Citation: CHEN Yang, ZHANG Zi-Lan, SUI Zhi-Jun, LIU Zhi-Ting, ZHOU Jing-Hong, ZHOU Xing-Gui. Preparation and Electrochemical Performance of Ni(OH)₂ Nanowires/ Three-Dimensional Graphene Composite Materials[J]. Acta Physico-Chimica Sinica, ;2015, 31(6): 1105-1112. doi: 10.3866/PKU.WHXB201504081 shu

Preparation and Electrochemical Performance of Ni(OH)₂ Nanowires/ Three-Dimensional Graphene Composite Materials

1.
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 9 February 2015
Available Online: 8 April 2015
Fund Project: 国家重点基础研究发展规划项目(973) (2014CB239702) (973) (2014CB239702)中央高校基本科研业务费专项基金(WA1514011)资助 (WA1514011)

We synthesized Ni(OH)₂ nanowires/three-dimensional graphene composites using a hydrothermal method, and compared their properties with those of three-dimensional graphene, Ni(OH)₂ nanowires, reduced graphene oxide, and Ni(OH)₂ nanowires/reduced graphene oxide. The samples were characterized using Xray diffraction, scanning electron microscopy, thermogravimetric analysis, and N₂ physisorption measurements. The electrochemical performances were investigated using cyclic voltammetry and galvanostatic chargedischarge methods. The results showed that Ni(OH)₂ nanowires of width 20-30 nm were closely combined with graphene and crosslinked to one another to form a three-dimensional structure with a high specific surface area (136 m²·g^-1) and mesoporosity (pore diameter 20-50 nm). The mass fraction of Ni(OH)₂ nanowires in the Ni(OH)₂ nanowires/three-dimensional graphene composite was 88%. The maximum specific capacitance of the Ni(OH)₂ nanowires/three-dimensional graphene composite was 1664 F·g^-1 in 6 mol·L^-1 KOH electrolyte at 1 A·g^-1. The specific capacitance decreased by only 7% after 3000 cycles at 1 A·g^-1. A comparative study of the specific capacitances and cycling performances of Ni(OH)₂ nanowires, Ni(OH)₂ nanowires/reduced graphene oxide, three-dimensional graphene, reduced graphene oxide, and Ni(OH)₂ nanowires/three-dimensional graphene indicated that three-dimensional graphene with three-dimensional porosity and a larger specific surface area than conventional reduced graphene oxide enabled improved use of the active material and significantly enhanced the electrochemical performance of Ni(OH)₂ nanowires.
- Graphene gel,
- Three-dimensional porosity,
- Specific capacitance,
- Hydrothermal method,
- Capacitance retention
1. [1]
  
