Citation: ZHENG Zhao-Lei, LIANG Zhen-Long. Reduced Chemical Kinetic Model of a Gasoline Surrogate Fuel for HCCI Combustion[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1265-1274. doi: 10.3866/PKU.WHXB201505131 shu

Reduced Chemical Kinetic Model of a Gasoline Surrogate Fuel for HCCI Combustion

1.
Key Laboratory of Low-Grade Energy Utilization Technologies and Systems, Ministry of Education, Chongqing University, Chongqing 400044, P. R. China

Received Date: 13 January 2015
Available Online: 13 May 2015
Fund Project: 国家自然科学基金(51376202) (51376202)中央高校基本科研基金(CDJZR13145501)资助项目 (CDJZR13145501)

A new reduced chemical kinetic model that includes 103 species and 199 reactions is developed and used to describe the oxidation of a gasoline surrogate fuel consisting of n-heptane, iso-octane, toluene, and diisobutylene (DIB) for homogeneous charge compression ignition (HCCI). DIB is mainly consumed by Habstraction reactions by OH radicals to form three isomers, namely JC₈H₁₅- A, JC₈H₁₅- B, and JC₈H₁₅- D. Decomposition reaction is also one of the main reactions of DIB consumption, and this process forms two important C₄ products, namely TC₄H₉ and IC₄H₇. These products are the primary sources for CH₂O generation. The skeletal mechanism of toluene reference fuel (TRF) is based on the existing semi-detailed TRF mechanism developed by Andrae. The toluene and DIB sub-mechanism is developed using reaction path and sensitivity analyses. od agreements are achieved with the experimental ignition delays observed in a shock tube and an HCCI engine. The present reduced model has reliable performance for HCCI combustion simulations.
- Reaction mechanism,
- Gasoline surrogate,
- Ignition delay time,
- Reaction path,
- Homogeneous charge compression ignition
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沈阳化工大学材料科学与工程学院沈阳 110142