Citation: LI Li, HE Xiao-Li, QIN Tao, DAI Fu-Tao, ZHANG Xiao-Hua, CHEN Jin-Hua. Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn₃O₄-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 927-932. doi: 10.3866/PKU.WHXB201503241 shu

Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn₃O₄-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation

1.
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China

Received Date: 2 January 2015
Available Online: 24 March 2015
Fund Project: 长江学者和创新团队发展计划(IRT1238) (IRT1238) 国家自然科学基金(21275041, 21235002, J1210040) (21275041, 21235002, J1210040) 国家自然科学基金创新研究群体科学基金(21221003) (21221003) 湖南省自然科学基金(12JJ2010) (12JJ2010)博士学科点专项科研基金(20110161110009)资助项目 (20110161110009)

A new Pt-based electrocatalyst with one-dimensional tubular Mn₃O₄-C as the catalyst support was synthesized by a dual-sacrificial template strategy. The morphology, structure, and composition of the Pt-Mn₃O₄- C composite were characterized by transmission electron microscopy, X-ray diffraction, and energy dispersive X-ray spectroscopy, respectively. The electrochemical performance of Pt-Mn₃O₄-C was investigated by cyclic voltammetry. The results show that Pt nanoparticles with an average size of 1.8 nm are uniformly dispersed on tubular Mn₃O₄-C, and Pt-Mn₃O₄-C exhibits superior electrocatalytic activity and higher stability for methanol oxidation than the commercial E-TEK Pt/C catalyst (20% (w, mass fraction) Pt). The excellent performance of Pt-Mn₃O₄-C is attributed to the uniform dispersion of Pt nanoparticles on Mn₃O₄-C and the synergetic catalytic effect of Pt and Mn₃O₄.
- Pt nanoparticle,
- Tubular Mn₃O₄-C,
- Electrocatalyst,
- Methanol electrooxidation
1. [1]
  