  (1) Miller, J. R.; Simon, P. Science 2008, 321 (5889), 651. doi: 10.1126/science.1158736
2. [2]
  (2) Wang, J. D.; Peng, T. J.; Sun, H. J.; Hou, Y. D. Acta Phys. -Chim. Sin. 2014, 30 (11), 2077. [汪建德, 彭同江, 孙红娟, 侯云丹. 物理化学学报, 2014, 30 (11), 2077.] doi: 10.3866/PKU.WHXB201409152
3. [3]
  (3) Zhu, Y.W.; Murali, S.; Stoller, M. D.; Ganesh, K.; Cai, W.W.; Ferreira, P. J.; Pirkle, A.; Wallace, R. M.; Cychosz, K. A.; Thommes, M.; Su, D.; Stach, E. A.; Ruoff, R. S. Science 2011, 332 (6037), 1537. doi: 10.1126/science.1200770
4. [4]
  (4) El-Kady, M. F.; Strong, V.; Dubin, S.; Kaner, R. B. Science 2012, 335 (6074), 1326. doi: 10.1126/science.1216744
5. [5]
  (5) Zhang, Y. D.; Lee, S. H.; Yoonessi, M.; Liang, K.W.; Pittman, C. U. Polymer 2006, 47 (9), 2984. doi: 10.1016/j. polymer.2006.03.005
6. [6]
  (6) Zhao, Y. Q.; Schiraldi, D. A. Polymer 2005, 46 (25), 11640. doi: 10.1016/j.polymer.2005.09.070
7. [7]
  (7) Dong, X. C.; Xu, H.; Wang, X.W.; Huang, Y. X.; Chan-Park, M. B.; Zhang, H.; Wang, L. H.; Huang, W.; Chen, P. ACS Nano 2012, 6 (4), 3206. doi: 10.1021/nn300097q
8. [8]
  (8) Wang, H. L.; Cui, L. F.; Yang, Y.; Casalongue, H. S.; Robinson, J. T.; Liang, Y. Y.; Cui, Y.; Dai, H. J. J. Am. Chem. Soc. 2010, 132 (40), 13978. doi: 10.1021/ja105296a
9. [9]
  (9) Zhang, X. J.; Shi, W. H.; Zhu, J. X.; Zhao, W. Y.; Ma, J.; Mhaisalkar, S.; Maria, T.; Yang, Y. H.; Zhang, H.; Hng, H. H.; Yan, Q. Y. Nano Res. 2010, 3 (9), 643. doi: 10.1007/s12274-010-0024-6
10. [10]
  (10) Feng, L. D.; Zhu, Y. F.; Ding, H. Y.; Ni, C. Y. J. Power Sources 2014, 267 430. doi: 10.1016/j.jpowsour.2014.05.092
11. [11]
  (11) Meher, S. K.; Justin, P.; Rao, G. R. Nanoscale 2011, 3 (2), 683. doi: 10.1039/C0NR00555J
12. [12]
  (12) Xia, X. H.; Tu, J. P.; Mai, Y. J.; Wang, X. L.; Gu, C. D.; Zhao, X. B. J. Mater. Chem. 2011, 21 (25), 9319. doi: 10.1039/c1jm10946d
13. [13]
  (13) Chen, Z.; Augustyn, V.; Wen, J.; Zhang, Y.W.; Shen, M. Q.; Dunn, B.; Lu, Y. F. Adv. Mater. 2011, 23 (6), 791. doi: 10.1002/adma.201003658
14. [14]
  (14) Xia, X. H.; Tu, J. P.; Zhang, Y. Q.; Mai, Y. J.; Wang, X. L.; Gu, C. D.; Zhao, X. B. RSC Adv. 2012, 2 (5), 1835. doi: 10.1039/c1ra00771h
15. [15]
  (15) Ji, J. Y.; Zhang, L. L.; Ji, H. Y.; Li, Y.; Zhao, X.; Bai, X.; Fan, X. B.; Zhang, F. B.; Ruoff, R. S. ACS Nano 2013, 7 (7), 6237. doi: 10.1021/nn4021955
16. [16]
  (16) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Gri rieva, I. V.; Dubonos, S. V.; Firsov, A. A. Nature 2005, 438 (7065), 197. doi: 10.1038/nature04233
17. [17]
  (17) Yan, J.; Fan, Z. J.; Sun, W.; Ning, G. Q.; Wei, T.; Zhang, Q.; Zhang, R. F.; Zhi, L. J.; Wei, F. Adv. Funct. Mater. 2012, 22 (12), 2632. doi: 10.1002/adfm.201102839
18. [18]
  (18) Wang, Y. G.; Zhou, D. D.; Zhao, D.; Hou, M. Y.; Wang, C. X.; Xia, Y. Y. J. Electrochem. Soc. 2013, 160 (1), A98.
19. [19]
  (19) Li, C.; Shi, G. Q. Nanoscale 2012, 4 (18), 5549. doi: 10.1039/c2nr31467c
20. [20]
  (20) Xu, Y. X.; Lin, Z. Y.; Huang, X. Q.; Wang, Y.; Huang, Y.; Duan, X. F. Adv. Mater. 2013, 25 (40), 5779. doi: 10.1002/adma.v25.40
21. [21]
  (21) Zhang, J. T.; Zhao, X. S. J. Phys. Chem. C 2012, 116 (9), 5420. doi: 10.1021/jp211474e
22. [22]
  (22) Chen, H. Q.; Müller, M. B.; Gilmore, K. J.; Wallace, G. G.; Li, D. Adv. Mater. 2008, 20 (18), 3557. doi: 10.1002/adma.200800757
23. [23]
  (23) Lu, Y. J.; Wang, H. R.; Gu, Y.; Xu, L.; Sun, X. J.; Deng, Y. D. Acta Chim. Sin. 2012, 70, 1731. [卢亚骏, 王浩然, 顾煜, 徐岚, 孙晓骏, 邓意达. 化学学报, 2012, 70, 1731.] doi: 10.6023/A12070376
24. [24]
  (24) Wang, H. L.; Robinson, J. T.; Li, X. L.; Dai, H. J. J. Am. Chem. Soc. 2009, 131 (29), 9910. doi: 10.1021/ja904251p
25. [25]
  (25) Hall, D. S.; Lockwood, D. J.; Poirier, S.; Bock, C.; MacDougall, B. R. J. Phys. Chem. A 2012, 116 (25), 6771. doi: 10.1021/jp303546r
26. [26]
  (26) Gao, T.; Jelle, B. P. J. Phys. Chem. C 2013, 117 (33), 17294. doi: 10.1021/jp405149d
27. [27]
  (27) Zhang, L.; Yang, X.; Zhang, F.; Long, G. K.; Zhang, T. F.; Leng, K.; Zhang, Y.W.; Huang, Y.; Ma, Y. F.; Zhang, M. T.; Chen, Y. S. J. Am. Chem. Soc. 2013, 135 (15), 5921. doi: 10.1021/ja402552h
28. [28]
  (28) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157 (1), 11. doi: 10.1016/j.jpowsour.2006.02.065
29. [29]
  (29) Lu, Q.; Chen, J. G.; Xiao, J. Q. Angew. Chem. Int. Edit. 2013, 52 (7), 1882. doi: 10.1002/anie.v52.7
30. [30]
  (30) Zhu, J.W.; Chen, S.; Zhou, H.; Wang, X. Nano Res. 2012, 5 (1), 11. doi: 10.1007/s12274-011-0179-9
31. [31]
  (31) Liu, H. Y.; Zhang, W.; Song, H. H.; Chen, X. H.; Zhou, J. S.; Ma, Z. K. Electrochim. Acta 2014, 146, 511. doi: 10.1016/j.electacta.2014.09.083
32. [32]
  (32) Simon, P.; tsi, Y. Nat. Mater. 2008, 7 (11), 845. doi: 10.1038/nmat2297
1. [1]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
2. [2]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
3. [3]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
4. [4]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
5. [5]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
6. [6]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
7. [7]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
8. [8]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
9. [9]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
11. [11]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
12. [12]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
13. [13]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
14. [14]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
15. [15]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
16. [16]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
17. [17]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
18. [18]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
19. [19]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
20. [20]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046

Get Citation

PDF

XML

Metrics

PDF Downloads(424)
Abstract views(1030)
HTML views(63)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Performance of Ni(OH)2 Nanowires/ Three-Dimensional Graphene Composite Materials

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Performance of Ni(OH)₂ Nanowires/ Three-Dimensional Graphene Composite Materials