Citation: LIANG Yi, LU Yun, YAO Wei-Shang, ZHANG Xue-Tong. Polyimide Aerogels Crosslinked with Chemically Modified Graphene Oxide[J]. Acta Physico-Chimica Sinica, ;2015, 31(6): 1179-1185. doi: 10.3866/PKU.WHXB201504146 shu

Polyimide Aerogels Crosslinked with Chemically Modified Graphene Oxide

1.
School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China

Received Date: 30 December 2014
Available Online: 14 April 2015
Fund Project: 国家自然科学基金(21373024) (21373024)

Polyimide (PI) aerogels, which are generally crosslinked using expensive chemical crosslinking agents, are novel porous materials with high strength, high heat resistance, high porosity, and low density. Graphene oxide ( ) is a functional nanofiller that has aroused wide interest in recent years. The reported PI/ composites have mostly been in the form of fibers and films. In this study, PI/ composite aerogels were obtained using chemically modified graphene oxide (m- ) as the crosslinking agent, instead of traditional ones such as 1,3,5-triaminophenoxybenzene (TAB), by reaction with 4,4'-oxydianiline (ODA) and 3,3',4,4'- biphenyltetracarboxylic dianhydride (BPDA). The chemical modification of was achieved by reacting with excess ODA using a hydrothermal method. The microstructures of the PI/m- aerogels were investigated using scanning electron microscopy (SEM). Nitrogen sorption tests, thermogravimetric analysis, and a hot-wire method were used to investigate the effects of m- on the pore properties, thermal stabilities, and thermal conductivities, respectively, of the resulting aerogels. The results show that the PI/m- aerogels are highly porous, thermally stable, and heat insulating. Compression tests showed that the PI aerogel prepared using 0.6% (mass fraction, w) m- instead of 1.8% (w) TAB as the crosslinking agent had a higher specific Young's modulus [Young's modulus/density (ρ)] and specific yield strength (yield strength/ρ), and less shrinkage.
- Polyimide aerogel,
- Graphene oxide,
- Crosslinking,
- Mechanical property,
- Shrinkage ratio
1. [1]
  
