Citation: XU Zhen, CHEN Yu, ZHANG Zhao, ZHANG Jian-Qing. Progress of Research on Underpotential Deposition—— I. Theory of Underpotential Deposition[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1219-1230. doi: 10.3866/PKU.WHXB201505071 shu

Progress of Research on Underpotential Deposition—— I. Theory of Underpotential Deposition

1.
1 Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China;
2 Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China

Received Date: 23 March 2015
Available Online: 7 May 2015
Fund Project: 国家自然科学基金(21273199, 21073162) (21273199, 21073162)教育部博士点基金(20130101110047)项目资助 (20130101110047)

Underpotential deposition (upd) has been a hotspot in the field of electrochemical research throughout the years owing to its significant theoretical and applied research value. Theoretical research on upd primarily centers around the relations and rules of interaction among deposition substrates, deposition species, and anions (or other organic additives) during upd process. In this paper, the developments in theoretical research in recent years on upd on both the local and international levels are systematically summarized mainly from two viewpoints, namely, thermodynamics and kinetics. With regard to the thermodynamics of upd process, introductory comments and mathematical formulas are summarized from four aspects, i.e., underpotential shift (ΔE_upd), electrosorption valency (γ), influence of temperature, and electrochemical adsorption isotherms. The applications and analyses of those related mathematical formulas are also presented in detail. In terms of the kinetics of upd process, nucleation and growth phenomena are mainly presented. We summarize the relevant mathematical models, and additionally introduce research studies on the characteristics of upd kinetics based on these mathematical models. Furthermore, this paper presents an outline of computational chemistry methods and application achievements concerning upd research. Finally, the theoretical research status of upd is presented, giving an overall view of the development trend.
- Electrochemistry,
- Underpotential deposition,
- Thermodynamics,
- Kinetics,
- Computational chemistry
1. [1]
  
  (1) Pangarov, N. Electrochim. Acta 1983, 28 (6), 763. doi: 10.1016/0013-4686(83)85145-7
2. [2]
  (2) Huang, M. H.; Henry, J. B.; Fortgang, P.; Henig, J.; Plumeré, N.; Bandarenka, A. S. RSC Adv. 2012, 2 (29), 10994. doi: 10.1039/c2ra21558f
3. [3]
  (3) Hevesy, G. V. Physik. Z. 1912, 13, 715.
4. [4]
  (4) Xing, X. K.; Bae, I. T.; Scherson, D. A. Electrochim. Acta 1995, 40 (1), 29. doi: 10.1016/0013-4686(94)00251-U
5. [5]
