Citation:
SU Hong-Zhen, YIN Jing-Mei, LIU Qing-Shan, LI Chang-Ping. Properties of Four Deep Eutectic Solvents: Density, Electrical Conductivity, Dynamic Viscosity and Refractive Index[J]. Acta Physico-Chimica Sinica,
;2015, 31(8): 1468-1473.
doi:
10.3866/PKU.WHXB201506111
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Four deep eutectic solvents (DESs) were prepared from tetrabutylammonium chloride: tetrabutylammonium chloride:propionic acid [TBAC:2PA], tetrabutylammonium chloride:ethylene glycol [TBAC:2EG], tetrabutylammonium chloride:polyethylene glycol [TBAC:2PEG], and tetrabutylammonium chloride:phenylacetic acid [TBAC:2PAA]. The density, electrical conductivity, dynamic viscosity, and refractive index of the samples were measured at 288.15-338.15 K under atmospheric pressure. The influence of the temperature on the density, electrical conductivity, dynamic viscosity, and refractive index are discussed. The thermal expansion coefficient, molecular volume, standard molar entropy, and lattice energy were determined from the measured values using empirical equations. The temperature dependences on the electrical conductivity and dynamic viscosity of the DESs were fitted by the Vogel- Fulcher-Tamman (VFT) equation. The Arrhenius equation is also discussed for the electrical conductivity and dynamic viscosity. The above study will be of great significance for the industrial and engineering applications of DESs.
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-
-
[1]
(1) Zhang, Q. H.; Vigier, K. D. O.; Royer, S.; Jérôme, F. Chem. Soc. Rev. 2012, 41, 7108. doi: 10.1039/c2cs35178a
-
[2]
(2) Jhong, H. R.; Wong, D. S. H.; Wan, C. C.; Wang, Y. Y.; Wei, T. C. Electrochem. Commun. 2009, 11, 209. doi: 10.1016/j.elecom.2008.11.001
-
[3]
(3) Singh, B. S.; Lobo, H. R.; Shankarling, G. S. Catal. Commun. 2012, 24, 70. doi: 10.1016/j.catcom.2012.03.021
-
[4]
(4) Dai, Y.; Sprosen, J. V.; Witkamp, G. J.; Verpoorte, R.; Choi, Y. H. Anal. Chim. Acta 2013, 766, 61. doi: 10.1016/j.aca. 2012.12.019
-
[5]
(5) Francisco, M.; Bruinhorst, A. V. D.; Kroon, M. C. Angew. Chem. Int. Edit. 2013, 52, 3074. doi: 10.1002/anie.201207548
-
[6]
(6) Krystof, M.; Pérez-Sánchez, M.; María, P. D. D. ChemSusChem 2013, 6, 630. doi: 10.1002/cssc.201200931
-
[7]
(7) Maugeri, Z.; María, P. D. D. ChemCatChem 2014, 6, 1535.
