Citation: CHEN Fei-Wu, LU Tian, WU Zhao. Surface Absorption of a Solution at Equilibrium[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1499-1503. doi: 10.3866/PKU.WHXB201506191 shu

Surface Absorption of a Solution at Equilibrium

1.
Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China; Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Beijing 100083, P. R. China

Received Date: 4 March 2015
Available Online: 19 June 2015
Fund Project: 国家自然科学基金(21173020, 21473008)资助项目 (21173020, 21473008)

Surface adsorption of a solution is still a challenging problem in the thermodynamics of surfaces. In this work, a new thermodynamic state function is defined. The equilibrium condition of surface adsorption is that the differential of this state function is equal to zero. Based on this condition, we derived a new equation to describe surface adsorption at equilibrium. No hypothetical dividing surface is needed in this derivation. The new equation is quite different from the Gibbs adsorption equation. We also performed molecular dynamic simulations of aqueous sodium chloride solutions. The simulated results are in od agreement with our theoretical predictions.
- Surface absorption,
- Equilibrium condition,
- Gibbs absorption equation,
- Thermodynamic state function,
- Solution
1. [1]
  
  (1) Cheng, X. H.; Zhao, O. D.; Zhao, H. N.; Huang, J. B. Acta Phys. -Chim. Sin. 2014, 30, 917. [程新皓, 赵欧狄, 赵海娜, 黄建滨. 物理化学学报, 2014, 30, 917.] doi: 10.3866/PKU. WHXB201403191
2. [2]
  (2) Hu, S. Q.; Ji, X. J; Fan, Z. Y.; Zhang, T. T.; Sun, S. Q. Acta Phys. -Chim. Sin. 2015, 31, 83. [胡松青, 纪贤晶, 范忠钰, 张田田, 孙霜青, 物理化学学报, 2015, 31, 83.] doi: 10.3866/PKU. WHXB201411191
3. [3]
  (3) Wang, K.; Yu, Y. X.; Gao, G. H. J. Chem. Phys. 2008, 128, 185101. doi: 10.1063/1.2918342
4. [4]
  (4) Peng, B.; Yu, Y. X. J. Chem. Phys. 2009, 131, 134703. doi: 10.1063/1.3243873
5. [5]
  (5) Ghosh, S.; Roy, A.; Banik, D.; Kundu, N.; Kuchlyan, J.; Dhir, A.; Sarkar, N. Langmuir 2015, 31, 2310. doi: 10.1021/la504819v
6. [6]
  (6) Bera, M. K.; Antonio, M. R. Langmuir 2015, 31, 5432. doi: 10.1021/acs.langmuir.5b01354
7. [7]
  (7) Atkins, P.; de Paula, J. Atkins' Physical Chemistry, 7th Ed.; Oxford University Press: Oxford, 2002.
8. [8]
  (8) Menger, F. M.; Shi, L.; Rizvi, S. A. A. J. Am. Chem. Soc. 2009, 131, 10380. doi: 10.1021/ja9044289
9. [9]
  (9) Menger, F. M.; Shi, L.; Rizvi, S. A. A. Langmuir 2010, 26, 1588. doi: 10.1021/la9043914
10. [10]
  (10) Menger, F. M.; Rizvi, S. A. A. Langmuir 2011, 27, 13975. doi: 10.1021/la203009m
11. [11]
  (11) Laven, J.; de With, G. Langmuir 2011, 27, 7958. doi: 10.1021/la200152d
12. [12]
  (12) Menger, F. M.; Rizvi, S. A. A.; Shi, L. Langmuir 2011, 27, 7963. doi: 10.1021/la201219g
13. [13]
  (13) Li, P. X.; Li, Z. X.; Shen, H. H.; Thomas, R. K.; Penfold, J.; Lu, J. R. Langmuir 2013, 29, 9324. doi: 10.1021/la4018344
14. [14]
  (14) Nath, S. J. Colloid Interface Sci. 1999, 209, 116.
15. [15]
  (15) Li, Z. B.; Li, Y. G.; Lu, J. F. Ind. Eng. Chem. Res. 1999, 38, 1133. doi: 10.1021/ie980465m
16. [16]
  (16) Yu, Y. X.; Gao, G. H.; Li, Y. G. Fluid Phase Equilibr. 2000, 173, 23. doi: 10.1016/S0378-3812(00)00396-4
17. [17]
  (17) Gromacs Program, Version 4.6.5. http://www.gromacs.org (accessed on Sep 14, 2014).
18. [18]