  (5) Zhu, W.; Yang, J. Y.; Zhou, D. X.; Bao, S. Q.; Fan, X. A.; Duan, X. K. Electrochim. Acta 2007, 52 (11), 3660. doi: 10.1016/j.electacta.2006.10.028
6. [6]
  (6) Kondo, T.; Takakusagi, S.; Uosaki, K. Electrochem. Commun. 2009, 11 (4), 804. doi: 10.1016/j.elecom.2009.01.036
7. [7]
  (7) Kirowa-Eisner, E.; Bonfil, Y.; Tzur, D.; Gileadi, E. J. Electroanal. Chem. 2003, 552, 171. doi: 10.1016/S0022-0728 (03)00181-5
8. [8]
  (8) Paddon, C. A.; Compton, R. G. J. Phys. Chem. C 2007, 111 (26), 9016. doi: 10.1021/jp073304h
9. [9]
  (9) Fu, Y. C.; Yan, J.W.; Wang, Y.; Tian, J. H.; Zhang, H. M.; Xie, Z. X.; Mao, B.W. J. Phys. Chem. C 2007, 111 (28), 10467. doi: 10.1021/jp0711621
10. [10]
  (10) Gasparotto, L. H. S.; Borisenko, N.; Bocchi, N.; El Abedin, S. Z.; Endres, F. Phys. Chem. Chem. Phys. 2009, 11 (47), 11140. doi: 10.1039/b916809e
11. [11]
  (11) Rosário, A. V.; Santos, M. C.; Mascaro, L. H.; Bulhões, L. O. S.; Pereira, E. C. Thin Solid Films 2010, 518 (10), 2669. doi: 10.1016/j.tsf.2009.08.035
12. [12]
  (12) Bouamrane, F.; Tadjeddine, A.; Tenne, R.; Butler, J. E.; Kalish, R.; Levy-Clement, C. J. Phys. Chem. B 1998, 102 (1), 134. doi: 10.1021/jp971516g
13. [13]
  (13) Su, X.; Zhan, X.; Hinds, B. J. J. Mater. Chem. 2012, 22 (16), 7979. doi: 10.1039/c2jm15395e
14. [14]
  (14) Lastraioli, E.; Loglio, F.; Innocenti, M.; Carlà, F.; Foresti, M. L. ECS Trans. 2010, 25 (34), 17. doi: 10.1149/1.3335488
15. [15]
  (15) Zhang, X.; Shi, X. Z.; Ye, W. C.; Ma, C. L.; Wang, C. M. Appl. Phys. A: Mater. Sci. Process. 2009, 94 (2), 381. doi: 10.1007/s00339-008-4815-5
16. [16]
  (16) Biçer, M.; Ayd1n, A. O.; ?i?man, ?. Electrochim. Acta 2010, 55 (11), 3749. doi: 10.1016/j.electacta.2010.02.015
17. [17]
  (17) Loglio, F.; Innocenti, M.; Jarek, A.; Caporali, S.; Pasquini, I.; Foresti, M. L. J. Electroanal. Chem. 2010, 638 (1), 15. doi: 10.1016/j.jelechem.2009.10.027
18. [18]
  (18) Alanyal?o?lu, M.; Bayrakçeken, F.; Demir, Ü. Electrochim. Acta 2009, 54 (26), 6554. doi: 10.1016/j.electacta.2009.06.056
19. [19]
  (19) Gao, L. X.; Wang, L. N.; Qi, T.; Yu, J. Acta Phys. -Chim. Sin. 2012, 28 (1), 111. [高丽霞, 王丽娜, 齐涛, 余江. 物理化学学报, 2012, 28 (1), 111.] doi: 10.3866/PKU.WHXB201228111
20. [20]
  (20) Li, M.; Sun, T. T.; Liu, B.; Han, W.; Sun, Y.; Zhang, M. L. Acta Phys. -Chim. Sin. 2015, 31 (2), 309. [李梅, 孙婷婷, 刘斌, 韩伟, 孙杨, 张密林. 物理化学学报, 2015, 31 (2), 309.] doi: 10.3866/PKU.WHXB201412182
21. [21]
  (21) Xue, Y.; Zhou, Z. P.; Yan, Y. D.; Zhang, M. L.; Li, X.; Ji, D. B.; Han, W.; Zhang, M. Acta Phys. -Chim. Sin. 2014, 30 (9), 1674. [薛云, 周志萍, 颜永得, 张密林, 李星, 纪德彬, 韩伟, 张萌. 物理化学学报, 2014, 30 (9), 1674.] doi: 10.3866/PKU.WHXB201407022
22. [22]
