Citation: GAO Shuang, YAN Jian-Biao, CONG De-Quan, SUI Qiang-Sheng, XIA Yan-Yang, CHENG Dong-Dong, BAO Qiang, WANG Zhen-Lü, WANG Li-Yan. Preparation of Sn-Modified Ru/H-CMK-3 Catalysts and Their Application in the Hydrogenation of Cinnamaldehyde[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1391-1398. doi: 10.3866/PKU.WHXB201504303 shu

Preparation of Sn-Modified Ru/H-CMK-3 Catalysts and Their Application in the Hydrogenation of Cinnamaldehyde

1.
Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received Date: 12 February 2015
Available Online: 30 April 2015
Fund Project: 国家自然科学基金(21473074) (21473074)吉林省科技攻关计划重点科技攻关项目(20150204020GX) (20150204020GX)吉林省科技厅自然科学基金项目(20130101015JC)资助 (20130101015JC)

Tin-promoted Ru/H-CMK-3 catalysts were prepared by a novel reductant-impregnation method for application in the hydrogenation of cinnamaldehyde. The catalysts were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface areas, X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). The effects of the synthesis reaction conditions on the selective hydrogenation of cinnamaldehyde were examined in detail. The results showed that the mesoporous CMK-3 carbon material could disperse the catalytically active species better. Using appropriate amounts of Sn(IV) provided electron-rich Ru sites, which are one of the main catalytically active species. The interaction between Ru and Sn promoted the activation of C＝O in cinnamaldehyde. Furthermore, changes in other reaction conditions, such as temperature and pressure, greatly influenced the selective hydrogenation of cinnamaldehyde.
- Ruthenium,
- Mesoporous carbon,
- Cinnamaldehyde,
- Cinnamyl alcohol,
- Catalytic hydrogenation
1. [1]
  
