Citation: XIA Long-Fei, JIANG Zhi, SHANGGUAN Wen-Feng, GU Shun-Chao, HIRANO Shinichi. Influence of Oxidation State of Nickel Supported on TiO₂ on Gas-Phase Hydrogenation of Acetonitrile[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 941-947. doi: 10.3866/PKU.WHXB201503051 shu

Influence of Oxidation State of Nickel Supported on TiO₂ on Gas-Phase Hydrogenation of Acetonitrile

1.
1 School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2 School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
3 Hirano Institute for Materials Innovation, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 9 December 2014
Available Online: 5 March 2015
Fund Project: 花王株式会社(日本)项目资助 (日本)

Nickel catalysts supported on TiO₂ were prepared using an impregnation method. Changes in the reduction temperature from 200 to 400 ℃ resulted in dispersion of nickel with different oxidation states on TiO₂. The gas-phase hydrogenation of acetonitrile was found to be influenced by the nickel oxidation state. Nickel reduced at 300 ℃ gave the highest acetonitrile conversion ratio, i.e., about 100%, when the reaction temperature was 100 ℃. The product yields depend on the amount of acidic sites on Ni/TiO₂ catalysts; this can be influenced not only by the TiO₂ support, but also by the properties of the supported nickel nanoparticles. The triethylamine yield increased to a maximum (from 34% to about 48%) with increasing reduction temperature; this corresponded to the gradual appearance of Ni⁰ in Ni/TiO₂ and a decrease in the intrinsic acidity of the Ni/TiO₂ catalyst. Triethylamine was the initial product in the hydrogenation of acetonitrile with Ni/TiO₂. The oxidation state of nickel influenced not only the conversion of acetonitrile but also desorption of the final products. Amechanism for the first step in this reaction is proposed.
- Gas-phase hydrogenation of acetonitrile,
- Impregnation method,
- TiO₂,
- Ni,
- Amine
1. [1]
  