  (22) Nicic, I.; Liang, J.; Cammarata, V.; Alanyalioglu, M.; Demir, U.; Shannon, C. J. Phys. Chem. B 2002, 106 (47), 12247. doi: 10.1021/jp026625w
23. [23]
  (23) Hölzle, M. H.; Retter, U.; Kolb, D. M. J. Electroanal. Chem. 1994, 371 (1-2), 101. doi: 10.1016/0022-0728(93)03235-H
24. [24]
  (24) Sibert, E.; Wang, L.; De Santis, M.; Soldo-Olivier, Y. Electrochim. Acta 2014, 135, 594. doi: 10.1016/j.electacta.2014.04.168
25. [25]
  (25) Lamy-Pitara, E.; Elouazzani-Benhima, L.; Barbier, J.; Cahoreau, M.; Caisso, J. J. Electroanal. Chem. 1994, 372 (1-2), 233. doi: 10.1016/0022-0728(93)03256-O
26. [26]
  (26) Garcia, S. G.; Salinas, D. R.; Staikov, G. Surf. Sci. 2005, 576 (1-3), 9. doi: 10.1016/j.susc.2004.11.037
27. [27]
  (27) Hepel, M.; Kanige, K.; Bruckenstein, S. Langmuir 1990, 6 (6), 1063. doi: 10.1021/la00096a006
28. [28]
  (28) Sackmann, J.; Bunk, A.; Pötzschke, R. T.; Staikov, G.; Lorenz, W. J. Electrochim. Acta 1998, 43 (19-20), 2863. doi: 10.1016/S0013-4686(98)00027-9
29. [29]
  (29) Mendoza-Huizar, L. H.; Robles, J.; Palomar - Pardavé, M. J. Electroanal. Chem. 2002, 521 (1-2), 95. doi: 10.1016/S0022-0728(02)00659-9
30. [30]
  (30) Mendoza-Huizar, L. H.; Robles, J.; Palomar - Pardavé, M. J. Electroanal. Chem. 2003, 545, 39. doi: 10.1016/S0022-0728(03)00087-1
31. [31]
  (31) Staikov, G.; García, S. G.; Salinas, D. R. ECS Trans. 2010, 25 (34), 3. doi: 10.1149/1.3335487
32. [32]
  (32) Popov, B. N.; Zheng, G.; White, R. E. Corrosion Sci. 1994, 36 (12), 2139. doi: 10.1016/0010-938X(94)90012-4
33. [33]
  (33) Zheng, G.; Popov, B. N.; White, R. E. J. Electrochem. Soc. 1994, 141 (5), 1220. doi: 10.1149/1.2054899
34. [34]
  (34) Kazemi, R.; Kiani, A. Int. J. Hydrog. Energy 2012, 37 (5), 4098. doi: 10.1016/j.ijhydene.2011.11.147
35. [35]
  (35) Kuttiyiel, K. A.; Sasaki, K.; Choi, Y.; Su, D.; Liu, P.; Adzic, R. R. Energy Environ. Sci. 2012, 5 (1), 5297. doi: 10.1039/c1ee02067f
36. [36]
  (36) Liu, J. P.; Zhou, H. H.; Huang, J. T.; Huang, Z. Y.; Zeng, F. Y.; Kuang, Y. F. Int. J. Hydrog. Energy 2012, 37 (22), 16764. doi: 10.1016/j.ijhydene.2012.08.130
37. [37]
  (37) Ni?anc?, F. B.; Öznülüer, T.; Demir, Ü. Electrochim. Acta 2013, 108, 281. doi: 10.1016/j.eleetacta.2013.06.135
38. [38]
  (38) Köse, H.; Biçer, M.; Tütüno?lu, Ç.; Ayd?n, A. O.; ?i?man, ?. Electrochim. Acta 2009, 54 (6), 1680. doi: 10.1016/j.electacta.2008.09.059
39. [39]
  (39) ?i?man, ?.; Demir, Ü. J. Electroanal. Chem. 2011, 651 (2), 222. doi: 10.1016/j.jelechem.2010.12.005
40. [40]
  (40) Herzog, G.; Arrigan, D.W. M. Electroanalysis 2003, 15 (15-16), 1302. doi: 10.1002/elan.200302812
41. [41]
  (41) Herzog, G.; Arrigan, D.W. M. TrAC, Trends Anal. Chem. 2005, 24 (3), 208. doi: 10.1016/j.trac.2004.11.014
42. [42]