  (18) Hess, B.; Kutzner, C.; van der Spoel, D.; Lindahl, E. J. Chem. Theory Comput. 2008, 4, 435. doi: 10.1021/ct700301q
19. [19]
  (19) Hoover, W. G. Phys. Rev. A 1985, 31, 1695. doi: 10.1103/PhysRevA.31.1695
20. [20]
  (20) Nosé, S. Mol. Phys. 1984, 52, 255. doi: 10.1080/00268978400101201
21. [21]
  (21) Weerasinghe, S.; Smith, P. E. J. Chem. Phys. 2003, 119, 11342. doi: 10.1063/1.1622372
22. [22]
  (22) Ploetz, E. A.; Bentenitis, N.; Smith, P. E. Fluid Phase Equilib. 2010, 290, 43. doi: 10.1016/j.fluid.2009.11.023
23. [23]
  (23) Berendsen, H. J. C.; Grigera, J. R.; Straatsma, T. P. J. Phys. Chem. 1987, 91, 6269. doi: 10.1021/j100308a038
24. [24]
  (24) Miyamoto, S.; Kollman, P. A. J. Comput. Chem. 1992, 13, 952.
25. [25]
  (25) Darden, T.; York, D.; Pedersen, L. J. Chem. Phys. 1993, 98, 10089. doi: 10.1063/1.464397
26. [26]
  (26) Chen, F.; Smith, P. E. J. Phys. Chem. B 2008, 112, 8975. doi: 10.1021/jp711062a
27. [27]
  (27) Jarvis, N. L.; Scheiman, M. A. J. Phys. Chem. 1968, 72, 74. doi: 10.1021/j100847a014
28. [28]
  (28) Weissenborn, P. K.; Pugh, R. J. Langmuir 1996, 11, 1422.
1. [1]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
2. [2]
  Xiaohui Li , Ze Zhang , Jingyi Cui , Juanjuan Yin . Advanced Exploration and Practice of Teaching in the Experimental Course of Chemical Engineering Thermodynamics under the “High Order, Innovative, and Challenging” Framework. University Chemistry, 2024, 39(7): 368-376. doi: 10.3866/PKU.DXHX202311027
3. [3]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
4. [4]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
5. [5]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
6. [6]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
7. [7]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
8. [8]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
9. [9]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
10. [10]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
11. [11]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
12. [12]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
13. [13]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
14. [14]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
15. [15]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
16. [16]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
17. [17]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
18. [18]
  Cheng Rong , Jiang Jiang , Xinyu Zheng . Constructivism and Deconstructivism in General Chemistry Teaching: Taking the Teaching of Colloidal Solutions as an Example. University Chemistry, 2024, 39(2): 292-297. doi: 10.3866/PKU.DXHX202308035
19. [19]
  Yinuo Wu , Jiantao Ye , Xie Zhou , Yu Qian , Lei Guo . Teaching Design of Basic Chemistry Based on PBL Methodology for Medical Undergraduates: A Case Study on “Osmotic Pressure of Solution”. University Chemistry, 2024, 39(3): 149-157. doi: 10.3866/PKU.DXHX202309077
20. [20]
  Xinxue Li . The Application of Reverse Thinking in Teaching of Boiling Point Elevation and Freezing Point Depression of Dilute Solutions in General Chemistry. University Chemistry, 2024, 39(11): 359-364. doi: 10.3866/PKU.DXHX202401075

Get Citation

PDF

XML

Metrics

PDF Downloads(312)
Abstract views(902)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142