-
[8]
(8) Serrano, M. C.; Gutiérrez, M. C.; Jiménez, R.; Ferrer, M. L.; Monte, F. D. Chem. Commun. 2012, 48, 579. doi: 10.1039/C1CC15284J
-
[9]
(9) Zhang, Z. H.; Zhang, X. N.; Mo, L. P.; Li, Y. X.; Ma, F. P. Green Chem. 2012, 14, 1502. doi: 10.1039/c2gc35258c
-
[10]
(10) Carriazo, D.; Gutirrez, M. C.; Pic, F.; Rojo, J. M.; Fierro, J. L. G.; Ferrer, M. L.; Monte, F. D. ChemSusChem 2012, 5, 1405. doi: 10.1002/cssc.v5.8
-
[11]
(11) Abbott, A. P.; Ttaib, K. E.; Frisch, G.; Ryder, K. S.; Weston, D. Phys. Chem. Chem. Phys. 2012, 14, 2443. doi: 10.1039/c2cp23712a
-
[12]
(12) Monte, F. D.; Carriazo, D.; Serrano, M. C.; Gutirrez, M. C.; Ferrer, M. L. ChemSusChem 2014, 7, 999. doi: 10.1002/cssc.201300864
-
[13]
(13) Abbott, A. P.; Cullis, P. M.; Gibson, M. J.; Harris, R. C.; Raven, E. Green Chem. 2007, 9, 868. doi: 10.1039/b702833d
-
[14]
(14) Shahbaz, K.; Mjalli, F. S.; Hashim, M. A.; AlNashef, I. M. Energy Fuels 2011, 25, 2671. doi: 10.1021/ef2004943
-
[15]
(15) Li, C. P.; Li, D.; Zou, S. S.; Li, Z.; Yin, J. M.; Wang, A. L.; Cui, Y. N.; Yao, Z. L.; Zhao, Q. Green Chem. 2013, 15, 2793. doi: 10.1039/c3gc41067f
-
[16]
(16) Abbott, A. P.; Capper, G.; Davias, D. L.; Rasheed, R. K.; Tambyrajah, V. Chem. Commun. 2003, 70, 70.
-
[17]
(17) Maugeri, Z.; María, P. D. D. RSC Adv. 2012, 2, 421. doi: 10.1039/C1RA00630D
-
[18]
(18) Ruß, C.; König, B. Green Chem. 2012, 14, 2969. doi: 10.1039/c2gc36005e
-
[19]
(19) Bahadori, L.; Manan, N. S.; Chakrabarti, M. H.; Hashim, M. A.; Mjalli, F. S.; AlNashef, I. M.; Hussain, M. A.; Low, C. T. J. Phys. Chem. Chem. Phys. 2013, 15, 1707. doi: 10.1039/C2CP43077K
-
[20]
(20) Liu, Q. S.; Yang, M.; Yan, P. F.; Liu, X. M.; Tan, Z. C.; Welz-Biermann, U. J. Chem. Eng. Data 2010, 55, 4928. doi: 10.1021/je100507n
-
[21]
(21) Liu, Q. S.; Li, P. P.; Welz-Biermann, U.; Chen, J.; Liu, X. X. J. Chem. Thermodyn. 2013, 66, 88. doi: 10.1016/j.jct.2013.06.008
-
[22]
(22) Chen, Y.; Zhuo, K.; Chen, J.; Bai, G. J. Chem. Thermodyn. 2015, 86, 13 doi: 10.1016/j.jct.2015.02.017
-
[23]
(23) Chen, Y.; Zhang, H.; Li, A.; Zhuo, K. Fluid Phase Equilibr. 2015, 388, 78. doi: 10.1016/j.fluid.2014.12.038
-
[24]
(24) Tong, J.; Hong, M.; Chen, Y.; Wang, H.; Guan, W.; Yang, J. Z. J. Chem. Thermodyn. 2012, 54, 352. doi: 10.1016/j.jct.2012.05.012
-
[25]
(25) Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRC Press: Boca Raton, FL, 2001-2002.
-
[26]
(26) Jacquemin, J.; Husson, P.; Padua, A. A. H.; Majer, V. Green Chem. 2006, 8, 172. doi: 10.1039/B513231B
-
[27]
(27) Glasser, L. Thermochim. Acta 2004, 421, 87. doi: 10.1016/j.tca.2004.03.015
-
[28]
(28) Vila, J.; Ginés, P.; Pico, J. M.; Franjo, C.; Jiménez, E.; Varela, L. M.; Cabeza, O. Fluid Phase Equilibr. 2006, 242, 141. doi: 10.1016/j.fluid.2006.01.022
-
[29]
(29) Schreiner, C.; Zugmann, S.; Hartl, R.; res, H. J. J. Chem. Eng. Data 2010, 55, 1784. doi: 10.1021/je900878j
-
[30]
(30) Belieres, J. P.; Angell, C. A. J. Phys. Chem. B 2007, 111, 4926. doi: 10.1021/jp067589u
-
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