Citation: ZENG Yu-Qun, GUO Yong-Sheng, WU Bing-Bin, HONG Xiang, WU Kai, ZHONG Kai-Fu. Synthesis and Electrochemical Performance of Plastic Crystal Compound-Based Ionic Liquid[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1351-1358. doi: 10.3866/PKU.WHXB201505121 shu

Synthesis and Electrochemical Performance of Plastic Crystal Compound-Based Ionic Liquid

1.
Research Institute, Ningde Amperex Technology Limited, Ningde 352100, Fujian Province, P. R. China

Received Date: 22 December 2014
Available Online: 12 May 2015

Highly pure plastic crystal, 1-ethyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (P₁₂TFSI), was synthesized and purified by an easily industrializable recrystallization method. The P₁₂TFSI/LiFSI ionic liquid was obtained by mixing P₁₂TFSI with 30% (molar fraction, x) LiFSI. Electrochemical characterization methods including cyclic voltammetry, constant voltage polarization and charge/discharge at constant current were used to investigate the electrochemical window, stability vs Al corrosion, and battery performance of the ionic liquid.Awide electrochemical window of 5.00 V, non-corrosion of theAl current collector, and 0.92mS·cm^-1 of ionic conductivity at room temperature were observed. LiCoO₂/Li batteries assembled using this ionic liquid electrolyte showed od charge-discharge characteristics and cycle performance, comparable with those of carbonate-based electrolyte at low rate. The specific capacity of the LiCoO₂ remained 175 mAh·g^-1 after 20 cycles (95.1% capacity retention) despite cycling at a high voltage up to 4.50 V. These results indicate that the plastic crystal-based ionic liquid P₁₂TFSI/LiFSI could be potentially applied in high-energy density lithium secondary batteries.
- Lithium ion battery,
- Plastic crystal,
- Ionic liquid,
- Pyrrolidinium,
- High voltage
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