Citation: SHI Chen-Yang, HE Hui-Bin, HONG Zan-Fa, ZHAN Hong-Bing, FENG Miao. Effect of HCl Post-Treatment on Morphology of Hydrothermally Prepared Titanate Nanomaterials with Optical Limiting Properties[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1430-1436. doi: 10.3866/PKU.WHXB201505112 shu

Effect of HCl Post-Treatment on Morphology of Hydrothermally Prepared Titanate Nanomaterials with Optical Limiting Properties

1.
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, P. R. China

Received Date: 3 April 2015
Available Online: 11 May 2015
Fund Project: 国家自然科学基金(51172045, 51402051) (51172045, 51402051)教育部高校博士点基金(20113514120006)资助项目 (20113514120006)

The effect of post-treatment HCl concentration on titanate-titania transformation was investigated. Titanate was prepared by the alkaline hydrothermal treatment of TiO₂, and then transformed to titania/titanate upon subsequent washing with 0.10-0.55 mol·L^-1 HCl. The titanate almost completely transformed to rutile when treated with HCl concentrations>0.78 mol·L^-1. Accompanying this phase transformation, the morphology of the sample changed from nanotubes to nanosheets and nanoparticles. This was related to the rate of phase transformation, which depended on the HCl concentration. Titanate became resolved into detached TiO₆ octahedra during HCl treatment, and titanate-titania transformation occurred via rearrangement of the TiO₆ octahedra. The phase transformation and morphological evolution were studied by X- ray diffraction, and transmission and scanning electron microscopies. The linear and nonlinear optical properties of the products were investigated using ultraviolet-visible absorption spectroscopy and the open aperture Z-scan technique, respectively. The minimum transmittance at Z=0 and maximum optical limiting effect were obtained when the HCl concentration was 0.55 mol·L^-1. Different nonlinear optical effects were exhibited by different morphologies.
- Acid treatment,
- Titanium dioxide,
- Morphology,
- Phase transformation,
- Nonlinear optical property
1. [1]
  
