Citation: XIA Long-Fei, JIANG Zhi, SHANGGUAN Wen-Feng, GU Shun-Chao, HIRANO Shinichi. Influence of Oxidation State of Nickel Supported on TiO₂ on Gas-Phase Hydrogenation of Acetonitrile[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 941-947. doi: 10.3866/PKU.WHXB201503051 shu

Influence of Oxidation State of Nickel Supported on TiO₂ on Gas-Phase Hydrogenation of Acetonitrile

1.
1 School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2 School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
3 Hirano Institute for Materials Innovation, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 9 December 2014
Available Online: 5 March 2015
Fund Project: 花王株式会社(日本)项目资助 (日本)

Nickel catalysts supported on TiO₂ were prepared using an impregnation method. Changes in the reduction temperature from 200 to 400 ℃ resulted in dispersion of nickel with different oxidation states on TiO₂. The gas-phase hydrogenation of acetonitrile was found to be influenced by the nickel oxidation state. Nickel reduced at 300 ℃ gave the highest acetonitrile conversion ratio, i.e., about 100%, when the reaction temperature was 100 ℃. The product yields depend on the amount of acidic sites on Ni/TiO₂ catalysts; this can be influenced not only by the TiO₂ support, but also by the properties of the supported nickel nanoparticles. The triethylamine yield increased to a maximum (from 34% to about 48%) with increasing reduction temperature; this corresponded to the gradual appearance of Ni⁰ in Ni/TiO₂ and a decrease in the intrinsic acidity of the Ni/TiO₂ catalyst. Triethylamine was the initial product in the hydrogenation of acetonitrile with Ni/TiO₂. The oxidation state of nickel influenced not only the conversion of acetonitrile but also desorption of the final products. Amechanism for the first step in this reaction is proposed.
- Gas-phase hydrogenation of acetonitrile,
- Impregnation method,
- TiO₂,
- Ni,
- Amine
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沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Oxidation State of Nickel Supported on TiO2 on Gas-Phase Hydrogenation of Acetonitrile

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通讯作者: 陈斌, bchen63@163.com

Influence of Oxidation State of Nickel Supported on TiO₂ on Gas-Phase Hydrogenation of Acetonitrile