Citation: WANG Hao, SONG Ling-Jun, LI Xing-Hu, YUE Li-Meng. Hydrogen Production from Partial Oxidation of Methane by Dielectric Barrier Discharge Plasma Reforming[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1406-1412. doi: 10.3866/PKU.WHXB201504272 shu

Hydrogen Production from Partial Oxidation of Methane by Dielectric Barrier Discharge Plasma Reforming

1.
School of Transportation Science and Engineering, Beihang University, Beijing 100191, P. R. China

Received Date: 23 January 2015
Available Online: 27 April 2015
Fund Project: 国家自然科学基金(21106002) (21106002)中央高校基本科研业务费专项资金(2011113073)资助项目 (2011113073)

This paper presents an in-house-designed dielectric barrier discharge (DBD) plasma reformer for hydrogen production via partial oxidation reforming of methane. We examined the effects of oxygen/carbon (O/C) molar ratio, feed flow rate, discharge gap, discharge zone length, filler diameter, filler shape, filler materials, discharge voltage, and discharge frequency on the hydrogen production performance i.e., CH₄ conversion rate, H₂ yield, and selectivity of products (H₂, CO, and CO₂). The experimental results showed that the parameters of the discharge zone played an important role in the CH₄ conversion rate. For instance, CH₄ conversion rate increased with increasing discharge zone lengths. When the discharge zone length increased from 5 to 20 cm, CH₄ conversion rate increased from 6.87% to 22.26%, which corresponds to an improvement of 224%. Also, the fillers in the discharge zone strongly influenced the hydrogen production performance. Using reactors with fillers generated higher CH₄ conversion rates. Moreover, using fillers with more appropriate dielectric constants is advantageous for practical application. The H₂ yield and hydrogen selectivity increased with increasing discharge frequency. Specifically, when the discharge frequency increased from 1.5 to 7.0 kHz, H₂ yield increased from 1.10% to 9.49%, and hydrogen selectivity increased from 21.18% to 30.06%. It is believed that the current results would serve as a od guideline in hydrogen production from hydrocarbon fuels by plasma reforming.
- Dielectric barrier discharge,
- Reforming,
- Hydrogen production,
- Plasma,
- Methane,
- Partial oxidation
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