Citation:
LI Xiao-Ying, WANG Li, WANG Yan-Qiu, SONG Zhe, LIU Ben-Kang. Dynamics of Excited o-Dichlorobenzene[J]. Acta Physico-Chimica Sinica,
;2015, 31(9): 1655-1661.
doi:
10.3866/PKU.WHXB201506291
-
The dynamics of the first excited singlet electronic state (S1) of o-dichlorobenzene was investigated in real time by the femtosecond pump-probe method combined with time-of-flight mass spectroscopy and the photoelectron velocity mapping technique. The lifetime of the S1 vibrational ground state was determined experimentally to be (651 ± 10) ps, corresponding to the intersystem crossing process from the S1 state to the triplet state. Two decay channels were found in the S1 vibrationally excited mode 9a218a2. The fast process (lifetime constant (458 ± 12) fs) is because of the internal conversion from the S1 vibrationally excited mode to the highly vibrationally excited ground state (S0). The slow process (lifetime constant (90 ± 10) ps) is attributed to the intersystem crossing process from the S1 state to the triplet state (T1). Photoelectrons with long lifetime characteristics in the spectrum might be connected with the intersystem crossing process. Enhanced spinorbital coupling in the S1 highly vibrationally excited state accelerates the intersystem crossing process.
-
-
-
[1]
(1) Zewail, A. H. Angew. Chem. Intl. Edit. Engl. 2000, 39, 2586.
-
[2]
(2) Hertel, I. V.; Radloff, W. Rep. Prog. Phys. 2006, 69, 1897. doi: 10.1088/0034-4885/69/6/R06
-
[3]
(3) Gullett, B.; Oudejans, L.; Touati, A.; Ryan, S.; Tabor, D. J. Mater. Cycles Waste Manage. 2008, 10, 32. doi: 10.1007/s10163-007-0195-8
-
[4]
(4) Gaber, A.; Riese, M.; Grotemeyer, J. J. Phys. Chem. A 2008, 112, 425. doi: 10.1021/jp074802t
-
[5]
(5) Gaber, A.; Riese, M.; Witte, F.; Grotemeyer, J. Phys. Chem. Chem. Phys. 2009, 11, 1628. doi: 10.1039/b816800h
-
[6]
(6) Fujisawa, S.; Oonishi, I.; Masuda, S.; Ohno, K.; Harada, Y. J. Phys. Chem. 1991, 95, 4250. doi: 10.1021/j100164a017
-
[7]
(7) Scharping, H.; Zetzsch, C. J. Mol. Spectrosc. 1995, 112, 8. doi: 10.1016/0022-2852(85)90186-9
-
[8]
(8) Weichhardt, C.; Zimmermann, R.; Schramm, K. W.; Boesl, U.; Schlag, E. W. Rapid Commun. Mass Spectrom. 1994, 8, 381.
