Citation: WU Ke-Zhong, SUN Xiao-Long, CHEN Lei, RUAN Bei. Preparation and Thermal Performances of 1-Alkylammonium Tetrachlorocobaltate Eutectoid Mixtures as Phase Change Materials[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1260-1264. doi: 10.3866/PKU.WHXB201504163 shu

Preparation and Thermal Performances of 1-Alkylammonium Tetrachlorocobaltate Eutectoid Mixtures as Phase Change Materials

1.
Key Laboratory of Inorganic Nano-materials of Hebei Province, Department of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050024, P. R. China

Received Date: 12 February 2015
Available Online: 16 April 2015
Fund Project: 国家自然科学基金(21473048, 21246006) (21473048, 21246006)河北省自然科学基金(B2012205034)资助项目 (B2012205034)

The thermotropic phase-transition compounds 1-alkylammonium tetrachlorocobaltate (1-C_nH_2n+1NH₃)₂CoCl₄ (n=10, 18) and a series of their binary mixtures were prepared by solution reflux at 353 K in ethanol solutions. Binary-mixture (1-C₁₀H₂₁NH₃)₂CoCl₄-(1-C₁₈H₃₇NH₃)₂CoCl₄ systems were characterized over the entire composition range using differential scanning calorimetry and X-ray diffraction. The phase diagram constructed from the experiments indicated one stable intermediate phase, (1-C₁₀H₂₁NH₃)-(1-C₁₈H₃₇NH₃)CoCl₄, at a mass fraction w_C₁₀Co=52.51%, two invariant three-phase equilibria, and two eutectoid temperatures, which are assigned to e1 at (347±1) K, for the eutectoid point with w_C₁₀Co=38.50%, and e2 at (343±1) K, for the eutectoid point with w_C₁₀Co=69.86%. These three clear solid-solution ranges are α-phase on the left, β-phase on the right, and γ-phase in the middle of the phase diagram. The (1-C_nH_2n+1NH₃)₂CoCl₄ and their binary-mixture systems as phase change materials have phase-transition temperatures in the range 340-370 K, and transition enthalpies in the range 2.13 and 141.12 J·g^-1, between two polymorphic crystal forms.
- Bis(1-alkyammonium) tetrahelometallate,
- Phase change materials,
- Differential scanning calorimetry,
- Eutectoid temperature,
- Phase diagram
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