved Photoelectron Spectroscopy