Citation: TIAN Wen-Jie, WANG Hong, YIN Zhen, YANG Ying, LI Jian-Xin. Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1567-1574. doi: 10.3866/PKU.WHXB201506171 shu

Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol

  • Received Date: 20 January 2015
    Available Online: 17 June 2015

    Fund Project: 国家自然科学基金(21206119, 21303119) (21206119, 21303119)长江学者和创新团队发展计划(IRT13084)项目资助 (IRT13084)

  • MnOx nanoparticles obtained by the emulsion method were loaded on a microporous tubular titanium membrane to prepare a functional MnOx/Ti electrocatalytic membrane. The effects of calcination temperature on the crystal structure of MnOx as well as the electrochemical properties and catalytic performance to oxidize benzyl alcohol of MnOx/Ti membrane were systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), cyclic voltammetry (CV), chronoamperometry (CA), and other characterization methods. The results indicated that the crystal structure of MnOx was gradually transformed from Birnessite-MnO2 to K0.27MnO2, and finally to α- MnO2 from Mn3O4 with increasing calcination temperature. The α-MnO2 particles in the MnOx/Ti electrocatalytic membrane showed high crystallinity and uniform particle size (less than 30 nm). The superior electrochemical properties and catalytic performance of α-MnO2/Ti membrane obtained at a calcination temperature of 450 ℃ could be attributed to the binding effects between unsaturated coordination atoms of Mn and oxygen vacancies with the Ti substrate. The α-MnO2/Ti membrane obtained at 450 ℃ was used as the anode to assemble an electrocatalytic membrane reactor to oxidize benzyl alcohol. 64% conversion of benzyl alcohol and 79% selectivity to benzaldehyde was achieved under the operating conditions: reaction temperature 25 ℃, aqueous benzyl alcohol solution of 50 mmol·L-1, current density 2 mA·cm-2, and residence time 15 min.

  • 加载中
    1. [1]

      (1) Gelalcha, F. G. Chemical Reviews 2007, 107 (7), 3338. doi: 10.1021/cr0505223

    2. [2]

      (2) Dan, I. E.; Jennifer K. E.; Philip, L.; Benjamin, S.; Albert, F. C.; Andrew, A. H.; Masashi, W.; Christopher, J. K.; David, W. K.; Graham, J. H. Science 2006, 311, 5759.

    3. [3]

      (3) Opembe, N. N.; Guild, C.; King Ondu, C.; Nelson, N. C.; Slowing, I. I.; Suib, S. L. Industrial & Engineering Chemistry Research 2014, 53 (49), 19044. doi: 10.1021/ie5024639

    4. [4]

      (4) Rezaei, S. E.; Zonoz, F. M.; Estiri, M.; Tayebee, R. Industrial & Engineering Chemistry Research 2011, 50 (4), 1837. doi: 10.1021/ie101641t

    5. [5]

      (5) Parlett, C. M. A.; Bruce, D. W.; Hondow, N. S.; Lee, A. F.; Wilson, K. ACS Catalysis 2011, 1 (6), 636. doi: 10.1021/cs200145n

    6. [6]

      (6) Mallat, T.; Baiker, A. Chemical Reviews 2004, 104 (6), 3037. doi: 10.1021/cr0200116

    7. [7]

      (7) Guo, Z.; Liu, B.; Zhang, Q.; Deng, W.; Wang, Y.; Yang, Y. Chemical Society Reviews 2014, 43 (10), 3480. doi: 10.1039/c3cs60282f

    8. [8]

      (8) Camilla, P. F. C. Green Chem. 2012, 14, 547. doi: 10.1039/c2gc16344f

    9. [9]

      (9) Choudhary, V. R.; Chaudhari, P. A.; Narkhede, V. S. Catalysis Communications 2003, 4 (4), 171.

    10. [10]

      (10) Su, Y.; Wang, L.; Liu, Y.; Cao, Y.; He, H.; Fan, K. Catalysis Communications 2007, 8 (12), 2181.

    11. [11]

      (11) Li, J.; Wang, H.; Li, J. X.; Guan, Q. Q.; Yang, Y. Membrane Science and Technology 2013, 33 (6), 64. [李娇, 王虹, 李建新, 管崎崎, 杨阳. 膜科学与技术, 2013, 33(6), 64.]

    12. [12]

      (12) Li, J.; Li, J.; Wang, H.; Cheng, B.; He, B.; Yan, F.; Yang, Y.; Guo, W.; N , H. H. Chemical Communications 2013, 49 (40), 4501. doi: 10.1039/c3cc41181h

    13. [13]

      (13) Wang, H.; Wang, H.; Li, J.; Bin, D.; Yin, Z.; Kang, J.; He, B. Electrochimica Acta 2014, 123, 33. doi: 10.1016/j.electacta. 2014.01. 016

    14. [14]

      (14) Bin, D.; Wang, H.; Li, J.; Wang, H.; Yin, Z.; Kang, J.; He, B.; Li, Z. Electrochimica Acta 2014, 130, 170. doi: 10.1016/j. electacta.2014.02. 128

    15. [15]

      (15) Fang, X.; Yin, Z.; Wang, H.; Li, J.; Liang, X.; Kang, J.; He, B. Journal of Catalysis 2015, 329, 187. doi: 10.1016/j.jcat. 2015.05.004

    16. [16]

      (16) Xiao, W.; Wang, D.; Lou, X. W. The Journal of Physical Chemistry C 2010, 114 (3), 1694. doi: 10.1021/jp909386d

    17. [17]

      (17) Chen, H.; He, J.; Zhang, C.; He, H. The Journal of Physical Chemistry C 2007, 111 (49), 18033.

