Citation: ZHANG Xiao-Qing, XU Yan YAN, YANG Chun-Hui, ZHANG Yan-Ping, YIN Yong-Xiang, SHANG Shu-Yong. In-situ Co-Precipitation of Ni-Mg-Al-LDH Catalytic Precursor on γ-Al₂O₃ for Dry Reforming of Methane: Synthesis and Evaluation[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 948-954. doi: 10.3866/PKU.WHXB201503111 shu

In-situ Co-Precipitation of Ni-Mg-Al-LDH Catalytic Precursor on γ-Al₂O₃ for Dry Reforming of Methane: Synthesis and Evaluation

1.
1 School of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China;
2 Institute for Chemical Engineering and Technology, Yibin University, Yibin 644000, Sichuan Province, P. R. China;
3 School of Chemistry and Chemical Engineering, Xuzhou Institute of Technology, Xuzhou 221111, Jiangsu Province, P. R. China

Received Date: 20 November 2014
Available Online: 11 March 2015
Fund Project: 国家自然科学基金(11075113) (11075113)四川省科技基金(2012GZ0114)资助项目 (2012GZ0114)

A series of novel catalysts derived from Ni-Mg-Al-LDHs (LDHs: layered double hydroxides) were synthesized in-situ on γ-Al₂O₃ and evaluated in CO₂ reforming of CH₄ (dry reforming of methane, DRM) reaction system. The catalytic precursors were decomposed and reduced by calcination and an atmospheric plasma technique, respectively. Activity and stability tests showed that the catalytic properties were greatly affected by the pretreatment method. The best catalytic performance was obtained with the catalyst that was directly reduced and decomposed using an atmospheric H₂/Ar plasma jet. Compared with the pure LDH precursor, Ni- Mg-Al-LDHs/γ-Al₂O₃ had much greater mechanical strength, because of the γ-Al₂O₃ support. This feature extends the long lifetime of catalyst at high temperatures. X-ray diffraction (XRD), transmission electron microscopy (TEM), N₂-adsorption-desorption, and thermogravimetry-differential thermal analysis (TG-DTA) results showed that the excellent catalytic performance was based on the small particle size and uniform dispersion of active Ni crystals, as well as the high mechanical strength and large specific surface area of the catalyst.
- Dry reforming of methane,
- Layered double hydroxide,
- Ni-based catalyst,
- Catalytic activity,
- Stability,
- Coke resistance
1. [1]
  