-
[9]
(9) Imura, K.; Kishimoto, N.; Ohno, K. J. Phys. Chem. A 2001, 105, 9111. doi: 10.1021/jp011970r
-
[10]
(10) Singh, I. B.; Rai, S. B.; Rai, D. K. J. Mol. Spectrosc. 1994, 163, 364. doi: 10.1006/jmsp.1994.1032
-
[11]
(11) Borg, O. A.; Karlsson, D.; Isomaki-Krondahl, M.; Davidsson, J.; Lunell, S. Chem. Phys. Lett. 2008, 456, 123. doi: 10.1016/j.cplett.2008.03.030
-
[12]
(12) Potts, A. W.; Holland, D. M. P.; Powis, I.; Karlsson, L.; Trofimov, A. B.; Bodzuk, I. L. Chem. Phys. 2013, 415, 84. doi: 10.1016/j.chemphys.2012.12.031
-
[13]
(13) Powis, I.; Trofimov, A. B.; Bodzuk, I. L.; Holland, D. M. P.; Potts, A. W.; Karlsson, L. Chem. Phys. 2013, 415, 291. doi: 10.1016/j.chemphys.2012.09.026
-
[14]
(14) Shimoda, A.; Hikida, T.; Morl, Y. J. Phys. Chem. 1979, 83, 1309. doi: 10.1021/j100473a015
-
[15]
(15) Han, K. L.; He, G. Z. J. Photochem. Photobiol. C-Photochem. Rev. 2007, 8, 55. doi: 10.1016/j.jphotochemrev.2007.03.002
-
[16]
(16) Liu, B. K.; Wang, B. X.; Wang, Y. Q.; Wang, L. Chem. Phys. Lett. 2009, 477, 266. doi: 10.1016/j.cplett.2009.07.025
-
[17]
(17) Liu, Y. J.; Persson, P.; Lunell, S. J. Chem. Phys. 2004, 121, 11000. doi: 10.1063/1.1810135
-
[18]
(18) Sponer, H. Rev. Mod. Phys. 1942, 14, 224. doi: 10.1103/RevModPhys.14.224
-
[19]
(19) Ichimura, T.; Mori, Y. Chem. Phys. Lett. 1995, 122, 51. doi: 10.1016/0009-2614(85)85476-2
-
[20]
(20) Ichimura, T.; Mori, Y. J. Chem. Phys. 1997, 107, 835. doi: 10.1063/1.474383
-
[21]
(21) Zhu, R. S.; Zhang, H.; Wang, G. J.; Gu, X. B.; Han, K. L.; He, G. Z.; Lou, N. Q. Chem. Phys. 1999, 248, 285.
-
[22]
(22) Szaflarski, D. M.; Simon, J. D.; EI-Sayed, M. A. J. Phys. Chem. 1986, 90, 5050. doi: 10.1021/j100412a035
-
[23]
(23) Yang, J. J.; Simon, J. D.; EI-Sayed, M. A. J. Phys. Chem. 1984, 88, 6091. doi: 10.1021/j150669a005
-
[24]
(24) Diau Eric, W. G.; Casanova, J.; Roberts, J. D.; Zewail, A. H. Proc. Natl. Acad. Sci. U. S. A. 2000, 97, 1376. doi: 10.1073/pnas.030524797
-
[25]
(25) Kadi, M.; Davidsson, J.; Tarnovsky, A. N.; Rasmusson, M.; Åkesson, E. Chem. Phys. Lett. 2001, 350, 93. doi: 10.1016/S0009-2614(01)01283-0
-
[26]
(26) Yoshida, N.; Hirakawa, Y.; Imasaka, T. Anal. Chem. 2001, 73, 4417. doi: 10.1021/ac010187s
-
[27]
(27) Deguchi, T.; Takeyasu, N.; Imasaka, T. Appl. Spectrosc. 2002, 56, 1241. doi: 10.1366/000370202760295511
-
[28]
(28) Yuan, L. W.; Zhu, J. Y.; Wang, Y. Q.; Wang, L.; Bai, J. L.; He, G. Z. Chem. Phys. Lett. 2005, 410, 352. doi: 10.1016/j.cplett.2005.05.103
-
[29]
(29) Yuan, L. W.; Wang, Y. Q.; Wang, L.; Bai, J. L.; He, G. Z. Science in China Ser. B: Chemistry 2004, 47, 283. doi: 10.1360/03yb0251
-
[30]
(30) Suzuki, T. J. Phys. B, At. Mol. Opt. Phys. 2014, 47, 124001. doi: 10.1088/0953-4075/47/12/124001
-
[31]
(31) Liu, Z. M.; Hu, C. L.; Li, S.; Xu, Y. Q.; Wang, Y. M.; Zhang, B. Chem. Phys. Lett. 2015, 619, 44. doi: 10.1016/j.cplett. 2014.11.047
-
[32]
(32) Shen, H.; Chen, J. J.; Zhang, B. J. Phys. Chem. A 2014, 118, 4444. doi: 10.1021/jp500495b
-
[33]
(33) Qiu, X. J.; Ding, Z. H.; Xu, Y. Q.; Wang, Y. M.; Zhang, B. Phys. Rev. A 2014, 89, 033045.
