Citation: LI Xiao-Ying, WANG Li, WANG Yan-Qiu, SONG Zhe, LIU Ben-Kang. Dynamics of Excited o-Dichlorobenzene[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1655-1661. doi: 10.3866/PKU.WHXB201506291 shu

Dynamics of Excited o-Dichlorobenzene

1.
1 School of Physics and Electronic Technology, Liaoning Normal University, Dalian 116029, Liaoning Province, P. R. China;
2 College of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600, Liaoning Province, P. R. China;
3 State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China

Received Date: 7 April 2015
Available Online: 29 June 2015
Fund Project: 国家自然科学基金(21303199)资助项目 (21303199)

The dynamics of the first excited singlet electronic state (S₁) of o-dichlorobenzene was investigated in real time by the femtosecond pump-probe method combined with time-of-flight mass spectroscopy and the photoelectron velocity mapping technique. The lifetime of the S₁ vibrational ground state was determined experimentally to be (651 ± 10) ps, corresponding to the intersystem crossing process from the S₁ state to the triplet state. Two decay channels were found in the S₁ vibrationally excited mode 9a₂18a₂. The fast process (lifetime constant (458 ± 12) fs) is because of the internal conversion from the S₁ vibrationally excited mode to the highly vibrationally excited ground state (S₀). The slow process (lifetime constant (90 ± 10) ps) is attributed to the intersystem crossing process from the S₁ state to the triplet state (T₁). Photoelectrons with long lifetime characteristics in the spectrum might be connected with the intersystem crossing process. Enhanced spinorbital coupling in the S₁ highly vibrationally excited state accelerates the intersystem crossing process.
- o-Dichlorobenzene,
- Vibrational excitation,
- Photoelectron imaging,
- Photoelectron kinetic energy spectrum
1. [1]
  