  (1) Tao, X. M.; Bai, M. G.; Li, X. A.; Long, H. L.; Shang, S. Y.; Yin, Y. X.; Dai, X. Y. Prog. Energy Combust. Sci. 2011, 37, 113. doi: 10.1016/j.pecs.2010.05.001
2. [2]
  (2) Brock, S. L.; Shimojo, T.; Suib, S. L.; Hayashi, Y.; Matsumoto, H. Research on Chemical Intermediates 2002, 28, 13. doi: 10.1163/156856702760129465
3. [3]
  (3) Bradford, M. C. J.; Vannice, M. A. Catal. Rev.-Sci. Eng. 1999, 41, 1. doi: 10.1081/CR-100101948
4. [4]
  (4) Liu, D.; Wang, Y.; Shi, D.; Jia, X.; Wang, X.; Borgna, A.; Lau, R.; Yang, Y. International Journal of Hydrogen Energy 2012, 37, 10135. doi: 10.1016/j.ijhydene.2012.03.158
5. [5]
  (5) Son, I. H.; Lee, S. J.; Soon, A.; Roh, H. S.; Lee, H. Applied Catalysis B-Environmental 2013, 134, 103.
6. [6]
  (6) Enger, B. C.; Lodeng, R.; Holmen, A. Applied Catalysis AGeneral 2008, 346, 1. doi: 10.1016/j.apcata.2008.05.018
7. [7]
  (7) Lin, J. J.; Chan, Y. N.; Lan, Y. F. Materials 2010, 3, 2588. doi: 10.3390/ma3042588
8. [8]
  (8) Guo, Z. L.; Huang, L. Q.; Chu, W.; Luo, S. Z. Acta Physico- Chimica Sinica 2014, 30, 723. [郭章龙, 黄丽琼, 储伟, 罗仕忠. 物理化学学报, 2014, 30, 723.] doi: 10.3866/PKU.WHXB201402242
9. [9]
  (9) Zumreoglu-Karan, B.; Ay, A. N. Chem. Pap. 2012, 66, 1. doi: 10.2478/s11696-011-0100-8
10. [10]
  (10) Tonelli, D.; Scavetta, E.; Giorgetti, M. Anal. Bioanal. Chem. 2013, 405, 603. doi: 10.1007/s00216-012-6586-2
11. [11]
  (11) h, K. H.; Lim, T. T.; Dong, Z. Water Res. 2008, 42, 1343. doi: 10.1016/j.watres.2007.10.043
12. [12]
  (12) Takehira, K.; Shishido, T.; Wang, P.; Kosaka, T.; Takaki, K. Journal of Catalysis 2004, 221, 43. doi: 10.1016/j.jcat.2003.07.001
13. [13]
  (13) Bhattacharyya, A.; Chang, V.W.; Schumacher, D. J. Applied Clay Science 1998, 13, 317. doi: 10.1016/S0169-1317(98)00030-1
14. [14]
  (14) Tsyganok, A. I.; Tsunoda, T.; Hamakawa, S.; Suzuki, K.; Takehira, K.; Hayakawa, T. Journal of Catalysis 2003, 213, 191. doi: 10.1016/S0021-9517(02)00047-7
15. [15]
  (15) Long, H.; Xu, Y.; Zhang, X.; Hu, S.; Shang, S.; Yin, Y.; Dai, X. Journal of Energy Chemistry 2013, 22, 733. doi: 10.1016/S2095-4956(13)60097-2
16. [16]
  (16) Gennequin, C.; Safariamin, M.; Siffert, S.; Aboukais, A.; Abi- Aad, E. Catalysis Today 2011, 176, 139. doi: 10.1016/j.cattod.2011.01.029
17. [17]
  (17) Wang, Q.; Ren, W.; Yuan, X.; Mu, R.; Song, Z.; Wang, X. International Journal of Hydrogen Energy 2012, 37, 11488. doi: 10.1016/j.ijhydene.2012.05.010
18. [18]
  (18) nzalez, A. R.; Asencios, Y. J. O.; Assaf, E. M.; Assaf, J. M. Appl. Surf. Sci. 2013, 280, 876. doi: 10.1016/j.apsusc.2013.05.082
19. [19]
  (19) Wang, J.; Fan, G. L.; Wang, H.; Li, F. Ind. Eng. Chem. Res. 2011, 50, 13717. doi: 10.1021/ie2015087
20. [20]
  (20) Gabrovska, M.; Edreva-Kardjieva, R.; Crisan, D.; Tzvetkov, P.; Shopska, M.; Shtereva, I. React. Kinet. Mech. Catal. 2012, 105, 79. doi: 10.1007/s11144-011-0378-0
21. [21]
  (21) Wang, Q.; Zhang, X.; Zhu, J.; Guo, Z.; O'Hare, D. Chemical Communications 2012, 48, 7450. doi: 10.1039/c2cc32708b
22. [22]
  (22) Liu, Z.; Zhou, J.; Cao, K.; Yang, W.; Gao, H.; Wang, Y.; Li, H. Applied Catalysis B-Environmental 2012, 125, 324. doi: 10.1016/j.apcatb.2012.06.003
23. [23]
  (23) Kathiraser, Y.; Thitsartarn, W.; Sutthiumporn, K.; Kawi, S. Journal of Physical Chemistry C 2013, 117, 8120. doi: 10.1021/jp401855x
24. [24]
  (24) Hou, Z. Y.; Yashima, T. Applied Catalysis A-General 2004, 261, 205. doi: 10.1016/j.apcata.2003.11.002
25. [25]
  (25) Nazemi, M. K.; Sheibani, S.; Rashchi, F.; nzalez-DelaCruz, V. M.; Caballero, A. Advanced Powder Technology 2012, 23, 833. doi: 10.1016/j.apt.2011.11.004
26. [26]
  (26) Lopez-Fonseca, R.; Jimenez- nzalez, C.; de Rivas, B.; Gutierrez-Ortiz, J. I. Applied Catalysis A-General 2012, 437, 53.
27. [27]
  (27) Zhang, Y. P.; Zhu, X. L.; Pan, Y. X.; Liu, C. J. Chinese Journal of Catalysis 2008, 29, 1058. [张月萍, 祝新利, 潘云翔, 刘昌俊. 催化学报, 2008, 29, 1058.]
28. [28]
  (28) Li, M. Z.; Fan, G. L.; Qin, H.; Li, F. Ind. Eng. Chem. Res. 2012, 51, 11892. doi: 10.1021/ie3008659
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In-situ Co-Precipitation of Ni-Mg-Al-LDH Catalytic Precursor on γ-Al2O3 for Dry Reforming of Methane: Synthesis and Evaluation

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通讯作者: 陈斌, bchen63@163.com

In-situ Co-Precipitation of Ni-Mg-Al-LDH Catalytic Precursor on γ-Al₂O₃ for Dry Reforming of Methane: Synthesis and Evaluation