  (1) Jiang, S. P.; Liu, Z.; Tian, Z. Q. Adv. Mater. 2006, 18, 1068.
2. [2]
  (2) Liu, H.; Song, C.; Zhang, L.; Zhang, J.; Wang, H.; Wilkinson, D. P. J. Power Sources 2006, 155, 95. doi: 10.1016/j.jpowsour.2006.01.030
3. [3]
  (3) Shen, Y.; Zhang, Z. H.; Long, R. R.; Xiao, K. J.; Xi, J. Y. ACS Appl. Mater. Inter. 2014, 6, 15162.
4. [4]
  (4) Huang, H.; Chen, Q.; He, M.; Sun, X.; Wang, X. J. Power Sources 2013, 239, 189. doi: 10.1016/j.jpowsour.2013.03.133
5. [5]
  (5) Cao, L.; Scheiba, F.; Roth, C.; Schweiger, F.; Cremers, C.; Stimming, U.; Fuess, H.; Chen, L.; Zhu, W.; Qiu, X. Angew. Chem. Int. Edit. 2006, 45, 5315.
6. [6]
  (6) Gu, Y. J.; Wong, W. T. Langmuir 2006, 22, 11447. doi: 10.1021/la062053l
7. [7]
  (7) Wang, C.; Kang, J. X.; Wang, L. L.; Chen, T.W.; Li, J.; Zhang, D. F.; Guo, L. Acta Phys. -Chim. Sin. 2014, 30, 708. [王纯, 康建新, 王利利, 陈庭文, 李杰, 张东凤, 郭林. 物理化学学报, 2014, 30, 708.] doi: 10.3866/PKU.WHXB201401222
8. [8]
  (8) Pietron, J. J.; Pomfret, C. N.; Chervin, C. N.; Long, J.W.; Rolison, D. R. J. Mater. Chem. 2012, 22, 5197. doi: 10.1039/c2jm15553b
9. [9]
  (9) Zhou, Y.; Chu, Y. Q.; Liu, W. M.; Ma, C. A. Acta Phys. -Chim. Sin. 2013, 29, 287. [周阳, 褚有群, 刘委明, 马淳安. 物理化学学报, 2013, 29, 287.] doi: 10.3866/PKU.WHXB201211261
10. [10]
  (10) Zhao, Z. G.; Yao, Z. J.; Zhang, J.; Zhu, R.; Jin, Y.; Li, Q.W. J. Mater. Chem. 2012, 22, 16514. doi: 10.1039/c2jm32769d
11. [11]
  (11) Guo, D. J.; You, J. M. J. Power Sources 2012, 198, 127. doi: 10.1016/j.jpowsour.2011.10.017
12. [12]
  (12) Yang, S.; Zhao, C.; Ge, C.; Dong, X.; Liu, X.; Liu, Y.; Fang, Y.; Wang, H.; Li, Z. J. Mater. Chem. 2012, 22, 7104. doi: 10.1039/c2jm00144f
13. [13]
  (13) Carabineiro, S. A. C.; Bastos, S. S. T.; Órfão, J. J. M.; Pereira, M. F. R.; Delgado, J. J.; Figueiredo, J. L. Catal. Lett. 2010, 134, 217. doi: 10.1007/s10562-009-0251-1
14. [14]
  (14) Maltha, A.; Favre, T. L. F.; Kist, H. F.; Zuur, A. P.; Ponec, V. J. Catal. 1994, 149, 364. doi: 10.1006/jcat.1994.1304
15. [15]
  (15) Lee, J.W.; Hall, A. S.; Kim, J. D.; Mallouk, T. E. Chem. Mater. 2012, 24, 1158. doi: 10.1021/cm203697w
16. [16]
  (16) rlin, Y.; Chung, C. J.; Nordlund, D.; Clemens, B. M.; Jaramillo, T. F. ACS Catal. 2012, 2, 2687. doi: 10.1021/cs3004352
17. [17]
  (17) Wang, H.; Cui, L. F.; Yang, Y.; Casalongue, H. S.; Robinson, J. T.; Liang, Y.; Cui, Y.; Dai, H. J. Am. Chem. Soc. 2010, 132, 13978. doi: 10.1021/ja105296a
18. [18]
  (18) Choi, C. H.; Park, S. H.; Woo, S. I. Phys. Chem. Chem. Phys. 2012, 14, 6842. doi: 10.1039/c2cp24128e
19. [19]
  (19) Zhao, Y.; Nie, S.; Wang, H.; Tian, J.; Ning, Z.; Li, X. J. Power Sources 2012, 218, 320. doi: 10.1016/j.jpowsour.2012.07.012
20. [20]
  (20) Xiao, Y. P.; Jiang, W. J.; Wan, S.; Zhang, X.; Hu, J. S.; Wei, Z. D.; Wan, L. J. J. Mater. Chem. A 2013, 1, 7463. doi: 10.1039/c3ta10298j
21. [21]
  (21) Yang, X. L.; Wang, X. Y.; Zhang, G. Q.; Zheng, J. P.; Wang, T. S.; Liu, X. Z.; Shu, C. Y.; Li, J.; Wang, C. R. Int. J. Hydrogen. Energ. 2012, 37, 11167. doi: 10.1016/j.ijhydene.2012.04.153
22. [22]
  (22) Kim, K.W.; Kim, S. M.; Choi, S.; Kim, J.; Lee, I. S. ACS Nano 2012, 6, 5122. doi: 10.1021/nn300782m
23. [23]
  (23) Zhu, L.; Zhang, S.; Cui, Y.; Song, H.; Chen, X. Electrochim. Acta 2013, 89, 18. doi: 10.1016/j.electacta.2012.10.157
24. [24]
  (24) Xiao, C.; Chen, J.; Liu, B.; Chu, X.; Wu, L.; Yao, S. Phys. Chem. Chem. Phys. 2011, 13, 1568. doi: 10.1039/C0CP00980F
25. [25]
  (25) Li, H.; Zhang, X.; Pang, H.; Huang, C.; Chen, J. J. Solid State Electrochem. 2010, 14, 2267.
26. [26]
  (26) Lv, Q.; Yin, M.; Zhao, X.; Li, C.; Liu, C.; Xing, W. J. Power Sources 2012, 218, 93. doi: 10.1016/j.jpowsour.2012.06.051
27. [27]
  (27) Zeng, J.; Francia, C.; Gerbaldi, C.; Baglio, V.; Specchia, S.; Aricò, A. S.; Spinelli, P. Electrochim. Acta 2013, 94, 80. doi: 10.1016/j.electacta.2013.01.139
28. [28]
  (28) Pozio, A.; Francesco, M. D.; Cemmi, A.; Cardellini, F.; Giorgi, L. J. Power. Sources 2002, 105, 13. doi: 10.1016/S0378-7753(01)00921-1
29. [29]
  (29) Ye, K. H.; Zhou, S. A.; Zhu, X. C.; Xu, C.W.; Shen, P. K. Electrochim. Acta 2013, 90, 108. doi: 10.1016/j. electacta.2012.12.012
30. [30]
  (30) Hao, Y. F.; Yang, Y. Y.; Hong, L. J.; Niu, L.; Gui, Y. H. ACS Appl. Mater. Interfaces 2014, 6, 21986. doi: 10.1016/10.1021/am5047747
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
3. [3]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
4. [4]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
5. [5]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
8. [8]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
9. [9]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
10. [10]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
11. [11]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
12. [12]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
13. [13]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
14. [14]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
15. [15]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
16. [16]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
17. [17]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
18. [18]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
19. [19]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
20. [20]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019

Get Citation

PDF

XML

Metrics

PDF Downloads(213)
Abstract views(374)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn3O4-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation

Metrics

通讯作者: 陈斌, bchen63@163.com

Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn₃O₄-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation