Citation: TIAN Wen-Jie, WANG Hong, YIN Zhen, YANG Ying, LI Jian-Xin. Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1567-1574. doi: 10.3866/PKU.WHXB201506171 shu

Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol

TIAN Wen-Jie ^1,2 ,
WANG Hong ^1,2 ,
YIN Zhen ^1,3, ,
YANG Ying ^1,2 ,
LI Jian-Xin ^1,2,

1.
1. State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
2. School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
3. School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received Date: 20 January 2015
Available Online: 17 June 2015
Fund Project: 国家自然科学基金(21206119, 21303119) (21206119, 21303119)长江学者和创新团队发展计划(IRT13084)项目资助 (IRT13084)

MnO_x nanoparticles obtained by the emulsion method were loaded on a microporous tubular titanium membrane to prepare a functional MnO_x/Ti electrocatalytic membrane. The effects of calcination temperature on the crystal structure of MnO_x as well as the electrochemical properties and catalytic performance to oxidize benzyl alcohol of MnO_x/Ti membrane were systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), cyclic voltammetry (CV), chronoamperometry (CA), and other characterization methods. The results indicated that the crystal structure of MnO_x was gradually transformed from Birnessite-MnO₂ to K_0.27MnO₂, and finally to α- MnO₂ from Mn3O4 with increasing calcination temperature. The α-MnO₂ particles in the MnO_x/Ti electrocatalytic membrane showed high crystallinity and uniform particle size (less than 30 nm). The superior electrochemical properties and catalytic performance of α-MnO₂/Ti membrane obtained at a calcination temperature of 450 ℃ could be attributed to the binding effects between unsaturated coordination atoms of Mn and oxygen vacancies with the Ti substrate. The α-MnO₂/Ti membrane obtained at 450 ℃ was used as the anode to assemble an electrocatalytic membrane reactor to oxidize benzyl alcohol. 64% conversion of benzyl alcohol and 79% selectivity to benzaldehyde was achieved under the operating conditions: reaction temperature 25 ℃, aqueous benzyl alcohol solution of 50 mmol·L^-1, current density 2 mA·cm^-2, and residence time 15 min.
- Porous titanium membrane,
- Electrocatalytic membrane reactor,
- Manganite,
- Benzyl alcohol,
- C atalytic oxidation
1. [1]
  