-
[34]
(34) Abulimiti, B.; Zhu, R. S.; Qiu, X. J.; Qin, C.; Zhang, B. Acta Phys. -Chim. Sin. 2014, 30, 22. [布玛利亚?阿布力米提, 朱荣淑, 邱学军, 秦晨, 张冰. 物理化学学报, 2014, 30, 22.]
-
[35]
(35) Liu, Y. Z.; Knopp, G.; Qin, C. C.; Gerber, T. Chem. Phys. 2015, 446, 142. doi: 10.1016/j.chemphys.2014.11.016
-
[36]
(36) Liu, B. K.; Wang, Y. Q.; Wang, L. J. Phys. Chem. A 2012, 116, 111. doi: 10.1021/jp209211s
-
[37]
(37) Parker, D. H.; Eppink, A. T. J. B. J. Chem. Phys. 1997, 107, 2357. doi: 10.1063/1.474624
-
[38]
(38) Eppink, A. T. J. B.; Parker, D. H. Rev. Sci. Instrum. 1997, 68, 3477. doi: 10.1063/1.1148310
-
[39]
(39) Qin, C. C.; Liu, Y. Z.; Zhang, S.; Wang, Y. M.; Tang, Y.; Zhang, B. Phys. Rev. A 2011, 83, 033423. doi: 10.1103/PhysRevA. 83.033423
-
[40]
(40) Garcia, G. A.; Nahon, L.; Powis, I. Rev. Sci. Instrum. 2004, 75, 4989. doi: 10.1063/1.1807578
-
[41]
(41) O'Keeffe, P.; Bolognesi, P.; Coreno, M.; Moise, A.; Richter, R.; Cautero, G.; Stebel, L.; Ser , R.; Pravica, L.; Ovcharenko, Y.; Avaldi, L. Rev. Sci. Instrum. 2011, 82, 033109. doi: 10.1063/1.3563723
-
[42]
(42) Zakrzewski, V. G.; Ortiz, J. V. J. Phys. Chem. 1996, 100, 13979. doi: 10.1021/jp960978b
-
[43]
(43) Holland, D. M. P.; Powis, I.; Trofimov, A. B.; Bodzuk, I. L.; Soshnikov, D. Y.; Potts, A. W.; Karlsson, L. Chem. Phys. 2015, 448, 61. doi: 10.1016/j.chemphys.2014.11.025
-
[1]
-
-
-
[1]
Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
-
[2]
Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
-
[3]
Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of 68Ga-labeled PM2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468
-
[4]
Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
-
[5]
Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
-
[6]
Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
-
[7]
Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
-
[8]
Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
-
[9]
Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
-
[10]
Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr3 Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
-
[11]
Yuhang Zhang , Weiwei Zhao , Hongwei Liu , Junpeng Lü . 基于低维材料的自供电光电探测器研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2310004-. doi: 10.3866/PKU.WHXB202310004
-
[12]
Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045
-
[13]
Supin Zhao , Jing Xie . Understanding the Vibrational Stark Effect of Water Molecules Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 178-185. doi: 10.12461/PKU.DXHX202406024
-
[14]
Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
-
[15]
Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
-
[16]
Yanan Jiang , Yuchen Ma . Brief Discussion on the Electronic Exchange Interaction in Quantum Chemistry Computations. University Chemistry, 2025, 40(3): 10-15. doi: 10.12461/PKU.DXHX202402058
-
[17]
Yaqin Zheng , Lian Zhuo , Meng Li , Chunying Rong . Enhancing Understanding of the Electronic Effect of Substituents on Benzene Rings Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 193-198. doi: 10.12461/PKU.DXHX202406119
-
[18]
Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
-
[19]
Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
-
[20]
Qingjun PAN , Zhongliang GONG , Yuwu ZHONG . Advances in modulation of the excited states of photofunctional iron complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 45-58. doi: 10.11862/CJIC.20240365
-
[1]
Metrics
- PDF Downloads(257)
- Abstract views(745)
- HTML views(30)