Citation: JIAO Jin-Zhen, LI Shi-Hui, HUANG Bi-Chun. Preparation of Manganese Oxides Supported on Graphene Catalysts and Their Activity in Low-Temperature NH₃-SCR[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1383-1390. doi: 10.3866/PKU.WHXB201504292 shu

Preparation of Manganese Oxides Supported on Graphene Catalysts and Their Activity in Low-Temperature NH₃-SCR

1.
1 College of Environment and Energy, South China University of Technology, Guangzhou 510006, P. R. China;
2 Key Laboratory of the Ministry of Education for Pollution Control and Ecosystem Restoration in Industry Clusters, South China University of Technology, Guangzhou 510006, P. R. China

Received Date: 7 January 2015
Available Online: 29 April 2015
Fund Project: 国家自然科学基金(51478191)资助项目 (51478191)

Graphene oxide ( ) was synthesized using an improved Hummers method. Subsequently, catalysts of manganese oxides (at varying loadings) supported on graphene (MnO_x/GR) were prepared by hydrothermal reaction for application in the selective catalytic reduction (SCR) of NO_x with NH₃ at low temperatures. The structural properties and catalytic performance were evaluated by Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), N₂ adsorption-desorption, X-ray photoelectron spectroscopy (XPS), and H₂ temperature-programmed reduction (H₂-TPR). The characterization results indicated that abundant functional groups existed on the surface of the prepared that could combine with manganese during preparation of the catalysts. Manganese oxide entities, with different crystallinities (MnO, Mn₃O₄, or MnO₂), were dispersed on the surface of graphene. The results of the catalytic studies showed that the MnO_x/GR catalysts prepared with different MnO_x loadings all exhibited excellent low-temperature SCR activities. The catalyst with 20%(w) MnO_x displayed the best activity, which was attributed to the high content of high-valent manganese and oxygen adsorbed onto the catalyst surface, as well as to the enhancement in redox abilities and the addition of active sites at low temperatures.
- Selective catalytic reduction,
- Nitrogen oxide,
- Graphene,
- Graphene oxide,
- Manganese oxide
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Manganese Oxides Supported on Graphene Catalysts and Their Activity in Low-Temperature NH3-SCR

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通讯作者: 陈斌, bchen63@163.com

Preparation of Manganese Oxides Supported on Graphene Catalysts and Their Activity in Low-Temperature NH₃-SCR