  (1) Zewail, A. H. Angew. Chem. Intl. Edit. Engl. 2000, 39, 2586.
2. [2]
  (2) Hertel, I. V.; Radloff, W. Rep. Prog. Phys. 2006, 69, 1897. doi: 10.1088/0034-4885/69/6/R06
3. [3]
  (3) Gullett, B.; Oudejans, L.; Touati, A.; Ryan, S.; Tabor, D. J. Mater. Cycles Waste Manage. 2008, 10, 32. doi: 10.1007/s10163-007-0195-8
4. [4]
  (4) Gaber, A.; Riese, M.; Grotemeyer, J. J. Phys. Chem. A 2008, 112, 425. doi: 10.1021/jp074802t
5. [5]
  (5) Gaber, A.; Riese, M.; Witte, F.; Grotemeyer, J. Phys. Chem. Chem. Phys. 2009, 11, 1628. doi: 10.1039/b816800h
6. [6]
  (6) Fujisawa, S.; Oonishi, I.; Masuda, S.; Ohno, K.; Harada, Y. J. Phys. Chem. 1991, 95, 4250. doi: 10.1021/j100164a017
7. [7]
  (7) Scharping, H.; Zetzsch, C. J. Mol. Spectrosc. 1995, 112, 8. doi: 10.1016/0022-2852(85)90186-9
8. [8]
  (8) Weichhardt, C.; Zimmermann, R.; Schramm, K. W.; Boesl, U.; Schlag, E. W. Rapid Commun. Mass Spectrom. 1994, 8, 381.
9. [9]
  (9) Imura, K.; Kishimoto, N.; Ohno, K. J. Phys. Chem. A 2001, 105, 9111. doi: 10.1021/jp011970r
10. [10]
  (10) Singh, I. B.; Rai, S. B.; Rai, D. K. J. Mol. Spectrosc. 1994, 163, 364. doi: 10.1006/jmsp.1994.1032
11. [11]
  (11) Borg, O. A.; Karlsson, D.; Isomaki-Krondahl, M.; Davidsson, J.; Lunell, S. Chem. Phys. Lett. 2008, 456, 123. doi: 10.1016/j.cplett.2008.03.030
12. [12]
  (12) Potts, A. W.; Holland, D. M. P.; Powis, I.; Karlsson, L.; Trofimov, A. B.; Bodzuk, I. L. Chem. Phys. 2013, 415, 84. doi: 10.1016/j.chemphys.2012.12.031
13. [13]
  (13) Powis, I.; Trofimov, A. B.; Bodzuk, I. L.; Holland, D. M. P.; Potts, A. W.; Karlsson, L. Chem. Phys. 2013, 415, 291. doi: 10.1016/j.chemphys.2012.09.026
14. [14]
  (14) Shimoda, A.; Hikida, T.; Morl, Y. J. Phys. Chem. 1979, 83, 1309. doi: 10.1021/j100473a015
15. [15]
  (15) Han, K. L.; He, G. Z. J. Photochem. Photobiol. C-Photochem. Rev. 2007, 8, 55. doi: 10.1016/j.jphotochemrev.2007.03.002
16. [16]
  (16) Liu, B. K.; Wang, B. X.; Wang, Y. Q.; Wang, L. Chem. Phys. Lett. 2009, 477, 266. doi: 10.1016/j.cplett.2009.07.025
17. [17]
  (17) Liu, Y. J.; Persson, P.; Lunell, S. J. Chem. Phys. 2004, 121, 11000. doi: 10.1063/1.1810135
18. [18]
  (18) Sponer, H. Rev. Mod. Phys. 1942, 14, 224. doi: 10.1103/RevModPhys.14.224
19. [19]
  (19) Ichimura, T.; Mori, Y. Chem. Phys. Lett. 1995, 122, 51. doi: 10.1016/0009-2614(85)85476-2
20. [20]
  (20) Ichimura, T.; Mori, Y. J. Chem. Phys. 1997, 107, 835. doi: 10.1063/1.474383
21. [21]
  (21) Zhu, R. S.; Zhang, H.; Wang, G. J.; Gu, X. B.; Han, K. L.; He, G. Z.; Lou, N. Q. Chem. Phys. 1999, 248, 285.
22. [22]
  (22) Szaflarski, D. M.; Simon, J. D.; EI-Sayed, M. A. J. Phys. Chem. 1986, 90, 5050. doi: 10.1021/j100412a035
23. [23]
  (23) Yang, J. J.; Simon, J. D.; EI-Sayed, M. A. J. Phys. Chem. 1984, 88, 6091. doi: 10.1021/j150669a005
24. [24]
  (24) Diau Eric, W. G.; Casanova, J.; Roberts, J. D.; Zewail, A. H. Proc. Natl. Acad. Sci. U. S. A. 2000, 97, 1376. doi: 10.1073/pnas.030524797
25. [25]
  (25) Kadi, M.; Davidsson, J.; Tarnovsky, A. N.; Rasmusson, M.; Åkesson, E. Chem. Phys. Lett. 2001, 350, 93. doi: 10.1016/S0009-2614(01)01283-0
26. [26]
  (26) Yoshida, N.; Hirakawa, Y.; Imasaka, T. Anal. Chem. 2001, 73, 4417. doi: 10.1021/ac010187s
27. [27]
  (27) Deguchi, T.; Takeyasu, N.; Imasaka, T. Appl. Spectrosc. 2002, 56, 1241. doi: 10.1366/000370202760295511
28. [28]
  (28) Yuan, L. W.; Zhu, J. Y.; Wang, Y. Q.; Wang, L.; Bai, J. L.; He, G. Z. Chem. Phys. Lett. 2005, 410, 352. doi: 10.1016/j.cplett.2005.05.103
29. [29]
  (29) Yuan, L. W.; Wang, Y. Q.; Wang, L.; Bai, J. L.; He, G. Z. Science in China Ser. B: Chemistry 2004, 47, 283. doi: 10.1360/03yb0251
30. [30]