  (1) Weissermel, K.; Arpe, H. J. Industrial Organic Chemistry; Verlag Chemie: Berlin, 1978.
2. [2]
  (2) Grayson, M. Kirk-Othmer Encyclopedia of Chemical Technology, 2nd ed.; Wiley: New York, 1983; Vol. 2, p 272.
3. [3]
  (3) Li, H. X.; Wu, Y. D.; Luo, H. S.; Wang, M. H.; Xu, Y. P. Journal of Catalysis 2003, 21, 15.
4. [4]
  (4) Wang, M. H.; Li, H. X.; Wu, Y. D.; Zhang, J. Materials Letters 2003, 57, 2954. doi: 10.1016/S0167-577X(02)01404-0
5. [5]
  (5) Braos-García, P.; García-Sancho, C.; Infantes-Molina, A.; Rodríguez-Castellón, E.; Jiménez-López, A. Applied Catalysis A: General 2010, 381, 132. doi: 10.1016/j.apcata.2010.03.061
6. [6]
  (6) Medina, F.; Salagre, P.; Sueiras, J. E.; Fierro, J. L. G. Journal of Molecular Catalysis 1991, 68, L17.
7. [7]
  (7) Medina, F.; Dutartre, R.; Tichit, D.; Coq, B.; Dung, N. T.; Salagre, P.; Sueiras, J. E. Journal of Molecular Catalysis A: Chemical 1997, 119, 201. doi: 10.1016/S1381-1169(96)00484-0
8. [8]
  (8) Braos-García, P.; Maireles-Torres, P.; Rodríguez-Castellón, E.; Jiménez-López, A. Journal of Molecular Catalysis A: Chemical 2003, 193, 185. doi: 10.1016/S1381-1169(02)00454-5
9. [9]
  (9) Yang, P. F.; Jiang, Z. X.; Ying, P. L.; Li, C. Journal of Catalysis 2008, 253, 66. doi: 10.1016/j.jcat.2007.10.029
10. [10]
  (10) mez, S.; Peters, J. A.; Maschmeyer, T. Adv. Synth. Catal. 2002, 344, 1037.
11. [11]
  (11) Verhaak, M. J. F. M.; Dillen, A. J.; Geus, J.W. Catalysis Letters 1994, 26, 37. doi: 10.1007/BF00824030
12. [12]
  (12) Zhao, J.; Chen, H.; Tian, X. C.; Zang, H.; Fu, Y. C.; Shen, J. Y. Journal of Catalysis 2013, 298, 161. doi: 10.1016/j.jcat.2012.11.010
13. [13]
  (13) Rode, C. V.; Arai, M.; Shirai, M.; Nishiyama, Y. Applied Catalysis A: General 1997, 148, 405. doi: 10.1016/S0926-860X(96)00238-4
14. [14]
  (14) Huang, Y. Y.; Sachtler, W. M. H. Journal of Catalysis 1999, 188, 215. doi: 10.1006/jcat.1999.2645
15. [15]
  (15) Huang, Y. Y.; Adeeva, V.; Sachtler, W. M. H. Applied Catalysis A: General 2000, 196, 73. doi: 10.1016/S0926-860X(99)00457-3
16. [16]
  (16) Gluhoi, A. C.; M?rginean, P.; St?nescu, U. Applied Catalysis A: General 2005, 294, 208. doi: 10.1016/j.apcata.2005.07.036
17. [17]
  (17) Cerveny, L. Catalytic Hydrogenation; Elsevier: Amsterdam, 1986.
18. [18]
  (18) Coq, B.; Tichit, D.; Ribet, S. Journal of Catalysis 2000, 189, 117. doi: 10.1006/jcat.1999.2694
19. [19]
  (19) Cabello, F. M.; Tichit, D.; Coq, B.; Vaccari, A.; Dung, N. T. Journal of Catalysis 1997, 167, 142. doi: 10.1006/jcat.1997.1523
20. [20]
  (20) Feng, W. M. Acta Phys. -Chim. Sin. 1992, 8, 313. [冯言貝民. 物理化学学报, 1992, 8, 313.] doi: 10.3866/PKU.WHXB19920307
21. [21]
  (21) Barr, T. L. J. Phys. Chem. 1978, 82, 1801. doi: 10.1021/j100505a006
22. [22]
  (22) Moulder, J. F.; Stickle, W. F.; Sobol, P. E.; Bomben, K. D. Handbook of X-ray Photoelectron Spectroscopy; Perkin Elmer Eden Prairie:Minnesota, MN, 1992.
23. [23]
  (23) Ramqvist, L.; Hamrin, K.; Johansson, G.; Fahlman, A.; Nordling, C. Journal of Physics and Chemistry of Solids 1969, 30, 1835. doi: 10.1016/0022-3697(69)90252-2
24. [24]
  (24) Hopfengärtner, G.; Borgmann, D.; Rademacher, I.; Wedler, G.; Hums, E.; Spitznagel, G. Journal of Electron Spectroscopy and Related Phenomena 1993, 63, 91. doi: 10.1016/0368-2048(93)80042-K
25. [25]
  (25) Leinen, D.; Fernandez, A.; Espinos, J.; Holgado, J.; nzález- Elipe, A. Applied Surface Science 1993, 68, 453. doi: 10.1016/0169-4332(93)90226-2
26. [26]
  (26) Rats, D.; Vandenbulcke, L.; Herbin, R.; Benoit, R.; Erre, R.; Serin, V.; Sevely, J. Thin Solid Films 1995, 270, 177. doi: 10.1016/0040-6090(95)06913-5
27. [27]
  (27) Perry, S. S.; Ager, J.W., III; Somorjai, G. A.; McClelland, R. J.; Drory, M. D. Journal of Applied Physics 1993, 74, 7542. doi: 10.1063/1.354980
28. [28]
  (28) Kim, K. S.; Davis, R. Journal of Electron Spectroscopy and Related Phenomena 1973, 1, 251.
29. [29]
  (29) Kuznetsov, M.; Zhuravlev, J. F.; Gubanov, V. Journal of Electron Spectroscopy and Related Phenomena 1992, 58, 169. doi: 10.1016/0368-2048(92)80016-2
1. [1]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
2. [2]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
3. [3]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
4. [4]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
5. [5]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
6. [6]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
7. [7]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
8. [8]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
9. [9]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
10. [10]
  Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO₂ catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315
11. [11]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
12. [12]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
13. [13]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
14. [14]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
15. [15]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
16. [16]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
17. [17]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
18. [18]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2023.100309
19. [19]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
20. [20]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240

Get Citation

PDF

XML

Metrics

PDF Downloads(225)
Abstract views(366)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Oxidation State of Nickel Supported on TiO2 on Gas-Phase Hydrogenation of Acetonitrile

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of Oxidation State of Nickel Supported on TiO₂ on Gas-Phase Hydrogenation of Acetonitrile