  (1) Kistler, S. S. Nature 1931, 127, 741.
2. [2]
  (2) Tamon, H.; Ishizaka, H.; Mikami, M.; Okazaki, M. Carbon 1997, 35 (6), 791. doi: 10.1016/S0008-6223(97)00024-9
3. [3]
  (3) Wang, Z.; Dai, Z.; Wu, J.; Zhao, N.; Xu, J. Adv. Mater. 2013, 25 (32), 4494. doi: 10.1002/adma.v25.32
4. [4]
  (4) Xu, Z. J.; Ji, T.; Zhao, L.; Wang, W. Y.; Yang, C. Y.; Gan, L. H. Acta Phys. -Chim. Sin. 2012, 28 (2), 361. [徐子颉, 吉涛, 赵蕾, 王玮衍, 杨春艳, 甘礼华. 物理化学学报, 2012, 28 (2), 361.] doi: 10.3866/PKU.WHXB201112063
5. [5]
  (5) Guo, X. Z.; Yan, L. Q.; Yang, H.; Li, J.; Li, C. Y.; Cai, X. B. Acta Phys. -Chim. Sin. 2011, 27 (10), 2478. [郭兴忠, 颜立清, 杨辉, 李建, 李超宇, 蔡晓波. 物理化学学报, 2011, 27 (10), 2478.] doi: 10.3866/PKU.WHXB20110925
6. [6]
  (6) Xu, W.W.; Du, A.; Tang, J.; Chen, K.; Zou, L. P.; Zhang, Z. H.; Shen, J.; Zhou, B. Acta Phys. -Chim. Sin. 2012, 28 (12), 2958. [许维维, 杜艾, 唐俊, 陈珂, 邹丽萍, 张志华, 沈军, 周斌. 物理化学学报, 2012, 28 (12), 2958.] doi: 10.3866/PKU.WHXB201209282
7. [7]
  (7) Rhine, W.; Wang, J.; Begag, R. Production of Polyimide Aerogel for Carbon Aerogel, Involves Contacting Diamine and Aromatic Dianhydride Monomers in Solvent, Contacting Resulting Poly(amic acid) with Dehydrating Agent, and Drying Resulting Polyimide Gel. U. S. Patent 2004/0132845 A1, 2004-07-08.
8. [8]
  (8) Guo, H.; Meador, M. A. B.; McCorkle, L.; Quade, D. J.; Guo, J.; Hamilton, B.; Cakmak, M.; Sprowl, G. ACS Appl. Mater. Interfaces 2011, 3 (2), 546. doi: 10.1021/am101123h
9. [9]
  (9) Guo, H.; Meador, M. A. B.; McCorkle, L.; Quade, D. J.; Guo, J.; Hamilton, B.; Cakmak, M. ACS Appl. Mater. Interfaces 2012, 4
10. [10]
  (10), 5422. doi: 10.1021/am301347a
11. [11]
  (10) Meador, M. A. B.; Malow, E. J.; Silva, R.; Wright, S.; Quade, D.; Vivod, S. L.; Guo, H.; Guo, J.; Cakmak, M. ACS Appl. Mater. Interfaces 2012, 4 (2), 536. doi: 10.1021/am2014635
12. [12]
  (11) Meador, M. A. B.; Wright, S.; Sandberq, A.; Nquyen, B. N.; Vankeuls, F.W.; Mueller, C. H.; Rodríguez-Solís, R.; Miranda, F. A. ACS Appl. Mater. Interfaces 2012, 4 (11), 6346. doi: 10.1021/am301985s
13. [13]
  (12) Novoselov, K. S.; Jiang, D.; Schedin, F.; Booth, T. J.; Khotkevich, V. V.; Morozov, S. V.; Geim, A. K. Proceedings of the National Academy of Sciences 2005, 102 (30), 10451. doi: 10.1073/pnas.0502848102
14. [14]
  (13) Mkhoyan, K. A.; Contryman, A.W.; Silcox, J.; Stewart, D. A.; Eda, G.; Mattevi, C.; Miller, S.; Chhowalla, M. Nano Lett. 2009, 9 (3), 1058. doi: 10.1021/nl8034256
15. [15]
  (14) Shi, H.; Li, Y.; Guo, T. J. Appl. Polym. Sci. 2013, 128 (5), 3163. doi: 10.1002/app.v128.5
16. [16]
  (15) Dong, J.; Yin, C.; Zhao, X.; Li, Y.; Zhang, Q. Polymer 2013, 54 (23), 6415. doi: 10.1016/j.polymer.2013.09.035
17. [17]
  (16) Huang, T.; Xin, Y. S.; Li, T. S.; Nutt, S.; Su, C.; Chen, H. M.; Liu, P.; Lai, Z. L. ACS Appl. Mater. Interfaces 2013, 5 (11), 4878. doi: 10.1021/am400635x
18. [18]
  (17) Park, O. K.; Hwang, J. Y.; h, M.; Lee, J. H.; Ku, B. C.; You, N. H. Macromolecules 2013, 46 (9), 3505. doi: 10.1021/ma400185j
19. [19]
  (18) Liao, W. H.; Yang, S. Y.; Wang, J. Y.; Tien, H.W.; Hsiao, S. T.; Wang, Y. S.; Li, S. M.; Ma, C. C. M.; Wu, Y. F. ACS Appl. Mater. Interfaces 2013, 5 (3), 869. doi: 10.1021/am302494c
20. [20]
  (19) Yoonessi, M.; Shi, Y.; Scheiman, D. A.; Lebron-Colon, M.; Tigelaar, D. M.; Weiss, R. A.; Meador, M. A. ACS Nano 2012, 6 (9), 7644.
21. [21]
  (20) Zhang, X.; Sui, Z.; Xu, B.; Yue, S.; Luo, Y.; Zhan, W.; Liu, B. J. Mater. Chem. 2011, 21 (18), 6494. doi: 10.1039/c1jm10239g
22. [22]
  (21) Ghani, M. A. A.; Abdallah, D.; Kazmaier, P. M.; Keoshkerian, B.; Buncel, E. Can. J. Chem. 2004, 82 (9), 1403. doi: 10.1139/v04-106
23. [23]
  (22) Wang, G. Q. Water Resources Protection 2007, 23 (4), 85. [王国贤. 水资源保护, 2007, 23 (4), 85.]
24. [24]
  (23) Chen, H.; Yin, J. 1, 3, 5-Tri (4-amino phenoxy) Benzene and Preparation Method Thereof. CN Patent 1405145 A, 2003-03-26. [陈焕, 印杰. 1, 3, 5-三(4-氨基苯氧基)苯及其制备方法: 中国, CN 1405145 A [P]. 2003-03-26.]
25. [25]
  (24) Chidambareswarapattar, C.; Larimore, Z.; Sotiriou-Leventis, C.; Mang, J. T.; Leventis, N. J. Mater. Chem. 2010, 20 (43), 9666. doi: 10.1039/c0jm01844a
26. [26]
  (25) Wu, W.; Wang, K.; Zhan, M, S. Ind. Eng. Chem. Res. 2012, 51 (39), 12821. doi: 10.1021/ie301622s
27. [27]
  (26) Leventis, N.; Sotiriou-Leventis, C.; Mohite, D. P.; Larimore, Z. J.; Mang, J. T.; Churu, G.; Lu, H. Chem. Mate. 2011, 23 (8), 2250. doi: 10.1021/cm200323e
28. [28]
  (27) Yang, S.; Feng, X.; Müllen, K. Adv. Mater. 2011, 23 (31), 3575. doi: 10.1002/adma.201101599
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
3. [3]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
4. [4]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
5. [5]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
6. [6]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
7. [7]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
8. [8]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
9. [9]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
10. [10]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
11. [11]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
12. [12]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
13. [13]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
14. [14]
  Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-. doi: 10.3866/PKU.WHXB202309041
15. [15]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
16. [16]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
17. [17]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
18. [18]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
19. [19]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
20. [20]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

Get Citation

PDF

XML

Metrics

PDF Downloads(359)
Abstract views(1018)
HTML views(79)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142