Citation: WANG Hao, SONG Ling-Jun, LI Xing-Hu, YUE Li-Meng. Hydrogen Production from Partial Oxidation of Methane by Dielectric Barrier Discharge Plasma Reforming[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1406-1412. doi: 10.3866/PKU.WHXB201504272 shu

Hydrogen Production from Partial Oxidation of Methane by Dielectric Barrier Discharge Plasma Reforming

1.
School of Transportation Science and Engineering, Beihang University, Beijing 100191, P. R. China

Received Date: 23 January 2015
Available Online: 27 April 2015
Fund Project: 国家自然科学基金(21106002) (21106002)中央高校基本科研业务费专项资金(2011113073)资助项目 (2011113073)

This paper presents an in-house-designed dielectric barrier discharge (DBD) plasma reformer for hydrogen production via partial oxidation reforming of methane. We examined the effects of oxygen/carbon (O/C) molar ratio, feed flow rate, discharge gap, discharge zone length, filler diameter, filler shape, filler materials, discharge voltage, and discharge frequency on the hydrogen production performance i.e., CH₄ conversion rate, H₂ yield, and selectivity of products (H₂, CO, and CO₂). The experimental results showed that the parameters of the discharge zone played an important role in the CH₄ conversion rate. For instance, CH₄ conversion rate increased with increasing discharge zone lengths. When the discharge zone length increased from 5 to 20 cm, CH₄ conversion rate increased from 6.87% to 22.26%, which corresponds to an improvement of 224%. Also, the fillers in the discharge zone strongly influenced the hydrogen production performance. Using reactors with fillers generated higher CH₄ conversion rates. Moreover, using fillers with more appropriate dielectric constants is advantageous for practical application. The H₂ yield and hydrogen selectivity increased with increasing discharge frequency. Specifically, when the discharge frequency increased from 1.5 to 7.0 kHz, H₂ yield increased from 1.10% to 9.49%, and hydrogen selectivity increased from 21.18% to 30.06%. It is believed that the current results would serve as a od guideline in hydrogen production from hydrocarbon fuels by plasma reforming.
- Dielectric barrier discharge,
- Reforming,
- Hydrogen production,
- Plasma,
- Methane,
- Partial oxidation
1. [1]
  