  (1) Gelalcha, F. G. Chemical Reviews 2007, 107 (7), 3338. doi: 10.1021/cr0505223
2. [2]
  (2) Dan, I. E.; Jennifer K. E.; Philip, L.; Benjamin, S.; Albert, F. C.; Andrew, A. H.; Masashi, W.; Christopher, J. K.; David, W. K.; Graham, J. H. Science 2006, 311, 5759.
3. [3]
  (3) Opembe, N. N.; Guild, C.; King Ondu, C.; Nelson, N. C.; Slowing, I. I.; Suib, S. L. Industrial & Engineering Chemistry Research 2014, 53 (49), 19044. doi: 10.1021/ie5024639
4. [4]
  (4) Rezaei, S. E.; Zonoz, F. M.; Estiri, M.; Tayebee, R. Industrial & Engineering Chemistry Research 2011, 50 (4), 1837. doi: 10.1021/ie101641t
5. [5]
  (5) Parlett, C. M. A.; Bruce, D. W.; Hondow, N. S.; Lee, A. F.; Wilson, K. ACS Catalysis 2011, 1 (6), 636. doi: 10.1021/cs200145n
6. [6]
  (6) Mallat, T.; Baiker, A. Chemical Reviews 2004, 104 (6), 3037. doi: 10.1021/cr0200116
7. [7]
  (7) Guo, Z.; Liu, B.; Zhang, Q.; Deng, W.; Wang, Y.; Yang, Y. Chemical Society Reviews 2014, 43 (10), 3480. doi: 10.1039/c3cs60282f
8. [8]
  (8) Camilla, P. F. C. Green Chem. 2012, 14, 547. doi: 10.1039/c2gc16344f
9. [9]
  (9) Choudhary, V. R.; Chaudhari, P. A.; Narkhede, V. S. Catalysis Communications 2003, 4 (4), 171.
10. [10]
  (10) Su, Y.; Wang, L.; Liu, Y.; Cao, Y.; He, H.; Fan, K. Catalysis Communications 2007, 8 (12), 2181.
11. [11]
  (11) Li, J.; Wang, H.; Li, J. X.; Guan, Q. Q.; Yang, Y. Membrane Science and Technology 2013, 33 (6), 64. [李娇, 王虹, 李建新, 管崎崎, 杨阳. 膜科学与技术, 2013, 33(6), 64.]
12. [12]
  (12) Li, J.; Li, J.; Wang, H.; Cheng, B.; He, B.; Yan, F.; Yang, Y.; Guo, W.; N , H. H. Chemical Communications 2013, 49 (40), 4501. doi: 10.1039/c3cc41181h
13. [13]
  (13) Wang, H.; Wang, H.; Li, J.; Bin, D.; Yin, Z.; Kang, J.; He, B. Electrochimica Acta 2014, 123, 33. doi: 10.1016/j.electacta. 2014.01. 016
14. [14]
  (14) Bin, D.; Wang, H.; Li, J.; Wang, H.; Yin, Z.; Kang, J.; He, B.; Li, Z. Electrochimica Acta 2014, 130, 170. doi: 10.1016/j. electacta.2014.02. 128
15. [15]
  (15) Fang, X.; Yin, Z.; Wang, H.; Li, J.; Liang, X.; Kang, J.; He, B. Journal of Catalysis 2015, 329, 187. doi: 10.1016/j.jcat. 2015.05.004
16. [16]
  (16) Xiao, W.; Wang, D.; Lou, X. W. The Journal of Physical Chemistry C 2010, 114 (3), 1694. doi: 10.1021/jp909386d
17. [17]
  (17) Chen, H.; He, J.; Zhang, C.; He, H. The Journal of Physical Chemistry C 2007, 111 (49), 18033.
18. [18]
  (18) Lee, J. W.; Hall, A. S.; Kim, J.; Mallouk, T. E. Chemistry of Materials 2012, 24 (6), 1158. doi: 10.1021/cm203697w
19. [19]
  (19) Devaraj, S.; Munichandraiah, N. The Journal of Physical Chemistry C 2008, 112 (11), 4406. doi: 10.1016/j.orgel. 2008.12.008
20. [20]
  (20) Nesbitt, H. W. B. The American Mineralogist 1998, 83 (3-4), 305.
21. [21]
  (21) Beyreuther, E.; Grafstr, M. S.; Eng, L. M. Physical Review B 2006, 73 (15), 155425. doi: 10.1103/PhysRevB.73.155425
22. [22]
  (22) Kang, J.; Hirata, A.; Qiu, H. J.; Chen, L.; Ge, X.; Fujita, T.; Chen, M. Advanced Materials 2014, 26 (2), 269. doi: 10.1002/adma.201302975
23. [23]
  (23) Dai, Y.; Li, J. H.; Peng, Y.; Tang, X. F. Acta Phys.-Chim. Sin. 2012, 7, 1771. [戴韵, 李俊华, 彭悦, 唐幸福. 物理化学学报, 2012, 7, 1771.]. doi: 10.3866/PKU.WHXB201204175
24. [24]
  (24) Crist, B. V. Handbook of Monochromatic XPS Spectra, Volume 1: The Elements of Native Oxides; Wiley & Sons; Chichester, 2000; pp 515-519.
25. [25]
  (25) Chen, Q. Y.; Tong, H. X.; Yin, Z. L.; Hu, H. P.; Li, J.; Liu, L. L. Acta Phys. -Chim. Sin. 2007, 12, 1917. [陈启元, 童海霞, 尹周澜, 胡慧萍, 李洁, 刘亮亮. 物理化学学报, 2007, 12, 1917.] doi: 10.3866/PKU.WHXB20071216
26. [26]
  (26) Huang, Y.; Li, H.; Balogun, M.; Liu, W.; Tong, Y.; Lu, X.; Ji, H. ACS Applied Materials & Interfaces 2014, 6 (24), 22920. doi: 10.1021/am507641k
27. [27]
  (27) Zhang, X. J.; Liu, Q. J.; Deng, S. G.; Chen, J.; Gao, P. Acta Phys. Sin. 2011, 08, 567. [张学军, 柳清菊, 邓曙光, 陈娟, 高攀. 物理学报, 2011, 08, 567.]
28. [28]
  (28) Lu, X.; Wang, G.; Zhai, T.; Yu, M.; Gan, J.; Tong, Y.; Li, Y. Nano Letters 2012, 12 (3), 1690.
29. [29]
  (29) Zhang, Y.; Sun, C.; Lu, P.; Li, K.; Song, S.; Xue, D. CrystEngComm 2012, 14 (18), 5892. doi: 10.1039/c2ce25610j
30. [30]
  (30) Cheng, F.; Su, Y.; Liang, J.; Tao, Z.; Chen, J. Chemistry of Materials 2010, 22 (3), 898. doi: 10.1021/cm901698s
31. [31]
  (31) Dupont, M.; Hollenkamp, A. F.; Donne, S. W. Electrochimica Acta 2013, 104, 140. doi: 10.1016/j.electacta.2013.04.007
1. [1]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
2. [2]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
3. [3]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
4. [4]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
5. [5]
  Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181
6. [6]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
7. [7]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
12. [12]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
13. [13]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
14. [14]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
15. [15]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
16. [16]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
17. [17]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
18. [18]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
19. [19]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
20. [20]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

Get Citation

PDF

XML

Metrics

PDF Downloads(257)
Abstract views(511)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142