    18. [18]

      (18) Lee, J. W.; Hall, A. S.; Kim, J.; Mallouk, T. E. Chemistry of Materials 2012, 24 (6), 1158. doi: 10.1021/cm203697w

    19. [19]

      (19) Devaraj, S.; Munichandraiah, N. The Journal of Physical Chemistry C 2008, 112 (11), 4406. doi: 10.1016/j.orgel. 2008.12.008

    20. [20]

      (20) Nesbitt, H. W. B. The American Mineralogist 1998, 83 (3-4), 305.

    21. [21]

      (21) Beyreuther, E.; Grafstr, M. S.; Eng, L. M. Physical Review B 2006, 73 (15), 155425. doi: 10.1103/PhysRevB.73.155425

    22. [22]

      (22) Kang, J.; Hirata, A.; Qiu, H. J.; Chen, L.; Ge, X.; Fujita, T.; Chen, M. Advanced Materials 2014, 26 (2), 269. doi: 10.1002/adma.201302975

    23. [23]

      (23) Dai, Y.; Li, J. H.; Peng, Y.; Tang, X. F. Acta Phys.-Chim. Sin. 2012, 7, 1771. [戴韵, 李俊华, 彭悦, 唐幸福. 物理化学学报, 2012, 7, 1771.]. doi: 10.3866/PKU.WHXB201204175

    24. [24]

      (24) Crist, B. V. Handbook of Monochromatic XPS Spectra, Volume 1: The Elements of Native Oxides; Wiley & Sons; Chichester, 2000; pp 515-519.

    25. [25]

      (25) Chen, Q. Y.; Tong, H. X.; Yin, Z. L.; Hu, H. P.; Li, J.; Liu, L. L. Acta Phys. -Chim. Sin. 2007, 12, 1917. [陈启元, 童海霞, 尹周澜, 胡慧萍, 李洁, 刘亮亮. 物理化学学报, 2007, 12, 1917.] doi: 10.3866/PKU.WHXB20071216

    26. [26]

      (26) Huang, Y.; Li, H.; Balogun, M.; Liu, W.; Tong, Y.; Lu, X.; Ji, H. ACS Applied Materials & Interfaces 2014, 6 (24), 22920. doi: 10.1021/am507641k

    27. [27]

      (27) Zhang, X. J.; Liu, Q. J.; Deng, S. G.; Chen, J.; Gao, P. Acta Phys. Sin. 2011, 08, 567. [张学军, 柳清菊, 邓曙光, 陈娟, 高攀. 物理学报, 2011, 08, 567.]

    28. [28]

      (28) Lu, X.; Wang, G.; Zhai, T.; Yu, M.; Gan, J.; Tong, Y.; Li, Y. Nano Letters 2012, 12 (3), 1690.

    29. [29]

      (29) Zhang, Y.; Sun, C.; Lu, P.; Li, K.; Song, S.; Xue, D. CrystEngComm 2012, 14 (18), 5892. doi: 10.1039/c2ce25610j

    30. [30]

      (30) Cheng, F.; Su, Y.; Liang, J.; Tao, Z.; Chen, J. Chemistry of Materials 2010, 22 (3), 898. doi: 10.1021/cm901698s

    31. [31]

      (31) Dupont, M.; Hollenkamp, A. F.; Donne, S. W. Electrochimica Acta 2013, 104, 140. doi: 10.1016/j.electacta.2013.04.007


  • 加载中
    1. [1]

      Yongmei Liu Lisen Sun Zhen Huang Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020

    2. [2]

      Ling Liu Haibin Wang Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080

    3. [3]

      Ye WangRuixiang GeXiang LiuJing LiHaohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019

    4. [4]

      Kai CHENFengshun WUShun XIAOJinbao ZHANGLihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

    5. [5]

      Feng Han Fuxian Wan Ying Li Congcong Zhang Yuanhong Zhang Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181

    6. [6]

      Ping ZHANGChenchen ZHAOXiaoyun CUIBing XIEYihan LIUHaiyu LINJiale ZHANGYu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

    7. [7]

      Yan LIUJiaxin GUOSong YANGShixian XUYanyan YANGZhongliang YUXiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

    8. [8]

      Xin Han Zhihao Cheng Jinfeng Zhang Jie Liu Cheng Zhong Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023

    9. [9]

      Wang WangYucheng LiuShengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059

    10. [10]

      Qingqing SHENXiangbowen DUKaicheng QIANZhikang JINZheng FANGTong WEIRenhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028

    11. [11]

      Yingchun ZHANGYiwei SHIRuijie YANGXin WANGZhiguo SONGMin WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    12. [12]

      Chuanming GUOKaiyang ZHANGYun WURui YAOQiang ZHAOJinping LIGuang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    13. [13]

      Shijie RenMingze GaoRui-Ting GaoLei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040

    14. [14]

      Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378

    15. [15]

      Lina GuoRuizhe LiChuang SunXiaoli LuoYiqiu ShiHong YuanShuxin OuyangTierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO2 Methanation of Derived Ni-Al2O3 Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002

    16. [16]

      Liangliang SongHaoyan LiangShunqing LiBao QiuZhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085

    17. [17]

      Caixia Lin Zhaojiang Shi Yi Yu Jianfeng Yan Keyin Ye Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005

    18. [18]

      Yan KongWei WeiLekai XuChen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO2 Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049

    19. [19]

      CCS Chemistry 综述推荐│绿色氧化新思路:光/电催化助力有机物高效升级

      . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.

    20. [20]

      Yaping ZHANGTongchen WUYun ZHENGBizhou LIN . Z-scheme heterojunction β-Bi2O3 pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256

Metrics
  • PDF Downloads(257)
  • Abstract views(577)
  • HTML views(4)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return