Citation: ZENG Yu-Qun, GUO Yong-Sheng, WU Bing-Bin, HONG Xiang, WU Kai, ZHONG Kai-Fu. Synthesis and Electrochemical Performance of Plastic Crystal Compound-Based Ionic Liquid[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1351-1358. doi: 10.3866/PKU.WHXB201505121 shu

Synthesis and Electrochemical Performance of Plastic Crystal Compound-Based Ionic Liquid

1.
Research Institute, Ningde Amperex Technology Limited, Ningde 352100, Fujian Province, P. R. China

Received Date: 22 December 2014
Available Online: 12 May 2015

Highly pure plastic crystal, 1-ethyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (P₁₂TFSI), was synthesized and purified by an easily industrializable recrystallization method. The P₁₂TFSI/LiFSI ionic liquid was obtained by mixing P₁₂TFSI with 30% (molar fraction, x) LiFSI. Electrochemical characterization methods including cyclic voltammetry, constant voltage polarization and charge/discharge at constant current were used to investigate the electrochemical window, stability vs Al corrosion, and battery performance of the ionic liquid.Awide electrochemical window of 5.00 V, non-corrosion of theAl current collector, and 0.92mS·cm^-1 of ionic conductivity at room temperature were observed. LiCoO₂/Li batteries assembled using this ionic liquid electrolyte showed od charge-discharge characteristics and cycle performance, comparable with those of carbonate-based electrolyte at low rate. The specific capacity of the LiCoO₂ remained 175 mAh·g^-1 after 20 cycles (95.1% capacity retention) despite cycling at a high voltage up to 4.50 V. These results indicate that the plastic crystal-based ionic liquid P₁₂TFSI/LiFSI could be potentially applied in high-energy density lithium secondary batteries.
- Lithium ion battery,
- Plastic crystal,
- Ionic liquid,
- Pyrrolidinium,
- High voltage
1. [1]
  