  (1) Chung, I.; Lee, B.; He, J.; Chang, R. P. H.; Kanatzidis, M. G. Nature 2012, 485 (7399), 486. doi: 10.1038/nature11067
2. [2]
  (2) Xia, T.; Zhang, W.; Murowchick, J.; Liu, G.; Chen, X. Nano Lett. 2013, 13 (11), 5289. doi: 10.1021/nl402810d
3. [3]
  (3) Liu, M.; Qiu, X.; Miyauchi, M.; Hashimoto, K. Chem. Mater. 2011, 23 (23), 5282. doi: 10.1021/cm203025b
4. [4]
  (4) Yang, D. J.; Zheng, Z. F.; Zhu, H. Y.; Liu, H.W.; Gao, X. P. Adv. Mater. 2008, 20 (14), 2777. doi: 10.1002/adma.v20:14
5. [5]
  (5) Xia, T.; Zhang, C.; Oyler, N. A.; Chen, X. Adv. Mater. 2013, 25 (47), 6905. doi: 10.1002/adma.v25.47
6. [6]
  (6) Rajh, T.; Dimitrijevic, N. M.; Bissonnette, M.; Koritarov, T.; Konda, V. Chem. Rev. 2014, 114 (19), 10177. doi: 10.1021/cr500029g
7. [7]
  (7) Bavykin, D. V.; Walsh, F. C. Eur. J. Inorg. Chem. 2009, 2009
8. [8]
  (8), 977. doi: 10.1002/ejic.v2009:8 (8) Zhang, H.; Banfield, J. F. Chem. Rev. 2014, 114 (19), 9613. doi: 10.1021/cr500072j
9. [9]
  (9) Xiao, Y. M.; Wu, J. H.; Yue, G. T.; Liu, J. M.; Huang, M. L.; Fan, L. Q.; Lan, Z. Acta Phys .-Chim Sin. 2012, 28 (3), 578. [肖尧明, 吴季怀, 岳根田, 林建明, 黄妙良, 范乐庆, 兰章. 物理化学学报, 2012, 28 (3), 578.]
10. [10]
  (10) Liu, C.; Miao, L.; Zhou, J.; Huang, R.; Fisher, C. A.; Tanemura, S. J. Phys. Chem. C 2013, 117 (22), 11487. doi: 10.1021/jp401132g
11. [11]
  (11) Maeda, K. ACS Catal. 2014, 4 (6), 1632. doi: 10.1021/cs500159a
12. [12]
  (12) Boppana, V. B. R.; Lobo, R. F. J. Catal. 2011, 281 (1), 156. doi: 10.1016/j.jcat.2011.04.014
13. [13]
  (13) Yang, D.; Sarina, S.; Zhu, H.; Liu, H.; Zheng, Z.; Xie, M.; Smith, S. V.; Komarneni, S. Angew. Chem. Int. Edit. 2011, 50 (45), 10594. doi: 10.1002/anie.201103286
14. [14]
  (14) Wang, L.; Sasaki, T. Chem. Rev. 2014, 114 (19), 9455. doi: 10.1021/cr400627u
15. [15]
  (15) Fukuda, K.; Ebina, Y.; Shibata, T.; Aizawa, T.; Nakai, I.; Sasaki, T. J. Am. Chem. Soc. 2007, 129 (1), 202. doi: 10.1021/ja0668116
16. [16]
  (16) Zhao, B.; Lin, L.; He, D. J. Mater. Chem. A 2013, 1 (5), 1659. doi: 10.1039/C2TA00755J
17. [17]
  (17) Zhu, H. Y.; Lan, Y.; Gao, X. P.; Ringer, S. P.; Zheng, Z. F.; Song, D. Y.; Zhao, J. J. Am. Chem. Soc. 2005, 127 (18), 6730. doi: 10.1021/ja044689+
18. [18]
  (18) Yang, M.; Chen, P.; Tsai, M.; Chen, T.; Chang, I.; Chiu, H.; Lee, C. CrystEngComm 2014, 16 (3), 441. doi: 10.1039/C3CE41750F
19. [19]
  (19) Murakami, N.; Kamai, T.; Tsubota, T.; Ohno, T. CrystEngComm 2010, 12 (2), 532. doi: 10.1039/B913586N
20. [20]
  (20) Morgan, D. L.; Liu, H.; Frost, R. L.; Waclawik, E. R. J. Phys. Chem. C 2009, 114 (1), 101.
21. [21]
  (21) Bavykin, D. V.; Kulak, A. N.; Walsh, F. C. Cryst. Growth Des. 2010, 10 (10), 4421.
22. [22]
  (22) Tsai, C.; Teng, H. Chem. Mater. 2006, 18 (2), 367. doi: 10.1021/cm0518527
23. [23]
  (23) Suetake, J.; Nosaka, A. Y.; Hodouchi, K.; Matsubara, H.; Nosaka, Y. J. Phys. Chem. C 2008, 112 (47), 18474. doi: 10.1021/jp8069223
24. [24]
  (24) Bavykin, D. V.; Friedrich, J. M.; Lapkin, A. A.; Walsh, F. C. Chem. Mater. 2006, 18 (5), 1124. doi: 10.1021/cm0521875
25. [25]
  (25) Hong, Z.; Xu, Y.; Liu, Y.; Wei, M. Chem. Eur. J. 2012, 18 (34), 10753. doi: 10.1002/chem.v18.34
26. [26]
  (26) Shieh, D.; Chen, P.; Lin, J. Mater. Chem. Phys. 2012, 134 (2), 1020.
27. [27]
  (27) You, W.; Feng, M.; Zhan, Y.; Chen, R.; Zhan, H. Chem. Eng. J. 2013, 233, 360. doi: 10.1016/j.cej.2013.08.047
28. [28]
  (28) Chen, Y.; Hanack, M.; Araki, Y.; Ito, O. Chem. Soc. Rev. 2005, 34 (6), 517. doi: 10.1039/b416368k
29. [29]
  (29) Chen, J.; Wang, S. Q.; Yang, G. Q. Acta Phys. -Chim Sin. 2015, 31 (4), 595. [陈军, 王双青, 杨国强. 物理化学学报, 2015, 31 (4), 595.]
30. [30]
  (30) Feng, M.; Zhan, H.; Chen, Y. Appl. Phys. Lett. 2010, 96 (3), 33107. doi: 10.1063/1.3279148
31. [31]
  (31) Philip, R.; Chantharasupawong, P.; Qian, H.; Jin, R.; Thomas, J. Nano Lett. 2012, 12 (9), 4661. doi: 10.1021/nl301988v
32. [32]
  (32) Jia, W. L.; Douglas, E. P.; Guo, F. G.; Sun, W. F. Appl. Phys. Lett. 2004, 85 (26), 6326. doi: 10.1063/1.1836871
33. [33]
  (33) Feng, M.; Zhan, H.; Miao, L. Nanotechnology 2010, 21 (18), 185707. doi: 10.1088/0957-4484/21/18/185707
34. [34]
  (34) Jiao, Y.; Zhao, B.; Chen, F.; Zhang, J. CrystEngComm 2011, 13 (12), 4167. doi: 10.1039/c0ce00932f
35. [35]
  (35) Yin, H.; Wada, Y.; Kitamura, T.; Kambe, S.; Murasawa, S.; Mori, H.; Sakata, T.; Yanagida, S. J. Mater. Chem. 2001, 11 (6), 1694. doi: 10.1039/b008974p
36. [36]
  (36) Yan, M.; Chen, F.; Zhang, J. Chem. Lett. 2004, 33 (10), 1352. doi: 10.1246/cl.2004.1352
37. [37]
  (37) Miyauchi, M.; Liu, Z.; Zhao, Z.; Anandan, S.; Tokudome, H. Langmuir 2009, 26 (2), 796.
38. [38]
  (38) Gateshki, M.; Yin, S.; Ren, Y.; Petkov, V. Chem. Mater. 2007, 19 (10), 2512. doi: 10.1021/cm0630587
39. [39]
  (39) Mao, Y.; Wong, S. S. J. Am. Chem. Soc. 2006, 128 (25), 8217. doi: 10.1021/ja0607483
40. [40]
  (40) Burdett, J. K.; Hughbanks, T.; Miller, G. J.; Richardson J.W., Jr.; Smith, J. V. J. Am. Chem. Soc. 1987, 109 (12), 3639. doi: 10.1021/ja00246a021
41. [41]
  (41) Wen, P.; Ishikawa, Y.; Itoh, H.; Feng, Q. J. Phys. Chem. C 2009, 113 (47), 20275. doi: 10.1021/jp908181e
42. [42]
  (42) Wen, P.; Itoh, H.; Tang, W.; Feng, Q. Langmuir 2007, 23 (23), 11782. doi: 10.1021/la701632t
43. [43]
  (43) Wang, J.; Chen, Y.; Blau, W. J. J. Mater. Chem. 2009, 19 (40), 7425. doi: 10.1039/b906294g
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