  (1) http://www.chinairn.com/news/20140211/085433111.html
2. [2]
  (2) Li, X. H. Conspectus of Electric Vehicle; Beijing Institute of Technology Press: Beijing, 2005; pp 1-5. [李兴虎. 电动汽车概论. 北京: 北京理工大学出版社, 2005: 1-5.]
3. [3]
  (3) Horng, R. F.; Wen, C. S.; Liauh, C. T.; Chao, Y.; Huang, C. T. Int. J. Hydrog. Energy 2008, 33 (24), 7619. doi: 10.1016/j.ijhydene.2008.09.078
4. [4]
  (4) Bisaria, V.; Smith, R. J. B. Energy Convers. Manage 2013, No.76, 746.
5. [5]
  (5) Bowers, B. J.; Zhao, J. L.; Ruffo, M.; Khan, R.; Dattatraya, D.; Dushman, N.; Beziat, J. C.; Boudjemaa, F. Int. J. Hydrog. Energy 2007, 32 (10-11), 1437. doi: 10.1016/j.ijhydene.2006.10.045
6. [6]
  (6) Noor, T.; Gil, M. V.; Chen, D. Appl. Catal. B-Environ. 2014, No. 150-151, 585.
7. [7]
  (7) Li, J.; Zhang, Q. J.; Long, X.; Qi, P.; Liu, Z. T.; Liu, Z.W. Chem. Eng. J. 2012, No. 187, 299.
8. [8]
  (8) Chen, M. N.; Zhang, D. Y.; Thompson, L. T.; Ma, Z. F. Acta Phys. -Chim. Sin. 2011, 27 (9), 2185. [陈孟楠, 章冬云, Thompson, L. T., 马紫峰. 物理化学学报, 2011, 27 (9), 2185.] doi: 10.3866/PKU.WHXB20110824
9. [9]
  (9) Yang, Z. B.; Zhang, Y.W.; Zhang, Y. Y.; Ding, W. Z.; Shen, P. J.; Liu, Y.; Zhou, Y. D.; Huang, S. Q. Acta Phys. -Chim. Sin. 2010, 26 (2), 350. [杨志彬, 张玉文, 张云妍, 丁伟中, 沈培俊, 刘勇, 周宇鼎, 黄少卿. 物理化学学报, 2010, 26 (2), 350.] doi: 10.3866/PKU.WHXB20100212
10. [10]
  (10) Du, C. M.; Mo, J. M.; Tang, J.; Huang, D.W.; Mo, Z. X.; Wang, Q. K.; Ma, S. Z.; Chen, Z. J. Appl. Energy 2014, 133 (15), 70.
11. [11]
  (11) Bundaleska, N.; Tsyganov, D.; Saavedra, R.; Tatarova, E.; Dias, F. M.; Ferreira, C.M. Int. J. Hydrog. Energy 2013, 38 (22), 9145. doi: 10.1016/j.ijhydene.2013.05.016
12. [12]
  (12) Chaubey, R.; Sahu, S.; James, O. O.; Maity, S. Renew. Sust. Energ. Rev. 2013, No. 23, 443.
13. [13]
  (13) Bromberg, L.; Cohn, D. R.; Hadidi, K.; Heywood, J. B.; Rabinovich, A. Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications. Diesel Engine Emission Reduction (DEER)Workshop, Coronado, CA, Aug 29-Sept 2, 2004.
14. [14]
  (14) Zou, J. J.; Zhang, Y. P.; Liu, C. J. Int. J. Hydrog. Energy 2007, 32 (8), 958. doi: 10.1016/j.ijhydene.2006.09.023
15. [15]
  (15) Song, L. J.; Li, X. H.; Zheng, T. L. Int. J. Hydrog. Energy 2008, 33 (19), 5060. doi: 10.1016/j.ijhydene.2008.07.090
16. [16]
  (16) Rueangjitt, N.; Sreethawong, T.; Chavadej, S.; Sekiguchi, H. Chem. Eng. J. 2009, 155 (3), 874. doi: 10.1016/j.cej.2009.10.009
17. [17]
  (17) Tao, J. L.; Xiong, Y. Q. Acta Phys. -Chim. Sin. 2013, 29 (1), 205. [陶晶亮, 熊源泉. 物理化学学报, 2013, 29 (1), 205.] doi: 10.3866/PKU.WHXB201210264
18. [18]
  (18) Deng, W. Y.; Su, Y. X.; Liu, S. G.; Shen, H. G. Int. J. Hydrog. Energy 2014, 39 (17), 9169. doi: 10.1016/j.ijhydene.2014.04.033
19. [19]
  (19) Xu, C.; Tu, X. J. Energy Chem. 2013, 22 (3), 420. doi: 10.1016/S2095-4956(13)60055-8
20. [20]
  (20) Hooshmand, N.; Rahimpour, M. R.; Jahanmiri, A.; Taghvaei, H.; Mohamadzadeh, S. M. Ind. Eng. Chem. Res. 2013, 52 (12), 4443. doi: 10.1021/ie3022779
21. [21]
  (21) Tu, X.; Whitehead, J. C. Appl. Catal. B-Environ. 2012, No. 125, 439.
22. [22]
  (22) Reddy, E. L.; Biju, V. M.; Subrahmanyam, C. Int. J. Hydrog. Energy 2012, 37 (3), 2204. doi: 10.1016/j.ijhydene.2011.10.118
23. [23]
  (23) Lee, D. H.; Kim, K. T.; Cha, M. S.; Song, Y. H. Int. J. Hydrog. Energy 2010, 35 (20), 10967. doi: 10.1016/j.ijhydene.2010.07.029
24. [24]
  (24) York, A. P. E.; Xiao, T. C.; Green, M. L. H. Top. Catal. 2003, 22 (3-4), 345.
25. [25]
  (25) Liu, C. M. Common Thermal Parameters Manual; China Metrology Publishing House: Beijing, 1989; p 537. [刘常满. 常用热工参数手册. 北京: 中国计量出版社, 1989: 537.]
1. [1]
  Mingjie Lei , Wenting Hu , Kexin Lin , Xiujuan Sun , Haoshen Zhang , Ye Qian , Tongyue Kang , Xiulin Wu , Hailong Liao , Yuan Pan , Yuwei Zhang , Diye Wei , Ping Gao . Co/Mn/Mo掺杂加速NiSe₂重构以提高其电催化尿素氧化性能. Acta Physico-Chimica Sinica, 2025, 41(8): 100083-. doi: 10.1016/j.actphy.2025.100083
2. [2]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
3. [3]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
4. [4]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
5. [5]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
6. [6]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
7. [7]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
8. [8]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
9. [9]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
10. [10]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
11. [11]
  Junqing WEN , Ruoqi WANG , Jianmin ZHANG . Regulation of photocatalytic hydrogen production performance in GaN/ZnO heterojunction through doping with Li and Au. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 923-938. doi: 10.11862/CJIC.20240243
12. [12]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
13. [13]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
14. [14]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
15. [15]
  Yongmei Liu , Lisen Sun , Yongmei Hao , Zhanxiang Liu , Shuyong Zhang . Innovative Design of Chemistry Experiment Courses with Ideological and Political Education: A Case Study of Catalytic Hydrogen Production Experiments. University Chemistry, 2025, 40(5): 224-229. doi: 10.12461/PKU.DXHX202412144
16. [16]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
17. [17]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
18. [18]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
19. [19]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
20. [20]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S型异质结光催化制氢及其电荷转移动力学. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-. doi: 10.1016/j.actphy.2025.100084

Get Citation

PDF

XML

Metrics

PDF Downloads(218)
Abstract views(493)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142