Citation: ZHAO Jia, LIU Li-Feng, ZHANG Ying. Synthesis of Silver Nanoparticles Loaded onto a Structural Support and Their Catalytic Activity[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1549-1558. doi: 10.3866/PKU.WHXB201506021 shu

Synthesis of Silver Nanoparticles Loaded onto a Structural Support and Their Catalytic Activity

1.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062, P. R. China

Received Date: 16 February 2015
Available Online: 2 June 2015
Fund Project: 国家自然科学基金(21173141) (21173141)陕西省工业攻关项目(2011K08-14) (2011K08-14)教育部长江学者和创新团队发展计划滚动支持项目(IRT-14R33)资助 (IRT-14R33)

The core-shell type poly(styrene-N-isopropylacrylamide)/poly(N-isopropylacrylamide-co-3-methacryloxypropyltrimethoxysilane) (P(St-NIPAM)/P(NIPAM-co-MPTMS)) composite microgels with thermosensitivity were synthesized by two-step polymerization methods. Using P(St-NIPAM)/P(NIPAM-co-MPTMS) composite microgels modified by (3-mercaptopropyl) trimethoxysilane (MPS) as support material, Ag nanoparticles (AgNPs) were in-situ controllably synthesized using ethanol as a reducing regent. The structure, composition and properties of the prepared P(St-NIPAM)/P(NIPAM-co-MPTMS)-(SH)Ag composite materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fouriertransform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and UV-visible spectroscopy (UV-Vis). Additionally, the catalytic activity of the composite microgels was investigated using the reduction of 4-nitrophenol (4-NP) by NaBH₄ as a model reaction. The results showed that the dispersity of the in situ formed AgNPs was greatly improved because of the confining effect of the organic-inorganic microgel network with mercapto groups. Although the thermosensitivity of the composite microgels decreased because of the PNIPAM segments separated by the inorganic networks formed by MPTMS, the composite microgels still showed excellent catalytic performance and thermosensitivity in modulating the catalytic activity of AgNPs. These findings are related to the following aspects. The separated PNIPAM segments are favorable for mass transfer, and the networks with mercapto groups allow control of the size and local distribution of the in situ formed AgNPs. The present results are significant for construction of functional nanoscale metal catalytic materials.
- Organic-inorganic hybrid microgel,
- Thermo-sensitivity,
- Supported catalyst,
- Silver nanoparticles,
- 4-Nitrophenol reduction
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