Citation: SHI Xia-Xing, LIAO Shi-Xuan, YUAN Bing, ZHONG Yan-Jun, ZHONG Ben-He, LIU Heng, GUO Xiao-Dong. Facile Synthesis of 0.6Li₂MnO₃-0.4LiNi_0.5Mn_0.5O₂ with Hierarchical Micro/Nanostructure and High Rate Capability as Cathode Material for Li-Ion Battery[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1527-1534. doi: 10.3866/PKU.WHXB201506151 shu

Facile Synthesis of 0.6Li₂MnO₃-0.4LiNi_0.5Mn_0.5O₂ with Hierarchical Micro/Nanostructure and High Rate Capability as Cathode Material for Li-Ion Battery

1.
1. College of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China;
2. College of Materials Science and Engineering, Sichuan University, Chengdu 610065, P. R. China

Received Date: 22 April 2015
Available Online: 15 June 2015
Fund Project: 四川大学科技支撑计划(2014GZ0077) (2014GZ0077)高等学校博士学科点专项科研基金(20120181120103)资助项目 (20120181120103)

The cuboid layered 0.6Li₂MnO₃-0.4LiNi_0.5Mn_0.5O₂ cobalt-free lithium-rich solid-solution cathode material was synthesized by a facile quick co-precipitation method. The prepared material was characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma (ICP) spectroscopy, field-emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical measurements. It was found that the as-prepared material has a typical hexa nal α-NaFeO₂ layered structure with R3m space group, and the chemical composition of this material is similar to the corresponding target material. SEM and TEM images reveal that the cuboid structures are assembled from nanoparticles with particle sizes of 40-200 nm. A possible formation mechanism of this cuboid aggregation is proposed. The electrochemical tests (in the voltage range 2.0-4.8 V vs Li/Li⁺) indicate that the as-prepared material exhibits excellent rate capability. It delivers approximately 243 and 143 mAh·g^-1 corresponding to 0.1C and 10C, respectively. Moreover, the asprepared material has od cycling stability even after high rate measurement, delivering a high capacity retention of 90.7% after 72 cycles at 0.5C. This co-precipitation approach, which has facile operation processes and od results, is a economic technique that could facilitate the application of Li-rich cathode on a large scale.
- Cathode material,
- Facile quick co-precipitation,
- Cuboid structure,
- Electrochemical performance,
- Li-ion battery
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通讯作者: 陈斌, bchen63@163.com

Facile Synthesis of 0.6Li₂MnO₃-0.4LiNi_0.5Mn_0.5O₂ with Hierarchical Micro/Nanostructure and High Rate Capability as Cathode Material for Li-Ion Battery