  (1) Dunn, B.; Kamath, H.; Tarascon, J. M. Science 2011, 334, 928. doi: 10.1126/science.1212741
2. [2]
  (2) Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a
3. [3]
  (3) Samad, Y. A.; Asghar, A.; Hashaikeh, R. Renewable Energy 2013, 56, 90. doi: 10.1016/j.renene.2012.09.015
4. [4]
  (4) Ren, X. Z.; Liu, T.; Sun, L. N.; Zhang, P. X. Acta Phys. -Chim. Sin. 2014, 30 (9), 1641. [任祥忠, 刘涛, 孙灵娜, 张培新.物理化学学报, 2014, 30 (9), 1641.] doi: 10.3866/PKU.WHXB201406172
5. [5]
  (5) Xue, Q. R.; Li, J. L.; Xu, G. F.; Hou, P. F.; Yan, G.; Dai, Y.; Wang, X. D.; Gao, F. Acta Phys. -Chim. Sin. 2014, 30 (9), 1667. [薛庆瑞, 李建玲, 徐国峰, 侯朋飞, 晏刚, 代宇, 王新东, 高飞. 物理化学学报, 2014, 30 (9), 1667.] doi: 10.3866/PKU.WHXB201406251
6. [6]
  (6) Armand, M.; Endres, F.; MacFarlane, D. R.; Ohno, H.; Scrosati, B. Nat. Mater. 2009, 8, 621. doi: 10.1038/nmat2448
7. [7]
  (7) Galinski, M.; Lewandowski, A.; Stepniak, I. Electrochim. Acta 2006, 51, 5567. doi: 10.1016/j.electacta.2006.03.016
8. [8]
  (8) Papageorgiou, N.; Athanassov, Y.; Armand, M.; Bonhote, P.; Pettersson, H.; Azam, A.; Grätzel, M. J. Electrochem. Soc. 1996, 143, 3099.
9. [9]
  (9) Fung, Y. S.; Zhou, R. Q. J. Power Sources 1999, 81/82, 891.
10. [10]
  (10) Henderson, W. A.; Young, V. G.; Fox, D. M. Chem. Commun. 2006, No. 12, 3708.
11. [11]
  (11) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. Chem. -Eur. J. 2006, 12 (8), 2196.
12. [12]
  (12) Domanska, U.; Królikowskaa, M.; Paduszynski, K. Fluid Phase Equilib. 2011, 303, 1. doi: 10.1016/j.fluid.2010.12.008
13. [13]
  (13) Matsumoto, H.; Terasawa, N.; Umecky, T. Chem. Lett. 2008, 37, 1020. doi: 10.1246/cl.2008.1020
14. [14]
  (14) Liu, Q. S.; Yan, P. F.; Yang, M.; Tan, Z. C.; Li, C. P.; Urs, W. B. Acta Phys. -Chim. Sin.2011, 27 (12), 2762. [刘青山, 颜佩芳, 杨淼, 谭志诚, 李长平, Urs, W. B. 物理化学学报, 2011, 27 (12), 2762.] doi: 10.3866/PKU.WHXB20112762
15. [15]
  (15) Sakaebe, H.; Matsumoto, H. Electrochem. Commun. 2003, 5, 594. doi: 10.1016/S1388-2481(03)00137-1
16. [16]
  (16) Matsumoto, H.; Sakaebe, H.; Tatsumi, K.; Kikuta, M.; Ishiko, E.; Kono, M. J. Power Sources 2006, 160, 1308. doi: 10.1016/j.jpowsour.2006.02.018
17. [17]
  (17) Borgel, V.; Markevich, E.; Aurbach, D.; Semraub, G. J. Power Sources 2009, 189, 331. doi: 10.1016/j.jpowsour.2008.08.099
18. [18]
  (18) Henderson, W. A.; Passerini, S. Chem. Mater. 2004, 16, 2881. doi: 10.1021/cm049942j
19. [19]
  (19) MacFarlane, D. R.; Huang, J. H.; Forsyth, M. Nature 1999, 402, 792. doi: 10.1038/45514
20. [20]
  (20) MacFarlane, D. R.; Sun, J.; Forsyth, M.; Meakin, P.; Amini, N. J. Phys. Chem. 1999, 103, 4164. doi: 10.1021/jp984145s
21. [21]
  (21) Sun, J.; Forsyth, M.; MacFarlane, D. R. J. Phys. Chem. 1998, 102, 8858. doi: 10.1021/jp981159p
22. [22]
  (22) Sylla, S.; Sanchez, J. Y.; Armand, M. Electrochim. Acta 1992, 37, 1699. doi: 10.1016/0013-4686(92)80141-8
23. [23]
  (23) Henderson, W. A.; Young, V. G.; Passerini, S.; Trulove, P. C. Chem. Mater. 2006, 18, 934. doi: 10.1021/cm051936f
24. [24]
  (24) Efthimiadis, J.; Pas, S. J.; Forsyth, M. Solid State Ionics 2002, 154-155, 279.
25. [25]
  (25) Awaludin, Z.; Okajima, T.; Ohsaka, T. Electrochem. Commun. 2013, 31, 100. doi: 10.1016/j.elecom.2013.03.020
26. [26]
  (26) Zhang, S. S.; Jow, T. R. J. Power Sources 2002, 109, 458. doi: 10.1016/S0378-7753(02)00110-6
27. [27]
  (27) Miao, R. R.; Yang, J.; Feng, X. J.; Jia, H.; Wang, J. L.; Nuli, Y. N. J. Power Sources 2014, 271, 291.
28. [28]
  (28) Lewandowski, A.; ?widerska -Mocek, A.; Acznik, I. Electrochim. Acta 2010, 55, 1990.
1. [1]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
2. [2]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
5. [5]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
6. [6]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
9. [9]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
10. [10]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
11. [11]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
12. [12]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
13. [13]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
14. [14]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
15. [15]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
16. [16]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
17. [17]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
18. [18]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
19. [19]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
20. [20]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032

Get Citation

PDF

XML

Metrics

PDF Downloads(299)
Abstract views(584)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142