Citation: XU Ke, CHENG Yi, SUN Bo, PEI Yan, YAN Shi-Run, QIAO Ming-Hua, ZHANG Xiao-Xin, ZONG Bao-Ning. Fischer-Tropsch Synthesis over Skeletal Co@HZSM-5 Core-Shell Catalysts[J]. Acta Physico-Chimica Sinica, ;2015, 31(6): 1137-1144. doi: 10.3866/PKU.WHXB201503311 shu

Fischer-Tropsch Synthesis over Skeletal Co@HZSM-5 Core-Shell Catalysts

XU Ke ¹ ,
CHENG Yi ¹ ,
SUN Bo ¹ ,
PEI Yan ¹ ,
YAN Shi-Run ¹ ,
QIAO Ming-Hua ^1, ,
ZHANG Xiao-Xin ² ,
ZONG Bao-Ning ^2,

1.
1 Collaborative Innovation Center for Energy Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China;
2 State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, China Petroleum & Chemical Corporation, Beijing 100083, P. R. China

Received Date: 2 February 2015
Available Online: 31 March 2015
Fund Project: 国家重点基础研究发展规划项目(973) (2012CB224804) (973) (2012CB224804) 国家自然科学基金(21373055) (21373055)上海市科委科技基金(08DZ2270500)资助 (08DZ2270500)

We used skeletal Co as the core to prepare a skeletal Co@HZSM-5 core-shell catalyst by growing an HZSM-5 membrane on skeletal Co via hydrothermal synthesis. The physicochemical properties of the catalyst were determined using elemental analysis, N₂ physisorption, X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and NH₃ desorption. In gas-phase Fischer-Tropsch synthesis (FTS), the skeletal Co@HZSM-5 core-shell catalyst was more efficient than a physically mixed skeletal Co-HZSM-5 catalyst in cracking long-chain hydrocarbons, giving higher selectivity for C₅-C₁₁ gasoline products. The thickness of the zeolite shell on the skeletal Co@HZSM-5 core-shell catalyst was easily tuned by adjusting the hydrothermal time. At a suitable zeolite shell thickness, the long-chain hydrocarbons were cracked completely, with high FTS activity, leading to high selectivity for the gasoline fraction. Increasing the reaction temperature resulted in higher FTS and cracking activities, but the product distribution shifted to short-chain hydrocarbons. For the optimum skeletal Co@HZSM-5 core-shell catalyst, which was subjected to hydrothermal treatment for 4 d, selectivity for the gasoline fraction reached 79% at 250 ℃, which shows an excellent synergistic effect between the FTS active sites and the acidic sites on this catalyst.
- Skeletal Co,
- HZSM-5,
- Zeolite,
- Core-shell structure,
- Fischer-Tropsch synthesis
1. [1]
  
