Citation: SHI Chen-Yang, HE Hui-Bin, HONG Zan-Fa, ZHAN Hong-Bing, FENG Miao. Effect of HCl Post-Treatment on Morphology of Hydrothermally Prepared Titanate Nanomaterials with Optical Limiting Properties[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1430-1436. doi: 10.3866/PKU.WHXB201505112 shu

Effect of HCl Post-Treatment on Morphology of Hydrothermally Prepared Titanate Nanomaterials with Optical Limiting Properties

1.
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, P. R. China

Received Date: 3 April 2015
Available Online: 11 May 2015
Fund Project: 国家自然科学基金(51172045, 51402051) (51172045, 51402051)教育部高校博士点基金(20113514120006)资助项目 (20113514120006)

The effect of post-treatment HCl concentration on titanate-titania transformation was investigated. Titanate was prepared by the alkaline hydrothermal treatment of TiO₂, and then transformed to titania/titanate upon subsequent washing with 0.10-0.55 mol·L^-1 HCl. The titanate almost completely transformed to rutile when treated with HCl concentrations>0.78 mol·L^-1. Accompanying this phase transformation, the morphology of the sample changed from nanotubes to nanosheets and nanoparticles. This was related to the rate of phase transformation, which depended on the HCl concentration. Titanate became resolved into detached TiO₆ octahedra during HCl treatment, and titanate-titania transformation occurred via rearrangement of the TiO₆ octahedra. The phase transformation and morphological evolution were studied by X- ray diffraction, and transmission and scanning electron microscopies. The linear and nonlinear optical properties of the products were investigated using ultraviolet-visible absorption spectroscopy and the open aperture Z-scan technique, respectively. The minimum transmittance at Z=0 and maximum optical limiting effect were obtained when the HCl concentration was 0.55 mol·L^-1. Different nonlinear optical effects were exhibited by different morphologies.
- Acid treatment,
- Titanium dioxide,
- Morphology,
- Phase transformation,
- Nonlinear optical property
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