  (1) Chambers, A.; Jackson, S. D.; Stirling, D.; Webb, G. J. Catal. 1997, 168, 301. doi: 10.1006/jcat.1997.1683
2. [2]
  (2) Chen, X. F.; Li, H. X.; Dai, W. L.; Wang, J.; Ran, Y.; Qiao, M. H. Appl. Catal. A 2003, 253, 359. doi: 10.1016/S0926-860X(03)00544-1
3. [3]
  (3) Marehi, A. J.; rdo, D. A.; Trasarti, A. F.; APesteguia, C. R. Appl. Catal. A 2003, 249, 53. doi: 10.1016/S0926-860X(03)00199-6
4. [4]
  (4) Michalska, Z. M.; Ostaszewski, B.; Zientarska, J.; Rynkowski, J. M. J. Mol. Catal. 2002, 185, 279. doi: 10.1016/S1381-1169(02)00124-3
5. [5]
  (5) Loffreda, D.; Delbecq, F.; Vigne, F.; Sautet, P. J. Am. Chem. Soe. 2006, 128, 1316. doi: 10.1021/ja056689v
6. [6]
  (6) Poltarzewski, Z.; Galvagno, S.; Pietropaolo, R.; Staiti, P. J. Catal. 1986, 102, 190. doi: 10.1016/0021-9517(86)90153-3
7. [7]
  (7) Reyes, P.; Pecchi, G.; Fierro, J. L. G. Langmuir 2001, 17, 522. doi: 10.1021/la0006418
8. [8]
  (8) Mki-Arvela, P.; Hájek, J.; Salmi, T. Appl. Catal. A 2005, 292, 1. doi: 10.1016/j.apcata.2005.05.045
9. [9]
  (9) Zhang, Y. K.; Liao, S. J.; Xu, Y. Appl. Catal. A 2000, 192, 247. doi: 10.1016/S0926-860X(99)00400-7
10. [10]
  (10) Li, H.; Yang, H. X.; Li, H. X. J. Catal. 2007, 251, 233. doi: 10.1016/j.jcat.2007.07.022
11. [11]
  (11) Vu, H.; ncalves, F.; Philippe, R.; Lamouroux, E.; Corrias, M.; Kihn, Y.; Plee, D.; Kalck, P.; Serp, P. J. Catal. 2006, 240, 18. doi: 10.1016/j.jcat.2006.03.003
12. [12]
  (12) Samant, P. V.; Pereira, M. F. R.; Figueiredo, J. L. Catal. Today 2005, 102, 183.
13. [13]
  (13) Andrea, B. M.; Bruno, F. M.; Virginia, V.; Joaquim, L. F.; Mónica, L. C. Appl. Catal. A. 2010, 383, 43.
14. [14]
  (14) Eveline, B.; Roel, P.; Jeroen, A. Catal. Commun. 2007, 8, 1397. doi: 10.1016/j.catcom.2006.11.040
15. [15]
  (15) Hajek, J.; Kumar, N.; Maki-Arvela, P.; Salmi, T. Appl. Catal. A 2003, 251, 385. doi: 10.1016/S0926-860X(03)00345-4
16. [16]
  (16) Jan, H.; Narendra, K.; Päivi, M.; Tapio, S.; Dmitry, Y. M. J. Mol. Catal. A: Chem. 2004, 217, 145. doi: 10.1016/j.molcata.2004.03.015
17. [17]
  (17) Riguetto, B. A.; Rodrigues, C. E. C.; Morales, M. A. Appl. Catal. A: Gen. 2007, 318, 70. doi: 10.1016/j.apcata.2006.10.045
18. [18]
  (18) Jan, H.; Narendra, K.; Tapio, S. Ind. Eng. Chem. Res. 2003, 42, 295. doi: 10.1021/ie020419t
19. [19]
  (19) Ryoo, R.; Joo, S. H.; Kruk, M.; Jaroniec, M. Adv. Mater. 2001, 13, 677. doi: 10.1002/1521-4095(200105)13:9<>1.0.CO;2-3
20. [20]
  (20) Lee, J.; Kim, J.; Hyeon, T. Adv. Mater. 2006, 18, 2073.
21. [21]
  (21) Liang, C.; Li, Z.; Dai, S. Angew. Chem. Int. Edit. 2008, 47, 3696.
22. [22]
  (22) Wan, Y.; Shi, Y.; Zhao, D. Chem. Mater. 2008, 20, 932. doi: 10.1021/cm7024125
23. [23]
  (23) Geng, L. L.; Zhang, X. Y.; Zhang, W. X.; Jia, M. J.; Liu, G. Chem. Commun. 2014, 50, 2965. doi: 10.1039/c3cc47332e
24. [24]
  (24) Jun, S.; Joo, S. H.; Ryoo, R. J. Am. Chem. Soc. 2000, 122, 10712. doi: 10.1021/ja002261e
25. [25]
  (25) Zhuang, X.; Wan, Y.; Feng, C.; Shen, Y.; Zhao, D. Chem. Mater. 2009, 21, 706. doi: 10.1021/cm8028577
26. [26]
  (26) Lota, G.; Grzyb, B.; Machnikowska, H.; Machnikowski, J.; Frackowiak, E. Chem. Phys. Lett. 2005, 404, 1. doi: 10.1016/j.cplett.2005.01.034
27. [27]
  (27) Zhao, S. L.; Liang, H. D.; Zhou, Y. F. Catal. Commun. 2007, 8, 1305. doi: 10.1016/j.catcom.2006.11.033
28. [28]
  (28) Ji, H. B.; Huang, Y. Y.; Pei, L. X.; Yao, X. D. Catal. Commun. 2008, 9, 27. doi: 10.1016/j.catcom.2007.05.012
29. [29]
  (29) Luo, G.; Yan, S. R.; Qiao, M. H.; Fan, K. G. Appl. Catal. A: Gen 2007, 332, 79. doi: 10.1016/j.apcata.2007.08.007
30. [30]
  (30) Andrea, B. M.; Bruno, F. M.; Virginia, V.; Joaquim, L. F.; Mónica, L. C. Appl. Catal. A: Gen 2010, 383, 43. doi: 10.1016/j.apcata.2010.05.020
1. [1]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
4. [4]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
5. [5]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
6. [6]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
7. [7]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
8. [8]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
9. [9]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
10. [10]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
11. [11]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
12. [12]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
13. [13]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
14. [14]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
15. [15]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
16. [16]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
17. [17]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
18. [18]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
19. [19]
  Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO₂-Involved Carbon Cycle World. University Chemistry, 2024, 39(5): 144-153. doi: 10.3866/PKU.DXHX202309084
20. [20]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020

Get Citation

PDF

XML

Metrics

PDF Downloads(260)
Abstract views(353)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142