  (42) Orozco, J.; Fernández - Sánchez, C.; Jiménez - Jorquera, C. Environ. Sci. Technol. 2008, 42 (13), 4877. doi: 10.1021/es8005964
43. [43]
  (43) Huang, J. F. Talanta 2009, 77 (5), 1694. doi: 10.1016/j.talanta.2008.10.005
44. [44]
  (44) Sivasubramanian, R.; Sangaranarayanan, M. V. Talanta 2011, 85 (4), 2142. doi: 10.1016/j.talanta.2011.07.057
45. [45]
  (45) Oyamatsu, D.; Kanemoto, H.; Kuwabata, S.; Yoneyama, H. J. Electroanal. Chem. 2001, 497 (1-2), 97. doi: 10.1016/S0022-0728(00)00459-9
46. [46]
  (46) Lin, S. Y.; Tsai, T. K.; Lin, C. M.; Chen, C. H.; Chan, Y. C.; Chen, H.W. Langmuir 2002, 18 (14), 5473. doi: 10.1021/la0157364
47. [47]
  (47) Gebregziabiher, D. K.; Kim, Y. G.; Thambidurai, C.; Ivanova, V.; Haumesser, P. H.; Stickney, J. L. J. Cryst. Growth 2010, 312 (8), 1271. doi: 10.1016/j.jcrysgro.2009.11.038
48. [48]
  (48) Lin, S. X.; Shi, X. Z.; Zhang, X.; Kou, H. H.; Wang, C. M. Appl. Surf. Sci. 2010, 256 (13), 4365. doi: 10.1016/j.apsusc.2010.02.032
49. [49]
  (49) Innocenti, M.; Bellandi, S.; Lastraioli, E.; Loglio, F.; Foresti, M. Langmuir 2011, 27 (18), 11704. doi: 10.1021/la202174j
50. [50]
  (50) Innocenti, M.; Zangari, G.; Zafferoni, C.; Bencistà, I.; Becucci, L.; Lavacchi, A.; Di Benedetto, F.; Bellandi, S.; Vizza, F.; Foresti, M. L. J. Power Sources 2013, 241, 80. doi: 10.1016/j.jpowsour.2013.04.111
51. [51]
  (51) Wang, M. Y.; Wang, Z.; Guo, Z. C. Acta Phys.-Chim. Sin. 2009, 25 (5), 883. [王明涌, 王志, 郭占成. 物理化学学报, 2009, 25 (5), 883.] doi: 10.3866/PKU.WHXB20090511
52. [52]
  (52) Herrero, E.; Buller, L. J.; Abruna, H. D. Chem. Rev. 2001, 101 (1), 1897. doi: 10.1021/cr9600363
53. [53]
  (53) Anjos, D. M.; Rigsby, M. A.; Wieckowski, A. J. Electroanal. Chem. 2010, 639 (1-2), 8. doi: 10.1016/j.jelechem.2009.10.003
54. [54]
  (54) Sudha, V.; Sangaranarayanan, M. V. J. Phys. Chem. B 2002, 106 (10), 2699. doi: 10.1021/jp013544b
55. [55]
  (55) Sudha, V.; Sangaranarayanan, M. V. J. Phys. Chem. B 2003, 107 (16), 3907. doi: 10.1021/jp027818m
56. [56]
  (56) Sudha, V.; Sangaranarayanan, M. V. J. Chem. Sci. 2005, 117 (3), 207. doi: 10.1007/BF02709289
57. [57]
  (57) Kolb, D. M.; Przasnyski, M.; Gerischer, H. J. Electroanal. Chem. Interfacial Electrochem. 1974, 54 (1), 25. doi: 10.1016/0368-1874(74)85093-8
58. [58]
  (58) Campbell, F.W.; Compton, R. G. Int. J. Electrochem. Sci 2010, 5 (3), 407.
59. [59]
  (59) Campbell, F.W.; Zhou, Y. G.; Compton, R. G. New J. Chem. 2010, 34 (2), 187. doi: 10.1039/b9nj00669a
60. [60]
  (60) Zhou, Y. G.; Rees, N. V.; Compton, R. G. ChemPhysChem 2011, 12 (11), 2085. doi: 10.1002/cphc.201100282
61. [61]
  (61) Schultze, J.W.; Vetter, K. J. J. Electroanal. Chem. Interfacial Electrochem. 1973, 44 (1), 63.