  (1) Schulz, H. Appl. Catal. A 1999, 186, 3. doi: 10.1016/S0926-860X(99)00160-X
2. [2]
  (2) Khodakov, A. Y.; Chu, W.; Fongarland, P. Chem. Rev. 2007, 107, 1692. doi: 10.1021/cr050972v
3. [3]
  (3) Kang, J. C.; Cheng, K.; Zhang, L.; Zhang, Q. H.; Ding, J. S.; Hua, W. Q.; Lou, Y. C.; Zhai, Q. G.; Wang, Y. Angew. Chem. Int. Edit. 2011, 50, 5200. doi: 10.1002/anie.v50.22
4. [4]
  (4) Friedel, R. A.; Anderson, R. B. J. Am. Chem. Soc. 1950, 72, 2307. doi: 10.1021/ja01161a536
5. [5]
  (5) van der Laan, G. P.; Beenackers, A. A. C. M. Catal. Rev. Sci. Eng. 1999, 41, 255. doi: 10.1081/CR-100101170
6. [6]
  (6) de Smit, E.; Weckhuysen, B. M. Chem. Soc. Rev. 2008, 37, 2758. doi: 10.1039/b805427d
7. [7]
  (7) Udaya, V.; Rao, S.; rmley, R. J. Catal. Today 1990, 6, 207. doi: 10.1016/0920-5861(90)85003-7
8. [8]
  (8) Yao, M.; Hu, S.; Wang, J.; Dou, T.; Wu, Y. P. Acta Phys. -Chim. Sin. 2012, 28, 2122. [姚敏, 胡思, 王俭, 窦涛, 伍永平. 物理化学学报, 2012, 28, 2122.] doi: 10.3866/PKU.WHXB201206211
9. [9]
  (9) Zhang, S. L.; Zhang, L. L.; Wang, W. G.; Min, Y. Y.; Ma, T.; Song, Y.; ng, Y. J.; Dou, T. Acta Phys. -Chim. Sin. 2014, 30, 535. [张少龙, 张兰兰, 王务刚, 闵媛媛, 马通, 宋宇, 巩雁军, 窦涛. 物理化学学报, 2014, 30, 535.] doi: 10.3866/PKU.WHXB201401032
10. [10]
  (10) Zhang, Q. H.; Kang, J. C.; Wang, Y. ChemCatChem 2010, 2, 1030. doi: 10.1002/cctc.201000071
11. [11]
  (11) Sun, B.; Qiao, M. H.; Fan, K. N.; Ulrich, J.; Tao, F. ChemCatChem 2011, 3, 542. doi: 10.1002/cctc.v3.3
12. [12]
  (12) Sun, B.; Yu, G. B.; Lin, J.; Xu, K.; Pei, Y.; Yan, S. R.; Qiao, M. H.; Fan, K. N.; Zhang, X. X.; Zong, B. N. Catal. Sci. Technol. 2012, 2, 1625. doi: 10.1039/c2cy20155k
13. [13]
  (13) Martínez, A.; López, C. Appl. Catal. A 2005, 294, 251. doi: 10.1016/j.apcata.2005.07.038
14. [14]
  (14) Pour, A. N.; Zamani, Y.; Tavasoli, A.; Shahri, S. M. K.; Taheri, S. A. Fuel 2008, 87, 2004. doi: 10.1016/j.fuel.2007.10.014
15. [15]
  (15) Wang, P.; Kang, J. C.; Zhang, Q. H.; Wang, Y. Catal. Lett. 2007, 114, 178. doi: 10.1007/s10562-007-9062-4
16. [16]
  (16) Ngamcharussrivichai, C.; Imyim, A.; Li, X. H.; Fujimoto, K. Ind. Eng. Chem. Res. 2007, 46, 6883. doi: 10.1021/ie070099j
17. [17]
  (17) Nijs, H. H.; Jacobs, P. A. J. Catal. 1980, 66, 401. doi: 10.1016/0021-9517(80)90043-3
18. [18]
  (18) Yu, G. B.; Sun, B.; Pei, Y.; Xie, S. H.; Yan, S. R.; Qiao, M. H.; Fan, K. N.; Zhang, X. X.; Zong, B. N. J. Am. Chem. Soc. 2010, 132, 935. doi: 10.1021/ja906370b
19. [19]
  (19) Cheng, K.; Zhang, L.; Kang, J. C.; Peng, X. P.; Zhang, Q. H.; Wang, Y. Chem. Eur. J. 2015, 21, 1928. doi: 10.1002/chem.v21.5
20. [20]
  (20) Zhang, Q. H.; Cheng, K.; Kang, J. C.; Deng, W. P.; Wang, Y. ChemSusChem 2014, 7, 1251. doi: 10.1002/cssc.201300797
21. [21]
  (21) Sartipi, S.; Parashar, K.; Makkee, M.; Gascon, J.; Kapteijn, F. Catal. Sci. Technol. 2013, 3, 572. doi: 10.1039/C2CY20744C
22. [22]
  (22) He, J.; Liu, Z.; Yoneyama, Y.; Nishiyama, N.; Tsubaki, N. Chem. -Eur. J. 2006, 12, 8296.
23. [23]
  (23) Bao, J.; He, J. J.; Zhang, Y.; Yoneyama, Y.; Tsubaki, N. Angew. Chem. Int. Edit. 2008, 47, 353.
24. [24]
  (24) Li, X. G.; He, J. J.; Meng, M.; Yoneyama, Y.; Tsubaki, N. J. Catal. 2009, 265, 26. doi: 10.1016/j.jcat.2009.04.009
25. [25]
  (25) Zhou, J. L.; Lü, Y. J.; Zhang, Z. X.; Li, G. H.; Dong, L. Y.; Wang, H. R.; Zhou, P. Z.; Lee, L. K. Skeletal Iron Catalyst and Its Preparation for Fischer-Tropsch Synthesis Processes. US Pat. 6265451, 2001.
26. [26]
  (26) Janey, J. M.; Orella, C. J.; Njolito, E.; Baxter, J. M.; Rosen, J. D.; Palucki, M.; Sidler, R. R.; Li, W.; Kowal, J. J.; Davies, I.W. J. Org. Chem. 2008, 73, 3212. doi: 10.1021/jo8000996
27. [27]
  (27) Madon, R. J.; Iglesia, E. J. Catal. 1994, 149, 428. doi: 10.1006/jcat.1994.1309
28. [28]
  (28) Yang, G.; He, J.; Yoneyama, Y.; Tan, Y.; Han, Y.; Tsubaki, N. Appl. Catal. A 2007, 329, 99. doi: 10.1016/j.apcata.2007.06.028
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