Citation: TIAN Wen-Jie, WANG Hong, YIN Zhen, YANG Ying, LI Jian-Xin. Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1567-1574. doi: 10.3866/PKU.WHXB201506171 shu

Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol

TIAN Wen-Jie ^1,2 ,
WANG Hong ^1,2 ,
YIN Zhen ^1,3, ,
YANG Ying ^1,2 ,
LI Jian-Xin ^1,2,

1.
1. State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
2. School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
3. School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received Date: 20 January 2015
Available Online: 17 June 2015
Fund Project: 国家自然科学基金(21206119, 21303119) (21206119, 21303119)长江学者和创新团队发展计划(IRT13084)项目资助 (IRT13084)

MnO_x nanoparticles obtained by the emulsion method were loaded on a microporous tubular titanium membrane to prepare a functional MnO_x/Ti electrocatalytic membrane. The effects of calcination temperature on the crystal structure of MnO_x as well as the electrochemical properties and catalytic performance to oxidize benzyl alcohol of MnO_x/Ti membrane were systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), cyclic voltammetry (CV), chronoamperometry (CA), and other characterization methods. The results indicated that the crystal structure of MnO_x was gradually transformed from Birnessite-MnO₂ to K_0.27MnO₂, and finally to α- MnO₂ from Mn3O4 with increasing calcination temperature. The α-MnO₂ particles in the MnO_x/Ti electrocatalytic membrane showed high crystallinity and uniform particle size (less than 30 nm). The superior electrochemical properties and catalytic performance of α-MnO₂/Ti membrane obtained at a calcination temperature of 450 ℃ could be attributed to the binding effects between unsaturated coordination atoms of Mn and oxygen vacancies with the Ti substrate. The α-MnO₂/Ti membrane obtained at 450 ℃ was used as the anode to assemble an electrocatalytic membrane reactor to oxidize benzyl alcohol. 64% conversion of benzyl alcohol and 79% selectivity to benzaldehyde was achieved under the operating conditions: reaction temperature 25 ℃, aqueous benzyl alcohol solution of 50 mmol·L^-1, current density 2 mA·cm^-2, and residence time 15 min.
- Porous titanium membrane,
- Electrocatalytic membrane reactor,
- Manganite,
- Benzyl alcohol,
- C atalytic oxidation
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