62. [62]
  (62) Swathirajan, S.; Bruckenstein, S. J. Electrochem. Soc. 1982, 129 (6), 1202. doi: 10.1149/1.2124087
63. [63]
  (63) Swathirajan, S.; Bruckenstein, S. Electrochim. Acta 1983, 28 (7), 865. doi: 10.1016/0013-4686(83)85162-7
64. [64]
  (64) Swathirajan, S.; Bruckenstein, S. J. Electroanal. Chem. Interfacial Electrochem. 1983, 146 (1), 137. doi: 10.1016/S0022-0728(83)80117-X
65. [65]
  (65) Szabó, S. Int. Rev. Phys. Chem. 1991, 10 (2), 207. doi: 10.1080/01442359109353258
66. [66]
  (66) Ad?i?, R. R.; Minevski, L. V. Electrochim. Acta 1987, 32 (1), 125. doi: 10.1016/0013-4686(87)87020-2
67. [67]
  (67) Salie, G.; Bartels, K. Electrochim. Acta 1994, 39 (8-9), 1057. doi: 10.1016/0013-4686(94)E0020-Z
68. [68]
  (68) Santos, M. C.; Mascaro, L. H.; Machado, S. A. S. Electrochim. Acta 1998, 43 (16-17), 2263. doi: 10.1016/S0013-4686(97)10171-2
69. [69]
  (69) de Levie, R. J. Electroanal. Chem. 2004, 562 (2), 273. doi: 10.1016/j.jelechem.2003.08.027
70. [70]
  (70) Zolfaghari, A.; Jerkiewicz, G. J. Electroanal. Chem. 1999, 467 (1-2), 177. doi: 10.1016/S0022-0728(99)00084-4
71. [71]
  (71) Radovic-Hrapovic, Z.; Jerkiewicz, G. J. Electroanal. Chem. 2001, 499 (1), 61. doi: 10.1016/S0022-0728(00)00478-2
72. [72]
  (72) Zolfaghari, A.; Jerkiewicz, G. J. Electroanal. Chem. 1997, 422 (1-2), 1. doi: 10.1016/S0022-0728(97)00001-6
73. [73]
  (73) Abaci, S.; Zhang, L. S.; Shannon, C. J. Electroanal. Chem. 2004, 571 (2), 169. doi: 10.1016/j.jelechem.2004.05.006
74. [74]
  (74) Vra?ar, L.; Krstaji?, N.; Neophytides, S. G.; Jakši?, J. Int. J. Hydrog. Energy 2004, 29 (8), 835. doi: 10.1016/S0360-3199(03)00154-X
75. [75]
  (75) Blais, S.; Jerkiewicz, G.; Herrero, E.; Feliu, J. M. J. Electroanal. Chem. 2002, 519 (1-2), 111. doi: 10.1016/S0022-0728(01)00735-5
76. [76]
  (76) Jerkiewicz, G.; Perreault, F.; Radovic-Hrapovic, Z. J. Phys. Chem. C 2009, 113 (28), 12309. doi: 10.1021/jp900478u
77. [77]
  (77) Etzel, K. D.; Bickel, K. R.; Schuster, R. Rev. Sci. Instrum. 2010, 81 (3), 034101. doi: 10.1063/1.3309785
78. [78]
  (78) Schuster, R.; Rösch, R.; Timm, A. E. Z. Phys. Chem. 2007, 221 (11-12), 1479. doi: 10.1524/zpch.2007.221.11-12.1479
79. [79]
  (79) Etzel, K. D.; Bickel, K. R.; Schuster, R. ChemPhysChem 2010, 11 (7), 1416. doi: 10.1002/cphc.200900981
80. [80]
  (80) Swathirajan, S.; Mizota, H.; Bruckenstein, S. J. Phys. Chem. 1982, 86 (13), 2480. doi: 10.1021/j100210a048
81. [81]
  (81) Lasia, A. J. Electroanal. Chem. 2004, 562 (1), 23. doi: 10.1016/j.jelechem.2003.07.033
82. [82]
  (82) Chun, J. H.; Ra, K. H.; Kim, N. Y. Int. J. Hydrog. Energy 2001, 26 (9), 941. doi: 10.1016/S0360-3199(01)00028-3
83. [83]
  (83) Markovic, N. M.; Grgur, B. N.; Ross, P. N. J. Phys. Chem. B 1997, 101 (27), 5405. doi: 10.1021/jp970930d
84. [84]