  (30) Suzuki, T. J. Phys. B, At. Mol. Opt. Phys. 2014, 47, 124001. doi: 10.1088/0953-4075/47/12/124001
31. [31]
  (31) Liu, Z. M.; Hu, C. L.; Li, S.; Xu, Y. Q.; Wang, Y. M.; Zhang, B. Chem. Phys. Lett. 2015, 619, 44. doi: 10.1016/j.cplett. 2014.11.047
32. [32]
  (32) Shen, H.; Chen, J. J.; Zhang, B. J. Phys. Chem. A 2014, 118, 4444. doi: 10.1021/jp500495b
33. [33]
  (33) Qiu, X. J.; Ding, Z. H.; Xu, Y. Q.; Wang, Y. M.; Zhang, B. Phys. Rev. A 2014, 89, 033045.
34. [34]
  (34) Abulimiti, B.; Zhu, R. S.; Qiu, X. J.; Qin, C.; Zhang, B. Acta Phys. -Chim. Sin. 2014, 30, 22. [布玛利亚?阿布力米提, 朱荣淑, 邱学军, 秦晨, 张冰. 物理化学学报, 2014, 30, 22.]
35. [35]
  (35) Liu, Y. Z.; Knopp, G.; Qin, C. C.; Gerber, T. Chem. Phys. 2015, 446, 142. doi: 10.1016/j.chemphys.2014.11.016
36. [36]
  (36) Liu, B. K.; Wang, Y. Q.; Wang, L. J. Phys. Chem. A 2012, 116, 111. doi: 10.1021/jp209211s
37. [37]
  (37) Parker, D. H.; Eppink, A. T. J. B. J. Chem. Phys. 1997, 107, 2357. doi: 10.1063/1.474624
38. [38]
  (38) Eppink, A. T. J. B.; Parker, D. H. Rev. Sci. Instrum. 1997, 68, 3477. doi: 10.1063/1.1148310
39. [39]
  (39) Qin, C. C.; Liu, Y. Z.; Zhang, S.; Wang, Y. M.; Tang, Y.; Zhang, B. Phys. Rev. A 2011, 83, 033423. doi: 10.1103/PhysRevA. 83.033423
40. [40]
  (40) Garcia, G. A.; Nahon, L.; Powis, I. Rev. Sci. Instrum. 2004, 75, 4989. doi: 10.1063/1.1807578
41. [41]
  (41) O'Keeffe, P.; Bolognesi, P.; Coreno, M.; Moise, A.; Richter, R.; Cautero, G.; Stebel, L.; Ser , R.; Pravica, L.; Ovcharenko, Y.; Avaldi, L. Rev. Sci. Instrum. 2011, 82, 033109. doi: 10.1063/1.3563723
42. [42]
  (42) Zakrzewski, V. G.; Ortiz, J. V. J. Phys. Chem. 1996, 100, 13979. doi: 10.1021/jp960978b
43. [43]
  (43) Holland, D. M. P.; Powis, I.; Trofimov, A. B.; Bodzuk, I. L.; Soshnikov, D. Y.; Potts, A. W.; Karlsson, L. Chem. Phys. 2015, 448, 61. doi: 10.1016/j.chemphys.2014.11.025
1. [1]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
2. [2]
  Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of ⁶⁸Ga-labeled PM_2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468
3. [3]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
4. [4]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
5. [5]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
6. [6]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
7. [7]
  Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
8. [8]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
9. [9]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
10. [10]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
11. [11]
  Xiangchun Li , Wei Xue , Xu Liu , Wenyong Lai . Research and Practice on the Cultivation of Innovation Ability of Chemistry Graduate Students in Electronic Information Universities: A Case Study of Nanjing University of Posts and Telecommunications. University Chemistry, 2024, 39(6): 55-62. doi: 10.3866/PKU.DXHX202310018
12. [12]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
13. [13]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
14. [14]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
15. [15]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
16. [16]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
17. [17]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
18. [18]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
19. [19]
  Yunxin Xu , Wenbo Zhang , Jing Yan , Wangchang Geng , Yi Yan . A Fascinating Saga of “Energetic Materials”. University Chemistry, 2024, 39(9): 266-272. doi: 10.3866/PKU.DXHX202307008
20. [20]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

Get Citation

PDF

XML

Metrics

PDF Downloads(257)
Abstract views(697)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142