Citation: SUN Xue-Mei, GAO Li-Jun. Preparation and Electrochemical Properties of Carbon-Coated CoCO₃ as an Anode Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1521-1526. doi: 10.3866/PKU.WHXB201506081 shu

Preparation and Electrochemical Properties of Carbon-Coated CoCO₃ as an Anode Material for Lithium Ion Batteries

SUN Xue-Mei ,
GAO Li-Jun

1.
College of Physics, Optoelectronics and Energy, Soochow University, Suzhou 215006, Jiangsu Province, P. R. China

Received Date: 12 December 2014
Available Online: 8 June 2015
Fund Project: 国家自然科学基金(U1401248)资助项目 (U1401248)

Diamond-shaped carbon-coated CoCO₃ (CoCO₃/C) particles were prepared by a simple hydrothermal method, and carbon coating was realized using glucose as the carbon source. This study focuses on the electrochemical performance of CoCO₃/C as an anode material. Its surface morphology and crystal lattice structure were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The content and structure of the carbon coating layer were further investigated by the thermogravimetry-differential thermal analysis (TG-DTA) technique and Raman spectroscopy. The pore size distribution was characterized using the Barrett-Joyner-Halenda (BJH) method. The results show that the carbon coating process creates not only a layer of amorphous carbon on the surface of CoCO₃, but also a porous structure with pore size of ~30 nm. The amorphous carbon layer enhances the structural stability during the charging and discharging process, and the porous structure facilitates the movement of ions in the electrolyte, and thus improves its electrochemical performance. When the cycling performance was tested for 500 cycles, this CoCO₃/C material maintained a capacity of 539 mAh·g^-1 at 0.90C (1.00C = mAh·g^-1), showing its excellent cycling capacity. When the current rate was increased to 3.00C, the capacity was 130 mAh·g^-1. When the current rate was returned to 0.15C, its capacity was 770 mAh·g^-1, demonstrating the great rate performance and stability of CoCO₃/C.
- CoCO₃,
- Li-ion battery,
- Carbon coating,
- Electrochemical performance,
- Anode material
1. [1]
  