  (84) Chang, B. Y.; Ahn, E.; Park, S. M. J. Phys. Chem. C 2008, 112 (43), 16902. doi: 10.1021/jp805960j
85. [85]
  (85) Zolfaghari, A.; Jerkiewicz, G.; Chrzanowski, W.; Wieckowski, A. J. Electrochem. Soc. 1999, 146 (11), 4158. doi: 10.1149/1.1392607
86. [86]
  (86) Zinola, C. F.; Rodríguez, J. J. Solid State Electrochem. 2002, 6 (6), 412. doi: 10.1007/s100080100242
87. [87]
  (87) Quaiyyum, M. D.; Aramata, A.; Moniwa, S.; Taguchi, S.; Enyo, M. J. Electroanal. Chem. 1994, 373 (1-2), 61. doi: 10.1016/0022-0728(94)03268-8
88. [88]
  (88) Palomar - Pardavé, M.; nzález, I.; Batina, N. J. Phys. Chem. B 2000, 104 (15), 3545. doi: 10.1021/jp9931861
89. [89]
  (89) Arbib, M.; Zhang, B.; Lazarov, V.; Stoychev, D.; Milchev, A.; Buess-Herman, C. J. Electroanal. Chem. 2001, 510 (1-2), 67. doi: 10.1016/S0022-0728(01)00545-9
90. [90]
  (90) Palomar-Pardavé, M.; Garfias-García, E.; Romero-Romo, M.; Ramírez-Silva, M. T.; Batina, N. Electrochim. Acta 2011, 56 (27), 10083. doi: 10.1016/j.electacta.2011.08.105
91. [91]
  (91) Quayum, M. E.; Ye, S.; Uosaki, K. J. Electroanal. Chem. 2002, 520 (1-2), 126. doi: 10.1016/S0022-0728(02)00643-5
92. [92]
  (92) Palomar-Pardavé, M.; nzález, I.; Soto, A. B.; Arce, E. M. J. Electroanal. Chem. 1998, 443 (1), 125. doi: 10.1016/S0022-0728(97)00496-8
93. [93]
  (93) Armstrong, R. D.; Harrison, J. A. J. Electrochem. Soc. 1969, 116 (3), 328. doi: 10.1149/1.2411839
94. [94]
  (94) Guo, L.; Hu, K.; Li, W. P.; Zhang, S. T. Chin. J. Appl. Chem. 2013, 30 (2), 214. [郭雷, 胡舸, 李文坡, 张胜涛. 应用化学, 2013, 30 (2), 214.] doi: 10.3724/SP.J.1095.2013.20090
95. [95]
  (95) Alanyal?o?lu, M.; Çakal, H.; Öztürk, A. E.; Demir, Ü. J. Phys. Chem. B 2001, 105 (43), 10588. doi: 10.1021/jp004227s
96. [96]
  (96) Hölzle, M. H.; Zwing, V.; Kolb, D. M. Electrochim. Acta 1995, 40 (10), 1237. doi: 10.1016/0013-4686(95)00055-J
97. [97]
  (97) Martínez-Ruíz, A.; Palomar-Pardavé, M.; Valenzuela-Benavides, J.; Farías, M. H.; Batina, N. J. Phys. Chem. B 2003, 107 (42), 11660. doi: 10.1021/jp027197x
98. [98]
  (98) Mendoza-Huizar, L. H.; Rios-Reyes, C. H. J. Solid State Electrochem. 2011, 15 (4), 737. doi: 10.1007/s10008-010-1146-1
99. [99]
  (99) Leiva, E. Electrochim. Acta 1996, 41 (14), 2185. doi: 10.1016/0013-4686(96)00050-3
100. [100]
  (100) Sanchez, C. G.; Del Popolo, M. G.; Leiva, E. P. M. Surf. Sci. 1999, 421 (1-2), 59. doi: 10.1016/S0039-6028(98)00818-8
101. [101]
  (101) Sanchez, C. G.; Leiva, E. P. M.; Kohanoff, J. Langmuir 2001, 17 (7), 2219. doi: 10.1021/la001639j
102. [102]
  (102) Oviedo, O. A.; Leiva, E. P. M.; Rojas, M.I. Electrochim. Acta 2006, 51 (17), 3526. doi: 10.1016/j.electacta.2005.10.008
103. [103]
  (103) Guo, L.; Tan, J. H.; Li, W. P.; Hu, K.; Zhang, S. T. Prog. Chem. 2013, 25 (11), 1842. [郭雷, 谭建红, 李文坡, 胡舸, 张胜涛. 化学进展, 2013, 25 (11), 1842.] doi: 10.7536/PC130148