  (1) Ding, P.; Xu, Y. L.; Sun, X. F. Acta Phys. -Chim. Sin. 2013, 29 (2), 293. [丁朋, 徐友龙, 孙孝飞. 物理化学学报, 2013, 29 (2), 293.]
2. [2]
  (2) Chen, S. Y.; Wang, Z. X.; Fang, X. P.; Zhao, H. L.; Liu, X. J.; Chen, L. Q. Acta Phys. -Chim. Sin. 2011, 27 (1), 97. [陈仕玉, 王兆翔, 房向鹏, 赵海雷, 刘效疆, 陈立泉. 物理化学学报, 2011, 27 (1), 97.] doi: 10.3866/PKU.WHXB20110134
3. [3]
  (3) He, P.; Yu, H. J.; Li, D.; Zhou, H. S. J. Mater. Chem. 2012, 22, 3680. doi: 10.1039/c2jm14305d
4. [4]
  (4) Broussely, M.; Archdale, G. J. Power Sources 2004, 136 (2), 386. doi: 10.1016/j.jpowsour.2004.03.031
5. [5]
  (5) Vu, A.; Qian, Y. Q.; Stein, A. Adv. Energy Mater. 2012, 2 (9), 1056. doi: 10.1002/aenm.v2.9
6. [6]
  (6) Shi, S. Q.; Zhang, H.; Ke, X. Z.; Ouyang, C. Y.; Lei, M. S.; Chen, L. Q. Phys. Lett. A 2009, 373 (44), 4096. doi: 10.1016/j.physleta.2009.09.014
7. [7]
  (7) Ouyang, C. Y.; Du, Y. L.; Shi, S. Q.; Lei, M. S. Phys. Lett. A 2009, 373 (31), 2796. doi: 10.1016/j.physleta.2009.05.071
8. [8]
  (8) Xu, J. B.; Gao, P.; Zhao, T. S. Energy Environ. Sci. 2012, 5, 5333. doi: 10.1039/C1EE01431E
9. [9]
  (9) Yang, W. C.; Bi, Y. J.; Yang, B. C.; Wang, D. Y.; Shi, S. Q. Acta Phys. -Chim. Sin. 2014, 30 (3), 460. [杨文超, 毕玉敬, 杨邦成, 王德宇, 施思齐. 物理化学学报, 2014, 30(3), 460.] doi: 10.3866/PKU.WHXB201401074
10. [10]
  (10) Li, C. C.; Yin, X. M.; Wang, T. H.; Zeng, H. C. Chem. Mater. 2009, 21 (20), 4984. doi: 10.1021/cm902126w
11. [11]
  (11) Luo, Y.; Luo, J.; Zhou, W.; Qi, X.; Zhang, H.; Yu, D. Y. W.; Li, C. M.; Fan, H. J.; Yu, T. J. Mater. Chem. A 2013, 1, 273. doi: 10.1039/C2TA00064D
12. [12]
  (12) Wang, B.; Zhu, T.; Wu, H. B.; Xu, R.; Chen, J. S.; Lou, X. W. Nanoscale 2012, 4, 2145. doi: 10.1039/c2nr11897a
13. [13]
  (13) Ren, Z. X.; Liu, T.; Sun, L. N.; Zhang, P. X.; Liu, J. H.; Zhang, Q. L. Acta Phys. -Chim. Sin. 2014, 31 (3), 1641. [任祥忠, 刘涛, 孙灵娜, 张培新, 刘剑洪, 张黔玲. 物理化学学报, 2014, 31 (3), 1641.] doi: 10.3866/PKU.WHXB201406172
14. [14]
  (14) Xiong, Q. Q.; Xia, X. H.; Tu, J. P.; Chen, J.; Zhang, Y. Q.; Zhou, D.; Gu, C. D.; Wang, X. L. J. Power Sources 2013240, 344. doi: 10.1016/j.jpowsour.2013.04.042
15. [15]
  (15) Aragón, M. J.; Pérez-Vicente, C.; Tirado, J. L. Electrochem. Commumn. 2007, 9 (7), 1744. doi: 10.1016/j.elecom.2007.03.031
16. [16]
  (16) Mirhashemihaghighi, S.; León, B.; Vicente, P. C.; Tirado, J. L.; Stoyanova, R.; Yoncheva, M.; Zhecheva, E.; Puche, R. S.; Arroyo, E. M.; Romero de Paz, J. Inorg. Chem.2012, 51 (10), 5554. doi: 10.1021/ic3004382
17. [17]
  (17) Su, L. W.; Zhou, Z.; Qin, X.; Tang, Q. W.; Wu, D. H.; Shen P. W. Nano Energy 2013, 2 (2), 276. doi: 10.1016/j. nanoen.2012.09.012
18. [18]
  (18) Ding, Z. J.; Yao, B.; Feng, J. K.; Zhang, J. X. J. Mater. Chem. A 20131, 11200. doi: 10.1039/c3ta12227a
19. [19]
  (19) Eshkenazi, V.; Peled, E.; Burstein, L.; lodnitsky, D. Solid State Ionics 2004, 170 (1-2), 83. doi: 10.1016/S0167-2738(03)00107-3
20. [20]
  (20) Wu, X. L.; Jiang, L. Y.; Cao, F. F.; Guo, Y. G.; Wan, L. J. Adv. Mater. 2009, 21 (25-26), 2710. doi: 10.1002/adma.v21:25/26
21. [21]
  (21) Wang, G. X.; Liu, H.; Liu, J.; Qiao, S. Z.; Lu, G. Q. M.; Munroe, P.; Ahn, H. J. Adv. Mater. 2010, 22 (44), 4944. doi: 10.1002/adma.v22.44
22. [22]
  (22) Belharouak, I.; Johnson, C.; Amine, K. Electrochem. Commum. 2005, 7 (10), 983. doi: 10.1016/j.elecom.2005.06.019
23. [23]
  (23) Zhao, S. Q.; Yu, Y.; Wei, S. S.; Wang, Y. X.; Zhao, C. H.; Liu, R.; Shen, Q. J. Power Sources 2014, 253, 251.
24. [24]
  (24) Su, L. W.; Zhou, Z.; Shen, P. W. Electrochim. Acta 2013, 87, 180. doi: 10.1016/j.electacta.2012.09.003
25. [25]
  (25) Ang, W. A.; Gupta, N.; Prasanth, R.; Madhavi, S. ACS Appl. Mater. Interfaces 2012, 4 (12), 7011. doi: 10.1021/am3022653
26. [26]
  (26) Laruelle, S.; Grugeon, S.; Poizot, P.; Dollé, M.; Dupont, L.; Tarascon, J. M. Electrochem. Soc. 2002, 149 (5), A627.
27. [27]
  (27) Liu, J. Z.; Ni, J. F.; Zhao, Y.; Wang, H. B.; Gao, L. J. J. Mater. Chem. A 2013, 1, 12879. doi: 10.1039/c3ta13141f
28. [28]
  (28) Ma, R. G.; He, L. F.; Lu, Z. G.; Yang, S. L.; Xi, L. J.; Chung, J. C. CrystEngComm 2012, 14, 7882. doi: 10.1039/c2ce26041g
29. [29]
  (29) Kang, Y. M.; Song, M. S.; Kim, J. H.; Kim, H. S.; Park, M. S.; Lee, J. Y.; Liu, H. K.; Dou, S. X. Electrochim. Acta 2005, 50 (18), 3667. doi: 10.1016/j.electacta.2005.01.012
30. [30]
  (30) Ponrouch, A.; Taberna, P. L.; Simon, P.; Pala??n, M. R. Electrochim. Acta 2012, 61, 13. doi: 10.1016/j.electacta.2011.11.029
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Properties of Carbon-Coated CoCO3 as an Anode Material for Lithium Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Properties of Carbon-Coated CoCO₃ as an Anode Material for Lithium Ion Batteries