104. [104]
  (104) Újfalussy, B.; Szunyogh, L.; Bruno, P.; Weinberger, P. Phys. Rev. lett. 1996, 77 (9), 1805. doi: 10.1103/PhysRevLett.77.1805
105. [105]
  (105) Oviedo, O. A.; Leiva, E. P. M.; Mariscal, M. M. Phys. Chem. Chem. Phys. 2008, 10 (24), 3561. doi: 10.1039/b801838c
106. [106]
  (106) Oviedo, O. A.; Mariscal, M. M.; Leiva, E. P. M. Electrochim. Acta 2010, 55 (27), 8244. doi: 10.1016/j.electacta.2010.03.059
107. [107]
  (107) Mariscal, M. M.; Oviedo, O. A.; Leiva, E. P. M. J. Mater. Res. 2012, 27 (14), 1777. doi: 10.1557/jmr.2012.132
108. [108]
  (108) Oviedo, O. A.; Negre, C. F. A.; Mariscal, M. M.; Sánchez, C. G.; Leiva, E. P. M. Electrochem. Commun. 2012, 16 (1), 1. doi: 10.1016/j.elecom.2011.12.013
109. [109]
  (109) Oviedo, O. A.; Reinaudi, L.; Leiva, E. P. M. Electrochem. Commun. 2012, 21, 14. doi: 10.1016/j.elecom.2012.05.001
110. [110]
  (110) Oviedo, O. A.; Reinaudi, L.; Mariscal, M. M.; Leiva, E. P. M. Electrochim. Acta 2012, 76, 424. doi: 10.1016/j.electacta.2012.05.055
1. [1]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
2. [2]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
3. [3]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
4. [4]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
5. [5]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
6. [6]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
7. [7]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
8. [8]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
9. [9]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
10. [10]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
11. [11]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
12. [12]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
13. [13]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
14. [14]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
15. [15]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
16. [16]
  Xiaohui Li , Ze Zhang , Jingyi Cui , Juanjuan Yin . Advanced Exploration and Practice of Teaching in the Experimental Course of Chemical Engineering Thermodynamics under the “High Order, Innovative, and Challenging” Framework. University Chemistry, 2024, 39(7): 368-376. doi: 10.3866/PKU.DXHX202311027
17. [17]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
18. [18]
  Qian Huang , Zhaowei Li , Jianing Zhao , Ao Yu . Quantum Chemical Calculations Reveal the Details Below the Experimental Phenomenon. University Chemistry, 2024, 39(3): 395-400. doi: 10.3866/PKU.DXHX202309018
19. [19]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
20. [20]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001

Get Citation

PDF

XML

Metrics

PDF Downloads(607)
Abstract views(914)
HTML views(118)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142